journal article·2014Open access

Fabrication of ferroelectric silicate KNbSi2O7 single crystal

Akira SAHASHI, Takuya HOSHINA, Hiroaki TAKEDA, Takaaki TSURUMI

Journal of the Ceramic Society of Japan· Volume 122· Issue 1426

Abstract

ABSi2O7 is a new ferroelectric material group of which ferroelectricity has been discovered recently. In this study, we focused on potassium niobate silicate (KNbSi2O7), which comprises displacement-type ferroelectric substance KNbO3 and high-covalence substance SiO2 in the structure. KNbSi2O7 single crystals with a size of 10 × 10 × 1 mm3 were fabricated by the process of glass crystallization, re-melting, and slow-cooling. The polarization-electric field (P-E) curve of the KNbSi2O7 crystal was evaluated and KNbSi2O7 evidently showed ferroelectricity in the direction of c axis. The value of the spontaneous polarization was estimated to 0.11 µC/cm2. The dielectric permittivity was approximately 15 for both a and c axes at 1 MHz, and this material was found to be a ferroelectric material with low dielectric permittivity.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Glass properties and applications · Acoustic Wave Resonator Technologies

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Affiliations

Nano-Phononics Lab., Graduate School of Science and Engineering, Tokyo Institute of Technology

References (19)

Show source-provided references
1. 1) M. C. Foster, D. J. Arbogast, P. Photinos, R. M. Nielson and S. C. Abrahams, J. Appl. Cryst., 32, 421–425 (1999).10.1107/S0021889898016501 ↗
2. 2) M. P. Crosnier, D. Guyomard, A. Verbaere, Y. Piffard and M. Tournoux, Ferroelectrics, 124, 61–66 (1991).10.1080/00150199108209415 ↗
3. 3) M. P. Crosnier, D. Guyomard, A. Verbaere, Y. Piffard and M. Tournoux, J. Solid State Chem., 98, 128–132 (1992).10.1016/0022-4596(92)90077-9 ↗
4. 4) M. C. Foster, D. J. Arbogast, P. Photinos, R. M. Nielson and S. C. Abrahams, J. Appl. Cryst., 32, 421–425 (1999).10.1107/S0021889898016501 ↗
5. 5) P. Pernice, A. Aronne, V. N. Sigaev, P. D. Sarkisov, V. I. Molev and S. Y. Stefanovich, J. Am. Ceram. Soc., 82, 3447–3452 (1999).10.1111/j.1151-2916.1999.tb02263.x ↗
6. 6) V. N. Sigaev, P. D. Sarkisov, M. V. Kupriyanova, Y. A. Spiridonov, E. V. Lopatina, S. Y. Stefanovich, V. I. Molev, P. Pernice and A. Aronne, Glass Phys. Chem., 27, 497–503 (2001).10.1023/A:1013290023550 ↗
7. 7) H. Tanaka, M. Yamamoto, Y. Takahashi, Y. Benino, T. Fujiwara and T. Komatsu, Opt. Mater., 22, 71–79 (2003).10.1016/S0925-3467(02)00242-2 ↗
8. 8) V. N. Sigaev, P. D. Sarkisov and S. S. Sukhov, Glass Ceram., 60, 305–308 (2003).10.1023/B:GLAC.0000008232.88829.01 ↗
9. 9) D. E. Vernacotola and J. E. Shelby, Phys. Chem. Glasses, 35, 153–159 (1994).
10. 10) V. N. Sigaev, P. D. Sarkisov, S. Y. Stefanovich, P. Pernice and A. Aronne, Ferroelectrics, 233, 165–185 (1999).10.1080/00150199908018620 ↗
11. 11) P. Pernice, A. Aronne, V. Sigaev and M. Kupriyanova, J. Non-Cryst. Solids, 275, 216–224 (2000).10.1016/S0022-3093(00)00258-1 ↗
12. 12) A. Aronne, V. N. Sigaev, P. Pernice, E. Fanelli and L. Z. Usmanova, J. Non-Cryst. Solids, 337, 121–129 (2004).10.1016/j.jnoncrysol.2004.03.120 ↗
13. 13) I. P. Alekseeva, V. V. Golubkov, O. S. Dymshits, A. A. Zhilin, V. I. Petrov and M. Y. Tsenter, Glass Phys. Chem., 30, 311–320 (2004).10.1023/B:GPAC.0000038702.00600.11 ↗
14. 14) A. Aronne, V. N. Sigaev, B. Champagnon, E. Fanelli, V. Califano, L. Z. Usmanova and P. Pernice, J. Non-Cryst. Solids, 351, 3610–3618 (2005).10.1016/j.jnoncrysol.2005.09.019 ↗
15. 15) V. N. Sigaev, S. S. Sukhov, P. D. Sarkisov, S. Y. Stefanovich, P. Pernice, A. Aronne and I. Gregora, Ferroelectrics, 318, 95–104 (2005).10.1080/00150190590966117 ↗
16. 16) R. Santos, L. F. Santos, R. M. Almeida, J. Deubener and L. Wondraczek, J. Solid State Chem., 183, 128–135 (2010).10.1016/j.jssc.2009.10.031 ↗
17. 17) E. Fanelli, P. Pernice, M. Xiao, A. Aronne and V. N. Sigaev, J. Mater. Sci. Technol., 27, 189–192 (2011).10.1016/S1005-0302(11)60047-9 ↗
18. 18) T. Lehnert, J. Adam and M. Veith, J. Appl. Phys., 106, 064108 (2009).10.1063/1.3223323 ↗
19. 19) Y. Noguchi, T. Matsumoto and M. Miyayama, Jpn. J. Appl. Phys., 44, L570–L572 (2005).10.1143/JJAP.44.L570 ↗