An overview of double perovskites A2B′B″O6 with small ions at A site: Synthesis, structure and magnetic properties
Source abstract
Abstract
Abstract Layered oxides, A2B'B″O6, with small ions at A-site mostly occupied by unusual-metals like transitional metals are of great importance due to their strong and unusual magnetic interactions and technical applications. Due to small tolerance factors it is very difficult to synthesize such materials in ambient pressure and temperature. Depending upon the variation in temperature and pressure, same composition of the above mentioned materials can be crystallized with different structural arrangements. The effect of pressure and synthetic condition of different materials has been described in this review. The literature data on the effects of the A-site occupation by small ions on the structure and properties are summarized. Finally structural changes and dissimilar properties of high temperature and pressure synthesized recent developed materials are compared with the materials with usual B-site ordered double perovskite.
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Research context
OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials · Advanced Condensed Matter Physics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Mitchell · 2002
2. The perovskite structure - a review of its role in ceramic science and technology10.1007/s100190000062 ↗
3. Room-temperature magnetoresistance in an oxide material with an ordered double-perovskite structure10.1038/27167 ↗
4. Impact of cation size on magnetic properties of AA'2FeReO6 double perovskites10.1103/PhysRevB.69.144401 ↗
5. Structural and electronic properties of the ordered double perovskites A2MReO6 (A = Sr, Ca; M = Mg, Sc,Cr, Mn, Fe, Co, Ni, Zn)10.1103/PhysRevB.69.184412 ↗
6. Evidence of unquenched Re orbital magnetic moment in AA'FeReO6 double perovskites10.1063/1.2234292 ↗
7. Double perovskites with ferromagnetism above room temperature10.1088/0953-8984/19/2/023201 ↗
8. Variable range hopping in A2MnReO6 (A=Ca,Sr,Ba)10.1063/1.2967820 ↗
9. Electronic structure and half-metallic transport in the La1-xCaxMnO3 system10.1103/PhysRevB.53.1146 ↗
10. Superconductivity near 30 K without copper: the Ba0.6K0.4BiO3 perovskite10.1038/332814a0 ↗
11. Numerical data and functional relationships in science and technology, new series, group III: crystal and solid state physics
12. Synthesis, structure and magnetic properties of nanostructured La1-xAxFe0.5Mn0.5O3 (a = Ca, Sr and Pb; x = 0 & 0.25) perovskites10.1016/j.jmmm.2017.07.087 ↗
13. Piezoelectricity across a strain-induced isosymmetric ferri-to-ferroelectric transition10.1002/admi.201400042 ↗
14. Spin-glass behavior in Sr2FeRuO6 and BaLaNiRuO6: a comparison with antiferromagnetic BaLaZnRuO610.1016/0022-4596(89)90109-6 ↗
15. Frustration-driven spin freezing in the S= 1/2 fcc perovskite Sr2MgReO610.1103/PhysRevB.68.134410 ↗
16. Why are there so few perovskite ferroelectrics?10.1021/jp402046t ↗
17. Structural and magnetotransport properties of the Si doped B-site in La0.6Gd0.1Sr0.3Mn1-xSixO3 (0 ≤ x ≤ 0.15) manganite10.1016/j.jallcom.2016.12.277 ↗
18. A family of oxide ion conductors based on the ferroelectric perovskite Na0.5Bi0.5TiO310.1038/nmat3782 ↗
19. Advances in designing perovskite catalysts10.1016/S1359-0286(01)00035-3 ↗
20. Multiferroics: a magnetic twist for ferroelectricity10.1038/nmat1804 ↗
21. Double perovskites as anode materials for solid-oxide fuel cells10.1126/science.1125877 ↗
22. The emergence of perovskite solar cells10.1038/nphoton.2014.134 ↗
23. Chemically diverse and multifunctional hybrid organic–inorganic perovskites10.1038/natrevmats.2016.99 ↗
24. Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity10.1039/b511119f ↗
25. Multiferroic and magnetoelectric oxides: the emerging scenario10.1021/jz300688b ↗
26. Why are there so few magnetic ferroelectrics?10.1021/jp000114x ↗
27. The role of polar, lamdba (Λ)-Shaped building units in noncentrosymmetric inorganic structures10.1021/ja210984k ↗
28. High-pressure synthesis, crystal chemistry and physics of perovskites with small cations at the A site
29. Energetics and crystal chemical systematics among ilmenite, lithium niobate and perovskite structures10.1021/cm9801901 ↗
30. Incommensurate spin order in the metallic perovskite MnVO310.1103/PhysRevB.84.094450 ↗
31. The chemical imagination at work in very tight places10.1002/anie.200602485 ↗
32. High-pressure/high-temperature synthesis of transition metal oxide perovskites10.1515/znb-2006-1208 ↗
33. Structural and phase transition of Mg-doped on Mn-site in La0.7Sr0.3MnO3 bulk/nanostructured perovskite characterised through online ultrasonic technique
34. Recent developed different structural nanomaterials and their performance for supercapacitor application10.1016/j.apmt.2017.08.010 ↗
35. Synthesis, structures and magnetic properties of the dimorphic Mn2CrSbO6 oxide10.1039/C4DT03849E ↗
36. Perovskite, LiNbO3, corundum, and hexagonal polymorphs of (In(1-x)M(x))MO310.1021/ja2010362 ↗
37. A polar corundum oxide displaying weak ferromagnetism at room temperature10.1021/ja208395z ↗
38. Coexistence of weak ferromagnetism and ferroelectricity in the high pressure LiNbO3 type phase of FeTiO310.1103/PhysRevLett.103.047601 ↗
39. Polar and magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3-type structure: high-pressure synthesis10.1002/anie.201302775 ↗
40. A-site and B-Site charge orderings in an s–d level controlled perovskite oxide PbCoO310.1021/jacs.7b01851 ↗
41. (In1-yMny)MnO3 (1/9 ≤ y ≤ 1/3): unusual perovskites with unusual properties10.1002/anie.201003080 ↗
42. High pressure synthesis of ilmenite and perovskite type MnVO3 and their magnetic properties10.1016/S0022-3697(71)80026-4 ↗
43. Mn2MnReO6: synthesis and magnetic structure determination of a new transition-metal-only double perovskite canted antiferromagnet10.1021/acs.chemmater.6b00755 ↗
44. Compounds of post-transition elements with the ordered perovskite structure
45. A study of the crystal structures and the phase transitions of the ordered double perovskites Sr2ScSbO6 and Ca2ScSbO610.1016/j.jssc.2012.04.019 ↗
46. Magnetic-structure-stabilized polarization in an above-room-temperature ferrimagnet10.1002/anie.201406180 ↗
47. Mn2FeWO6: a new Ni3TeO6-Type polar and magnetic oxide10.1002/adma.201405244 ↗
48. Magnetic and crystal structure determination of Mn2FeSbO6 double perovskite10.1088/0953-8984/25/20/206004 ↗
49. Switching from ferro- to antiferromagnetism in A2CrSbO6 (A = Ca, Sr) double perovskites: a neutron diffraction study10.1039/b705797k ↗
50. A2FeSbO6 (A = Sr, Ca) double perovskites oxides: crystal structures, phases transitions and 57Fe Mössbauer spectroscopy study10.1107/S0108767307095888 ↗
51. High pressure synthesis and polymorphism of complex oxides Mn2BSbO6(B= Fe, V, Cr, Ga, Al)10.1006/jssc.1996.0246 ↗
52. Crystal structure of A2InSbO6 (A = Ca, Sr, Ba) ordered double perovskites10.1016/j.solidstatesciences.2010.01.011 ↗
53. Ivanov · Eur. J. Inorg. Chem. · 2011 · 2011 · 469110.1002/ejic.201100381 ↗
54. Dielectric relaxation in A2FeNbO6 (A=Ba, Sr, and Ca) perovskite ceramics10.1007/s10832-007-9353-6 ↗
55. Study of magnetic properties of A2B′NbO6 (A=Ba,Sr,BaSr; and B′=Fe and Mn) double perovskites10.1063/1.1682952 ↗
56. Magnetic susceptibilities and Mössbauer spectra of perovskites A2FeNbO6 (A=Sr, Ba)10.1006/jssc.2000.8900 ↗
57. Investigation of magnetic frustration in A2FeMO6(A =Ca, Sr, Ba; M = Nb, Ta, Sb) by magnetometry and Mössbauer spectroscopy10.1039/JM9950500865 ↗
58. Mathieu · Appl. Phys. Lett. · 2011 · 9810.1063/1.3593194 ↗
59. Sato · J. Phys. Soc. Jpn. · 1981 · 50 · 6
60. Designing polar and magnetic oxides: Zn2FeTaO6 - in search of multiferroics10.1021/ja502774v ↗
61. Mn2FeWO6: a new Ni3TeO6 -type polar and magnetic oxide10.1002/adma.201405244 ↗
62. Structural studies and order–disorder phenomenon in a series of new quaternary tellurates of the type A2+M4+Te6+O6 and A1+2M4+Te6+O610.1006/jssc.1999.8183 ↗
63. Li · Angew. Chem. Int. Ed. · 2014 · 53 · 1077410.1002/anie.201406180 ↗
64. Giant magnetoresistance in the half-metallic double-perovskite ferrimagnet Mn2FeReO610.1002/anie.201506456 ↗
65. Crystal structure and magnetic properties of double perovskite Mn2FeSbO610.1016/j.materresbull.2011.04.001 ↗
66. Synthesis, structure and magnetic properties of the new double perovskite Ca2CrSbO610.1016/j.ssc.2006.05.011 ↗
67. Structural distortion on metal–insulator transition in ordered double perovskite Ca2FeReO610.1143/JPSJ.72.1411 ↗
68. Large magnetization and frustration switching of magnetoresistance in the double-perovskite ferrimagnet Mn2FeReO610.1002/anie.201506540 ↗
69. Quantitative phase analysis using the Rietveld method10.1107/S0021889887009415 ↗
70. Crystallographic and magnetic structure of the Sr2MnReO6 double perovskite10.1088/0953-8984/16/1/013 ↗
71. Empirical bond-strength-bond-length curves for oxides10.1107/S0567739473000689 ↗
72. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
73. A2B′B″O6 perovskites: a review10.1016/j.progsolidstchem.2014.08.001 ↗
74. Designed ferromagnetic, ferroelectric Bi2NiMnO610.1021/ja0512576 ↗
75. Electronic and magnetic properties of La2NiMnO6 and La2CoMnO6 with cationic ordering10.1063/1.3683550 ↗
76. Magnetic frustration and dielectric relaxation in insulating Nd2NiMnO6 double perovskites10.1063/1.4906989 ↗
77. Sc2NiMnO6: a double-perovskite with a magnetodielectric response driven by multiple magnetic orders10.1021/acs.inorgchem.5b01195 ↗
78. High-pressure synthesis, crystal structure, and properties of In2NiMnO6 with antiferromagnetic order and field-induced phase transition10.1021/ic401917h ↗
79. Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO310.1103/PhysRev.100.564 ↗
80. Superexchange interaction and symmetry properties of electron orbitals10.1016/0022-3697(59)90061-7 ↗
81. Crystal chemistry of non-perovskite manganese oxides – implications for magnetic properties10.1002/pssc.200304432 ↗
82. High pressure synthesis of polar and non-polar cation-ordered polymorphs of Mn2ScSbO610.1039/C5DT03445K ↗
83. The interplay of microstructure and magnetism in La3Ni2SbO910.1016/j.jssc.2014.08.024 ↗
84. Weak ferromagnetism and domain effects in multiferroic LiNbO3-type MnTiO3-II10.1103/PhysRevB.88.104416 ↗
85. Magnetism and the Chemical Bond
86. Blundell · 2001
87. Large magnetoelectric coupling near room temperature in synthetic melanostibite Mn2FeSbO610.1002/ange.201609762 ↗
88. Sol–gel synthesis of the magnetically frustrated oxides Sr2FeSbO6 and SrLaFeSnO610.1039/JM9950500075 ↗
89. Double double cation order in the high-pressure perovskites MnRMnSbO610.1002/anie.201603526 ↗
90. Azad · 2002 · 37 · 1797
91. Independent ordering of two interpenetrating magnetic sublattices in the double perovskite Sr2CoOsO610.1021/ja407342w ↗
92. Large effects of A-site average cation size on the properties of the double perovskites Ba2-xSrxMnReO6: a d5-d1 system10.1103/PhysRevB.67.024406 ↗
93. Giant magnetostriction in Ca2FeReO6 double perovskite10.1016/j.jmmm.2004.11.390 ↗
94. Magnetism in Re-based ferrimagnetic double perovskites10.1088/1367-2630/11/7/073047 ↗
95. Electronic structure study of double perovskites A2FeReO6 (A=Ba,Sr,Ca) and Sr2MMoO6 (M=Cr,Mn,Fe,Co) by LSDA and LSDA+U10.1103/PhysRevB.64.125126 ↗
96. Synthesis and physical properties of double perovskite Pb2FeReO610.1021/ic900297q ↗
97. A thermodynamic theory of “weak” ferromagnetism of antiferromagnetics10.1016/0022-3697(58)90076-3 ↗
98. Anisotropic superexchange interaction and weak Ferromagnetism10.1103/PhysRev.120.91 ↗
99. Coulomb gap and low temperature conductivity of disordered systems10.1088/0022-3719/8/4/003 ↗
100. Glazer · Acta Crystallogr. Sect. B: Struct. Crystallogr. Cryst. Chem. B · 1972 · 28 · 338410.1107/S0567740872007976 ↗