Energy storage and thermodynamics of PNZST thick films with coexisting antiferroelectric and ferroelectric phases
Source abstract
Abstract
Abstract Pb 0.99 Nb 0.02 (Zr 0.85 Sn 0.13 Ti 0.02 )O 3 (PNZST) antiferroelectric (AFE) thick films are successfully deposited on silicon‐based Pt and LaNiO 3 electrodes by a sol‐gel method. The coexistence of ferroelectric (FE) and AFE phases are revealed in PNZST films by XRD, electric‐induced hysteresis loops, dielectric, and leakage current properties. Comparing with PNZST/Pt film, larger recoverable energy density and efficiency are obtained in PNZST/LaNiO 3 film due to the lower FE phase proportion. It is analyzed and demonstrated by a thermodynamic model of AFE and FE coexistence system. In addition, the fatigue behaviors of both AFE films are also affected by the proportion of the coexisting FE phase. PNZST/LaNiO 3 film exhibits good fatigue resistance on energy storage even after 10 10 switching cycles, which is attractive to pulsed power applications.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Dielectric materials and actuators
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Mechanical and Materials Engineering North China University of Technology Beijing China
School of Science Beijing University of Chemical Technology Beijing China
Department of Materials Science and Engineering University of Sheffield Sheffield UK
Funding
National Natural Science Foundation of China · Natural Science Foundation of Beijing Municipality
References (40)
Show source-provided references
1. 10.1111/jace.1649610.1111/jace.16496 ↗
2. 10.1111/jace.1676110.1111/jace.16761 ↗
3. 10.1002/adfm.20180732110.1002/adfm.201807321 ↗
4. 10.1039/C9TA02149C10.1039/C9TA02149C ↗
5. 10.1016/j.actamat.2017.12.04810.1016/j.actamat.2017.12.048 ↗
6. 10.1039/C9NR10616B10.1039/C9NR10616B ↗
7. 10.1016/j.ceramint.2019.11.12310.1016/j.ceramint.2019.11.123 ↗
8. 10.1111/jace.1640810.1111/jace.16408 ↗
9. 10.1016/j.jeurceramsoc.2019.11.06310.1016/j.jeurceramsoc.2019.11.063 ↗
10. 10.1016/j.ceramint.2015.09.06710.1016/j.ceramint.2015.09.067 ↗
11. 10.1016/j.nanoen.2018.03.00310.1016/j.nanoen.2018.03.003 ↗
12. 10.1016/j.ceramint.2019.02.09810.1016/j.ceramint.2019.02.098 ↗
13. 10.1063/1.472014610.1063/1.4720146 ↗
14. 10.1063/1.283102310.1063/1.2831023 ↗
15. 10.1039/C9TC02172H10.1039/C9TC02172H ↗
16. 10.1016/j.jeurceramsoc.2020.01.04910.1016/j.jeurceramsoc.2020.01.049 ↗
17. 10.1063/1.480279410.1063/1.4802794 ↗
18. 10.1007/s10971-015-3948-110.1007/s10971-015-3948-1 ↗
19. 10.1016/j.jallcom.2010.11.10910.1016/j.jallcom.2010.11.109 ↗
20. 10.1088/1361-6463/ab140a10.1088/1361-6463/ab140a ↗
21. 10.1111/jace.1638010.1111/jace.16380 ↗
22. 10.1088/1361-6463/ab1b0810.1088/1361-6463/ab1b08 ↗
23. 10.1088/1361-6463/aaba6b10.1088/1361-6463/aaba6b ↗
24. 10.1063/1.474212810.1063/1.4742128 ↗
25. 10.1016/j.jcrysgro.2008.04.02510.1016/j.jcrysgro.2008.04.025 ↗
26. 10.1039/C9RA06551B10.1039/C9RA06551B ↗
27. 10.1016/j.solmat.2018.07.01310.1016/j.solmat.2018.07.013 ↗
28. 10.1002/adom.20180110510.1002/adom.201801105 ↗
29. 10.1109/T-SU.1966.2939410.1109/T-SU.1966.29394 ↗
30. 10.1016/j.jallcom.2008.10.13910.1016/j.jallcom.2008.10.139 ↗
31. 10.1016/j.pmatsci.2014.01.00210.1016/j.pmatsci.2014.01.002 ↗
32. 10.1007/s10853-009-3553-110.1007/s10853-009-3553-1 ↗
33. 10.1016/j.nanoen.2020.10494410.1016/j.nanoen.2020.104944 ↗
34. 10.1039/C8EE03287D10.1039/C8EE03287D ↗
35. 10.1039/C7TA09857J10.1039/C7TA09857J ↗
36. 10.1007/s10854-016-5679-710.1007/s10854-016-5679-7 ↗
37. 10.1063/1.501800310.1063/1.5018003 ↗
38. 10.1039/C9TA01299K10.1039/C9TA01299K ↗
39. 10.1209/0295-5075/107/1700210.1209/0295-5075/107/17002 ↗
40. 10.1063/1.365090610.1063/1.3650906 ↗