journal article·2023-09-17Open access

Reproducible Preparation of Thin Graphene Films Using a Green and Efficient Liquid-Phase Exfoliation Method for Applications in Photovoltaics

Ahmed Adel A. Abdelazeez, Amira Ben Gouider Trabelsi, Fatemah. H. Alkallas, Salem AlFaify, Mohd. Shkir, Tahani A. Alrebdi, Kholoud S. Almugren, Feodor V. Kusmatsev, Mohamed Rabia

Coatings· Volume 13· Issue 9

Abstract

This paper presents an innovative, cost-effective, and environmentally sustainable approach to producing high-quality graphene nanosheets (G-NSs) on a large scale. Particularly, we have achieved a remarkable graphene material, expertly dissolved in ethanol at an impressive concentration of 0.7 mg/mL, using a cutting-edge electrophoretic deposition method on an ITO/PET surface. This achievement holds great promise for a wide range of photovoltaic applications. The G-NSs were rigorously analyzed using advanced techniques, including FESEM, EDAX elemental mapping, X-ray diffraction (XRD), and Raman analysis. This comprehensive examination yielded a significant discovery: the thickness of the deposited films profoundly influences the material’s interaction with photons. This finding positions the synthesized graphene material as a game changer in the field of light detection sensors, with the potential to revolutionize the landscape of optoelectronics.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Graphene research and applications · Quantum Dots Synthesis And Properties · Graphene and Nanomaterials Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Nanoscale Science, Chemistry Department, University of North Carolina at Charlotte, Charlotte, NC 28223, USA

State Key Lab of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China

Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia

Advanced Functional Materials & Optoelectronic Laboratory (AFMOL), Department of Physics, Faculty of Science, King Khalid University, Abha 61413, Saudi Arabia

Department of Chemistry and University Centre for Research & Development, Chandigarh University, Mohali 140413, Punjab, India

Department of Physics, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab Emirates

Nanophotonics and Applications Lab, Physics Department, Faculty of Science, Beni-Suef University, Beni-Suef 62514, Egypt

Nanomaterials Science Research Laboratory, Chemistry Department, Faculty of Science, Beni-Suef University, Beni-Suef 62514, Egypt

Funding

Princess Nourah bint Abdulrahman University

References (53)

Show source-provided references
1. The rise of graphene, Nanoscience and technology: A collection of reviews
2. Two-dimensional nanosheets produced by liquid exfoliation of layered materials10.1126/science.1194975 ↗
3. Graphene and related two-dimensional materials: Structure-property relationships for electronics and optoelectronics10.1063/1.4983646 ↗
4. Theoretical investigations of optical origins of fluorescent graphene quantum dots
6. Solid-state decomposition of silicon carbide for growing ultra-thin heteroepitaxial graphite films10.1063/1.1498962 ↗
7. Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics10.1021/jp040650f ↗
8. Electronic confinement and coherence in patterned epitaxial graphene10.1126/science.1125925 ↗
9. An introduction to the chemistry of graphene10.1039/C5CP05212B ↗
10. Processable aqueous dispersions of graphene nanosheets10.1038/nnano.2007.451 ↗
11. Water-soluble graphene covalently functionalized by biocompatible poly-L-lysine10.1021/la903265p ↗
12. Liquid-Phase Exfoliation of Nanotubes and Graphene10.1002/adfm.200901640 ↗
13. High-yield production of graphene by liquid-phase exfoliation of graphite10.1038/nnano.2008.215 ↗
14. Verification of experimental results with simulation on production of few-layer graphene by liquid-phase exfoliation utilizing sonication10.1038/s41598-022-10971-w ↗
15. Liquid-Based Exfoliation of Black Phosphorus into Phosphorene and Its Application for Energy Storage Devices10.1002/sstr.202000148 ↗
16. Single-step exfoliation of black phosphorus and deposition of phosphorene via bipolar electrochemistry for capacitive energy storage application10.1039/C9TA09641H ↗
17. Dispersion of graphene in ethanol by sonication10.1016/j.matpr.2020.06.441 ↗
18. Vacacela Gomez, C., Tene, T., Guevara, M., Tubon Usca, G., Colcha, D., Brito, H., Molina, R., Bellucci, S., and Tavolaro, A. (2019). Preparation of few-layer graphene dispersions from hydrothermally expanded graphite. Appl. Sci., 9.10.3390/app9122539 ↗
19. Liquid-phase exfoliated graphene self-assembled films: Low-frequency noise and thermal-electric characterization10.1016/j.apsusc.2016.01.115 ↗
20. Superior dispersion of highly reduced graphene oxide in N, N-dimethylformamide10.1016/j.jcis.2012.03.026 ↗
21. The effect of heat treatment on formation of graphene thin films from graphene oxide nanosheets10.1016/j.carbon.2009.09.069 ↗
22. Graphene oxide hole injection layer for high-efficiency polymer light-emitting diodes by using electrophoretic deposition and electrical reduction10.1016/j.carbon.2015.07.049 ↗
23. Aqueous electrophoretic deposition in asymmetric AC electric fields (AC–EPD)10.1016/j.elecom.2008.10.028 ↗
24. An interleaved porous laminate composed of reduced graphene oxide sheets and carbon black spacers by in situ electrophoretic deposition10.1039/C3RA45979A ↗
25. Laser-assisted simultaneous patterning and transferring of graphene10.1021/jp309382w ↗
26. From Materials to Devices: Graphene toward Practical Applications10.1002/smtd.202200671 ↗
27. Graphite/Rolled Graphene Oxide/Carbon Nanotube Photoelectrode for Water Splitting of Exhaust Car Solution10.1002/er.5501 ↗
28. Towards new graphene materials: Doped graphene sheets and nanoribbons10.1016/j.matlet.2012.04.033 ↗
29. Vibrational properties of graphene and graphene layers10.1002/jrs.2321 ↗
30. Balandin, Heat conduction in graphene: Experimental study and theoretical interpretation10.1088/1367-2630/11/9/095012 ↗
31. Facile and Safe Graphene Preparation on Solution Based Platform10.1016/j.jiec.2013.11.022 ↗
32. Efficient Photoselectrochemical Hydrogen Production Utilizing of APbI3 (A = Na, Cs, and Li) Perovskites Nanorods10.1002/er.6326 ↗
33. Successful 2D MoS2 Nanosheets Synthesis with SnSe Grid-like Nanoparticles: Photoelectrochemical Hydrogen Generation and Solar Cell Applications10.1016/j.solener.2022.10.058 ↗
34. Alkallas, F.H., Elsayed, A.M., Trabelsi, A.B.G., and Rabia, M. (2023). Quantum Dot Supernova-like-Shaped Arsenic (III) Sul-fide-Oxide/Polypyrrole Thin Film for Optoelectronic Applications in a Wide Optical Range from Ultraviolet to In-frared. Catalysts, 13.10.3390/catal13091274 ↗
35. Preparation and Characterization of Polyaniline and Ag/Polyaniline Composite Nanoporous Particles and Their Antimicrobial Activities10.1007/s10924-017-0937-1 ↗
36. Abdelazeez, A.A.A., Hadia, N.M.A., Mourad, A.H.I., El-Fatah, G.A., Shaban, M., Ahmed, A.M., Alzaid, M., Cherupurakal, N., and Rabia, M. (2022). Effect of Au Plasmonic Material on Poly M-Toluidine for Photoelectrochemical Hydrogen Generation from Sewage Water. Polymers, 14.10.3390/polym14040768 ↗
37. Effect of Annealing Temperature on the Photoactivity of ITO/VO 2 (M)/Au Film Electrodes for Water Splitting10.1166/jnn.2020.17681 ↗
38. Transparent conductors composed of nanomaterials
39. Graphene oxide-based transparent conductive films10.1016/j.pmatsci.2014.03.004 ↗
40. Design and Application of Nanoporous Graphene Oxide Film for CO2, H2, and C2H2 Gases Sensing10.1016/j.jmrt.2019.07.064 ↗
41. Graphene as transparent electrode material for organic electronics10.1002/adma.201100304 ↗
42. Graphene photonics and optoelectronics10.1038/nphoton.2010.186 ↗
43. Graphene-based electrodes10.1002/adma.201201587 ↗
44. Gate tuning of high-performance InSe-based photodetectors using graphene electrodes10.1002/adom.201500190 ↗
45. Highly polarization-sensitive, broadband, self-powered photodetector based on graphene/PdSe2/germanium heterojunction10.1021/acsnano.9b03994 ↗
46. Self-powered photodetectors based on 2D materials10.1002/adom.201900765 ↗
47. Extraordinary photo response in two-dimensional In2Se3 nanosheets10.1021/nn405037s ↗
48. Morphological imperfections of epitaxial graphene: From a hindrance to the generation of new photo-responses in the visible domain10.1039/C6NR08999B ↗
49. Semiconductor saturable absorber mirrors (SESAM’s) for femtosecond to nanosecond pulse generation in solid-state lasers10.1109/2944.571743 ↗
50. Photon Drag Currents and Terahertz Generation in α-Sn/Ge Quantum Wells10.3390/nano12172892 ↗
51. Graphene–metamaterial photodetectors for integrated infrared sensing10.1021/acsphotonics.6b00226 ↗
52. A roadmap for graphene10.1038/nature11458 ↗
53. Electron quantum optics with beam splitters and waveguides in dirac matter10.1002/qute.202300112 ↗