journal article·2024-10-21Open access

Structure and Properties of Thin Films Prepared on Flexible Substrates from SnCl4-Derived Solutions

Elena A. Dmitriyeva, Bedelbek M. Nurbaev, Ekaterina A. Bondar, Anastasiya S. Kovalenko, Anton M. Nikolaev, Olga A. Shilova

Coatings· Volume 14· Issue 10

Abstract

Thin transparent films of SnO2 were obtained from aqueous–alcohol solutions of SnCl4 on a flexible polyethylene terephthalate (PET) substrate by spray pyrolysis at 100 °C. The influence of the addition of aqueous ammonia to the film-forming solution on the different properties has been studied. Properties studied include surface morphology, phase composition and transparency of the formed films and the crystallization processes and band gap of the film material. It was found that the addition of aqueous ammonia causes the formation of skeletal crystals (NH4)2[SnCl6] with a perovskite structure in the film structure. The resulting films are promising for use in the technology of manufacturing flexible solar cells.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Physics and Technology, Satbayev University, Ibragimov 11, Almaty 050013, Kazakhstan

Branch of the Petersburg Nuclear Physics Institute named by B.P. Konstantinov of NRC «Kurchatov Institute»—Institute of Silicate Chemistry (Branch of the National Research Center “Kurchatov Institute”–PNPI–ISC), Saint-Petersburg 193312, Russia

Basic Department of Nanotechnology and Nanomaterials in Radioelectronics, Saint-Petersburg Electrotechnical University “LETI”, Saint-Petersburg 193312, Russia

Funding

Committee of Science of the Ministry of Science and Higher Education of the Republic of Kazakhstan

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