journal article·2019-02-11Open access

Flexible, transparent nanocellulose paper-based perovskite solar cells

Lei Gao, Lingfeng Chao, Meihui Hou, Jin Liang, Yonghua Chen, Hai-Dong Yu, Wei Huang

npj Flexible Electronics· Volume 3· Issue 1

Abstract

Abstract Recently perovskite solar cells (PSCs), as photoelectric conversion devices, exhibit excellent power conversion efficiency (PCE) and low-processing cost, and have become one of the most promising devices to replace conventional silicon-based solar cells and address current pressing energy issues. Among them, the flexible PSCs are especially more widely applicable and may propel the rapid advancements of wearable electronics, causing a significant paradigm shift in consumer electronics. Current flexible PSCs use non-biodegradable petroleum-based polymer substrates, discarding of which will aggravate “white pollution”. Therefore, development of green, biodegradable and low-cost flexible substrates will provide a great alternative to flexible PSCs. Here we have developed transparent nanocellulose paper (NCP) with coating of acrylic resin as substrates to fabricate flexible PSCs, which are biodegradable and easily disposable. The PCE of these NCP-based PSCs reached 4.25%, while the power per weight (the ratio of power to device weight) was as high as 0.56 W g–1. The flexible PSCs also showed good stability, retaining >80% of original efficiency after 50 times of bending. The NCP-based substrates can also be applied to other electronic systems, which may prosper next-generation green flexible electronics.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Lund, A. et al. Energy harvesting textiles for a rainy day: woven piezoelectrics based on melt-spun PVDF microfibres with a conducting core. npj Flex. Electron. 2, 1–9 (2018).10.1038/s41528-018-0022-4 ↗
2. Wang, Z., Shi, Z., Li, T., Chen, Y. & Huang, W. Stability of perovskite solar cells: a prospective on the substitution of the A cation and X anion. Angew. Chem. Int. Ed. 56, 1190–1212 (2017).10.1002/anie.201603694 ↗
3. Wang, F., Bai, S., Tress, W., Hagfeldt, A. & Gao, F. Defects engineering for high-performance perovskite solar cells. npj Flex. Electron. 2, 1–14 (2018).10.1038/s41528-017-0014-9 ↗
4. Zhang, W. et al. Enhanced optoelectronic quality of perovskite thin films with hypophosphorous acid for planar heterojunction solar cells. Nat. Commun. 6, 1–9 (2015).
5. Liu, Z., You, P., Xie, C., Tang, G. & Yan, F. Ultrathin and flexible perovskite solar cells with graphene transparent electrodes. Nano Energy 28, 151–157 (2016).10.1016/j.nanoen.2016.08.038 ↗
6. Roldán-Carmona, C. et al. Flexible high efficiency perovskite solar cells. Energy Environ. Sci. 7, 994–997 (2014).10.1039/c3ee43619e ↗
7. Hu, W. et al. High-performance flexible photodetectors based on high-quality perovskite thin films by a vapor-solution method. Adv. Mater. 29, 1–8 (2017).
8. Di Giacomo, F., Fakharuddin, A., Jose, R. & Brown, T. M. Progress, challenges and perspectives in flexible perovskite solar cells. Energy Environ. Sci. 9, 3007–3035 (2016).10.1039/C6EE01137C ↗
9. Irimia-Vladu, M., Głowacki, E. D., Voss, G., Bauer, S. & Sariciftci, N. S. Green and biodegradable electronics. Mater. Today 15, 340–346 (2012).10.1016/S1369-7021(12)70139-6 ↗
10. R. Jambeck, J. et al. Plastic waste inputs from land into the ocean. Science 347, 768–771 (2015).10.1126/science.1260352 ↗
11. Valavanidis, A., Iliopoulos, N., Gotsis, G. & Fiotakis, K. Persistent free radicals, heavy metals and PAHs generated in particulate soot emissions and residue ash from controlled combustion of common types of plastic. J. Hazard. Mater. 156, 277–284 (2008).10.1016/j.jhazmat.2007.12.019 ↗
12. Jung, Y. H. et al. High-performance green flexible electronics based on biodegradable cellulose nanofibril paper. Nat. Commun. 6, 1–11 (2015).
13. Lin, Y., Gritsenko, D., Liu, Q., Lu, X. & Xu, J. Recent advancements in functionalized paper-based electronics. ACS Appl. Mater. Interfaces 8, 20501–20515 (2016).10.1021/acsami.6b04854 ↗
14. Mahadeva, S. K., Walus, K. & Stoeber, B. Paper as a platform for sensing applications and other devices: a review. ACS Appl. Mater. Interfaces 7, 8345–8362 (2015).10.1021/acsami.5b00373 ↗
15. Zhang, Y. et al. Flexible electronics based on micro/nanostructured paper. Adv. Mater. 1801588, 1–39 (2018).
16. Hamedi, M. M. et al. Integrating electronics and microfluidics on paper. Adv. Mater. 28, 5054–5063 (2016).10.1002/adma.201505823 ↗
17. Ainla, A., Hamedi, M. M., Guder, F. & Whitesides, G. M. Electrical textile valves for paper microfluidics. Adv. Mater. 29, 1–10 (2017).10.1002/adma.201702894 ↗
18. Guder, F. et al. Paper-based electrical respiration sensor. Angew. Chem. Int. Ed. 55, 5727–5732 (2016).10.1002/anie.201511805 ↗
19. Siegel, A. C. et al. Foldable printed circuit boards on paper substrates. Adv. Funct. Mater. 20, 28–35 (2010).10.1002/adfm.200901363 ↗
20. Castro-Hermosa, S., Dagar, J., Marsella, A. & Brown, T. M. Perovskite solar cells on paper and the role of substrate and electrodes on performance. IEEE Electron Device Lett. 38, 1278–1281 (2017).10.1109/LED.2017.2735178 ↗
21. Xue, J., Song, F., Yin, X. W., Wang, X. L. & Wang, Y. Z. Let it shine: a transparent and photoluminescent foldable nanocellulose/quantum dot paper. ACS Appl. Mater. Interfaces 7, 10076–10079 (2015).10.1021/acsami.5b02011 ↗
22. Wang, S., Lu, A. & Zhang, L. Recent advances in regenerated cellulose materials. Progress. Polym. Sci. 53, 169–206 (2016).10.1016/j.progpolymsci.2015.07.003 ↗
23. Nogi, M., Iwamoto, S., Nakagaito, A. N. & Yano, H. Optically transparent nanofiber paper. Adv. Mater. 21, 1595–1598 (2009).10.1002/adma.200803174 ↗
24. Zhang, J. et al. All-cellulose nanocomposites reinforced with in situ retained cellulose nanocrystals during selective dissolution of cellulose in an ionic liquid. ACS Sustain. Chem. Eng. 4, 4417–4423 (2016).10.1021/acssuschemeng.6b01034 ↗
25. Zhu, H., Fang, Z., Preston, C., Li, Y. & Hu, L. Transparent paper: fabrications, properties, and device applications. Energy Environ. Sci. 7, 269–287 (2014).10.1039/C3EE43024C ↗
26. Zhang, Z., Wang, H., Li, S., Li, L. & Li, D. Transparent and flexible cellulose nanofibers/silver nanowires/acrylic resin composite electrode. Compos. Part A 76, 309–315 (2015).10.1016/j.compositesa.2015.06.010 ↗
27. Park, N.-M. et al. Electroluminescent nanocellulose paper. Mater. Lett. 196, 12–15 (2017).10.1016/j.matlet.2017.03.003 ↗
28. Devarayan, K., Lei, D., Kim, H.-Y. & Kim, B.-S. Flexible transparent electrode based on PANi nanowire/nylon nanofiber reinforced cellulose acetate thin film as supercapacitor. Chem. Eng. J. 273, 603–609 (2015).10.1016/j.cej.2015.03.115 ↗
29. Wang, X. et al. Layer-by-layer assembled hybrid multilayer thin film electrodes based on transparent cellulose nanofibers paper for flexible supercapacitors applications. J. Power Sources 249, 148–155 (2014).10.1016/j.jpowsour.2013.09.130 ↗
30. Zhu, H. et al. Extreme light management in mesoporous wood cellulose paper for optoelectronics. ACS Nano 10, 1369–1377 (2016).10.1021/acsnano.5b06781 ↗
31. Hu, L. et al. Transparent and conductive paper from nanocellulose fibers. Energy Environ. Sci. 6, 513–518 (2013).10.1039/C2EE23635D ↗
32. Zhu, H. et al. Biodegradable transparent substrates for flexible organic-light-emitting diodes. Energy Environ. Sci. 6, 2105–2111 (2013).10.1039/c3ee40492g ↗
33. Daniele, M. A., Knight, A. J., Roberts, S. A., Radom, K. & Erickson, J. S. Sweet substrate: a polysaccharide nanocomposite for conformal electronic decals. Adv. Mater. 27, 1600–1606 (2015).10.1002/adma.201404445 ↗
34. Hsieh, M. C., Kim, C., Nogi, M. & Suganuma, K. Electrically conductive lines on cellulose nanopaper for flexible electrical devices. Nanoscale 5, 9289–9295 (2013).10.1039/c3nr01951a ↗
35. Fang, Z. et al. Highly transparent paper with tunable haze for green electronics. Energy Environ. Sci. 7, 3313–3319 (2014).10.1039/C4EE02236J ↗
36. Zhu, H. et al. A gravure printed antenna on shape-stable transparent nanopaper. Nanoscale 6, 9110–9115 (2014).10.1039/C4NR02036G ↗
37. Hoeng, F., Denneulin, A. & Bras, J. Use of nanocellulose in printed electronics: a review. Nanoscale 8, 13131–13154 (2016).10.1039/C6NR03054H ↗
38. Docampo, P., Ball, J. M., Darwich, M., Eperon, G. E. & Snaith, H. J. Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates. Nat. Commun. 4, 1–6 (2013).10.1038/ncomms3761 ↗
39. Kaltenbrunner, M. et al. Flexible high power-per-weight perovskite solar cells with chromium oxide-metal contacts for improved stability in air. Nat. Mater. 14, 1032–1039 (2015).10.1038/nmat4388 ↗
40. Poorkazem, K., Liu, D. & L. Kelly, T. Fatigue resistance of a flexible, efficient, and metal oxide-free perovskite solar cell. J. Mater. Chem. A 3, 9241–9248 (2015).10.1039/C5TA00084J ↗
41. Li, Y. et al. High-efficiency robust perovskite solar cells on ultrathin flexible substrates. Nat. Commun. 7, 1–10 (2016).
42. Binek, A. et al. Recycling perovskite solar cells to avoid lead waste. ACS Appl. Mater. Interfaces 8, 12881–12886 (2016).10.1021/acsami.6b03767 ↗
43. Zhang, J., Gao, X., Deng, Y., Zha, Y. & Yuan, C. Comparison of life cycle environmental impacts of different perovskite solar cell systems. Sol. Energy Mater. Sol. Cells 166, 9–17 (2017).10.1016/j.solmat.2017.03.008 ↗
44. Yang, Q., Fukuzumi, H., Saito, T., Isogai, A. & Zhang, L. Transparent cellulose films with high gas barrier properties fabricated from aqueous alkali/urea solutions. Biomacromolecules 12, 2766–2771 (2011).10.1021/bm200766v ↗
45. Cheng, T., Zhang, Y.-Z., Zhang, J.-D., Lai, W.-Y. & Huang, W. High-performance free-standing PEDOT:PSS electrodes for flexible and transparent all-solid-state supercapacitors. J. Mater. Chem. A 4, 10493–10499 (2016).10.1039/C6TA03537J ↗
46. Bi, C. et al. Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells. Nat. Commun. 6, 1–7 (2015).
47. Kim, H., Lim, K.-G. & Lee, T.-W. Planar heterojunction organometal halide perovskite solar cells: roles of interfacial layers. Energy Environ. Sci. 9, 12–30 (2016).10.1039/C5EE02194D ↗
48. Jeon, N. J. et al. Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells. Nat. Mater. 13, 897–903 (2014).10.1038/nmat4014 ↗