journal article·2022-04-10Open access

Highly Efficient and Stable Eu3+-Doped CsPbBr3/Cs4PbBr6 Perovskites for White Light-Emitting Diodes

Song Wang, Yan Xu, Renjie Chen, Mengmeng Zhu, Muyi Wang, Mengmeng Cao, Yunpeng Liu, Haojie Ding, Shulan Zhang, Jueyao Bai, Jun Ren, Tongtong Xuan, Huili Li

Coatings· Volume 12· Issue 4

Abstract

All-inorganic halide perovskite nanomaterials have a high application potential in the field of display and lighting because of unique photoelectric properties. However, these materials suffer from problems related to poor water and thermal stabilities. In this study, green Eu3+-doped CsPbBr3/Cs4PbBr6 perovskite composites that were synthesized by a saturated recrystallization method at room temperature showed an enhanced photoluminescence quantum yield of 87% and superior water and thermal stabilities to that of undoped perovskites. Finally, green Eu3+-doped CsPbBr3/Cs4PbBr6 perovskite composites were fabricated into white light-emitting diodes (WLEDs) with a wide color gamut (124% of the National Television System Committee standard) and a high efficiency of 43.06 lm/W.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Luminescence Properties of Advanced Materials · Optical properties and cooling technologies in crystalline materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Engineering Research Center for Nanophotonics and Advanced Instrument, Ministry of Education, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China

Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen 361005, China

Shenzhen Research Institute of Xiamen University, Shenzhen 518000, China

Funding

Shanghai Municipal Natural Science Foundation · National Natural Science Foundation of China · Natural Science Foundation of Fujian Province · oint Institute of Advanced Science and Technology, East China Normal University, Shanghai 200062, People's Republic of China

References (43)

Show source-provided references
1. Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-Emitting Devices through the Interface Engineering with Perfluorinated lonomer10.1021/acs.nanolett.5b04959 ↗
2. Water-Assisted Size and Shape Control of CsPbBr3 Perovskite Nanocrystals10.1002/anie.201710869 ↗
3. Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX3)10.1002/adma.201570302 ↗
4. Computational Design of Functionalized Metal-Organic Framework Nodes for Catalysis10.1021/acscentsci.7b00500 ↗
5. Harnessing Defect-Tolerance at the Nanoscale: Highly Luminescent Lead Halide Perovskite Nanocrystals in Mesoporous Silica Matrixes10.1021/acs.nanolett.6b02688 ↗
6. Mesoporous Silica Particles Integrated with All-Inorganic CsPbBr3 Perovskite Quantum-Dot Nanocomposites (MP-PQDs) with High Stability and Wide Color Gamut Used for Backlight Display10.1002/anie.201603698 ↗
7. CsPbBr3 QD/AlOx Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat10.1002/anie.201703703 ↗
8. Low-Dimensional-Networked Metal Halide Perovskites: The Next Big Thing10.1021/acsenergylett.6b00705 ↗
9. Tunable CsPbBr3/Cs4PbBr6 phase transformation and their optical spectroscopic properties10.1039/C8DT00430G ↗
10. Cs4PbBr6/CsPbBr3 Nanocomposites for All-Inorganic Electroluminescent Perovskite Light-Emitting Diodes10.1021/acsanm.0c02274 ↗
11. Cs4PbBr6/CsPbBr3 perovskite composites for WLEDs: Pure white, high luminous efficiency and tunable color temperature10.1039/C9RA10183G ↗
12. CsPbBr3-Cs4PbBr6 composite nanocrystals for highly efficient pure green light emission10.1039/C9NR07096F ↗
13. Interlayer Determined Photoluminescence Excitation Properties of Cs-Rich and Pb-Rich Cs4PbBr6 Samples10.1021/acs.jpcc.1c01908 ↗
14. Fluorescent Phase-Pure Zero-Dimensional Perovskite-Related Cs4PbBr6 Microdisks: Synthesis and Single-Particle Imaging Study10.1021/acs.jpclett.7b02100 ↗
15. Solution-Grown CsPbBr3/Cs4PbBr6 Perovskite Nanocomposites: Toward Temperature-Insensitive Optical Gain
16. Pure Cs4PbBr6: Highly Luminescent Zero Dimensional Perovskite Solids10.1021/acsenergylett.6b00396 ↗
17. Highly Emissive Green Perovskite Nanocrystals in a Solid State Crystalline Matrix10.1002/adma.201605945 ↗
18. Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping10.1038/nature08777 ↗
19. Stabilizing Cesium Lead Halide Perovskite Lattice through Mn(II) Substitution for Air-Stable Light-Emitting Diodes10.1021/jacs.7b04000 ↗
20. Highly stable CsPbI3:Sr2+ nanocrystals with near-unity quantum yield enabling perovskite light-emitting diodes with an external quantum efficiency of 17.1%10.1016/j.nanoen.2021.106033 ↗
21. Ultrastable and highly efficient green-emitting perovskite quantum dot composites for Mini-LED displays or backlights10.1016/j.nanoen.2022.107003 ↗
22. White Lght Emission from the Tb3+/Eu3+ Co-doped All-inorganic Halide Perovskite Quantum Dots in Ambient Air
23. Theoretical study on the effect of the optical properties and electronic structure for the Bi-doped CsPbBr310.1088/1361-648X/ab6e90 ↗
24. Doping Lanthanide into Perovskite Nanocrystals: Highly Improved and Expanded Optical Properties10.1021/acs.nanolett.7b04575 ↗
25. Controllable and facile synthesis of CsPbBr3-Cs4PbBr6 perovskite composites in pure polar solvent10.1016/j.jcis.2018.11.041 ↗
26. Quantum Yields of Fluorescence of Plant Pigments10.1126/science.124.3222.585 ↗
27. Understanding Thermal and A-Thermal Trapping Processes in Lead Halide Perovskites Towards Effective Radiation Detection Schemes10.1002/adfm.202104879 ↗
28. Nanocrystalline structure control and tunable luminescence mechanism of Eu-doped CsPbBr3 quantum dot glass for WLEDs10.1039/D0NR01207F ↗
29. Enhanced multimodal luminescence and ultrahigh stability Eu3+-doped CsPbBr3 glasses for X-ray detection and imaging10.1364/PRJ.439744 ↗
30. Highly Resolved and Robust Dynamic X-Ray Imaging Using Perovskite Glass-Ceramic Scintillator with Reduced Light Scattering10.1002/advs.202003728 ↗
31. Super-Hydrophobic Cesium Lead Halide Perovskite Quantum Dot-Polymer Composites with High Stability and Luminescent Efficiency for Wide Color Gamut White Light-Emitting Diodes10.1021/acs.chemmater.8b04596 ↗
32. Intrinsic Lead Ion Emissions in Zero-Dimensional Cs4PbBr6 Nanocrystals10.1021/acsenergylett.7b01026 ↗
33. A Study of Eu Doping in Nanolayers of CsPbBr3 using Ab Initio Calculations to Understand f-f Transitions in Eu3+-Doped Nanocrystals for Light-Emitting Diodes10.1021/acsanm.0c00536 ↗
34. Stimulated emission from microcrystalline CsPbBr3 films: Edge emission versus surface emission10.1016/j.mseb.2006.11.002 ↗
35. The role of EuBr2 in modulating the crystallization and luminescence of caesium lead bromide10.1016/j.materresbull.2020.111191 ↗
36. Stability of the Eu2+ Dopant in CsPbBr3 Perovskites: A First-Principles Study10.1021/acs.jpcc.8b10261 ↗
37. Synthesis of thermally stable and highly luminescent spherical shaped ligand-free Cs4PbBr6 nanospheres with a single polar solvent10.1016/j.jlumin.2019.01.053 ↗
38. Temperature-Dependent Exciton and Trap-Related Photoluminescence of CdTe Quantum Dots Embedded in a NaCl Matrix: Implication in Thermometry10.1002/smll.201501984 ↗
39. Colloidal Nanocrystals Embedded in Macrocrystals: Robustness, Photostability, and Color Purity10.1021/nl3027444 ↗
40. Sodium chloride protected CdTe quantum dot based solid-state luminophores with high color quality and fluorescence efficiency10.1063/1.4820406 ↗
41. Photoluminescence Quantum Yield and Matrix-Induced Luminescence Enhancement of Colloidal Quantum Dots Embedded in Ionic Crystals10.1021/cm5009043 ↗
42. Cadmium-Doped Zinc Sulfide Shell as a Hole Injection Springboard for Red, Green, and Blue Quantum Dot Light-Emitting Diodes10.1002/advs.202104488 ↗
43. Alloyed Green-Emitting CdZnSeS/ZnS Quantum Dots with Dense Protective Layers for Stable Lighting and Display Applications10.1021/acsami.1c07647 ↗