journal article·2017-02-27Open access

Effect of Electrochemically Deposited MgO Coating on Printable Perovskite Solar Cell Performance

T. A. Peiris, Ajay Baranwal, Hiroyuki Kanda, Shouta Fukumoto, Shusaku Kanaya, Takeru Bessho, Ludmila Cojocaru, Tsutomu Miyasaka, Hiroshi Segawa, Seigo Ito

Coatings· Volume 7· Issue 3

Abstract

Herein, we studied the effect of MgO coating thickness on the performance of printable perovskite solar cells (PSCs) by varying the electrodeposition time of Mg(OH)2 on the fluorine-doped tin oxide (FTO)/TiO2 electrode. Electrodeposited Mg(OH)2 in the electrode was confirmed by energy dispersive X-ray (EDX) analysis and scanning electron microscopic (SEM) images. The performance of printable PSC structures on different deposition times of Mg(OH)2 was evaluated on the basis of their photocurrent density-voltage characteristics. The overall results confirmed that the insulating MgO coating has an adverse effect on the photovoltaic performance of the solid state printable PSCs. However, a marginal improvement in the device efficiency was obtained for the device made with the 30 s electrodeposited TiO2 electrode. We believe that this undesirable effect on the photovoltaic performance of the printable PSCs is due to the higher coverage of TiO2 by the insulating MgO layer attained by the electrodeposition technique.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan

Department of Materials and Synchrotron Radiation Engineering, Graduate School of Engineering, University of Hyogo, 2167 Shosha, Hyogo, Himeji 671-2280, Japan

Graduate School of Engineering, Toin University of Yokohama, Kanagawa, Yokohama 225-8503, Japan

Department of General Systems Studies, Graduate School of Arts and Science, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan

References (27)

Show source-provided references
1. NREL Best Research-Cell Efficiencies, Available online:http://www.nrel.gov/pv/assets/images/efficiency_chart.jpg.
2. Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells10.1021/ja809598r ↗
3. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites10.1126/science.1228604 ↗
4. Nickel oxide electrode interlayer in CH3NH3PbI3 perovskite/PCBM planar-heterojunction hybrid solar cells10.1002/adma.201306217 ↗
5. Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency10.1038/ncomms4834 ↗
6. A hole-conductor–free, fully printable mesoscopic perovskite solar cell with high stability10.1126/science.1254763 ↗
7. 100 °C Thermal Stability of Printable Perovskite Solar Cells Using Porous Carbon Counter Electrodes10.1002/cssc.201600933 ↗
8. Nanosheet-based printable perovskite solar cells10.1016/j.solmat.2016.09.043 ↗
9. Towards stable and commercially available perovskite solar cells10.1038/nenergy.2016.152 ↗
10. Retarding charge recombination in perovskite solar cells using ultrathin MgO-coated TiO2 nanoparticulate films10.1039/C4TA03684K ↗
11. Revealing and reducing the possible recombination loss within TiO2 compact layer by incorporating MgO layer in perovskite solar cells10.1016/j.solener.2016.07.019 ↗
12. Low-temperature processed meso-superstructured to thin-film perovskite solar cells10.1039/c3ee40810h ↗
13. Enhanced Performance of Flexible Dye-Sensitized Solar Cells: Electrodeposition of Mg(OH)2 on a Nanocrystalline TiO2 Electrode10.1021/jp208267p ↗
14. Insights into mechanical compression and the enhancement in performance by Mg(OH)2 coating in flexible dye sensitized solar cells10.1039/c3cp53260g ↗
15. Taguchi, T., Zhang, X., Sutanto, I., Tokuhiro, K., and Rao, T.N. (2003). Improving the performance of solid-state dye-sensitized solar cell using MgO-coated TiO2 nanoporous film. Chem. Commun, 2480–2481.10.1039/b306118c ↗
16. Enhancement of the photoelectric performance of dye-sensitized solar cells by using a CaCO3-coated TiO2 nanoparticle film as an electrode10.1016/j.solmat.2006.03.013 ↗
17. Fully Printable Mesoscopic Perovskite Solar Cells with Organic Silane Self-Assembled Monolayer10.1021/ja5125594 ↗
18. Enhanced photovoltaic performance of CH3NH3PbI3 perovskite solar cells through interfacial engineering using self-assembling monolayer10.1021/ja512518r ↗
19. Performance enhancement of perovskite solar cells with Mg-doped TiO2 compact film as the hole-blocking layer10.1063/1.4916345 ↗
20. Efficient hole-blocking layer-free planar halide perovskite thin-film solar cells10.1038/ncomms7700 ↗
21. Compact layer free perovskite solar cells with 13.5% efficiency10.1021/ja508758k ↗
22. Spin-coated vs. electrodeposited Mn oxide films as water oxidation catalysts10.3390/ma9040296 ↗
23. Strengths and Advantages of Electrodeposition as a Semiconductor Growth Technique for Applications in Macroelectronic Devices10.1149/1.2128120 ↗
24. Influence of Calcination Temperature on the Photoelectrochemical and Photocatalytic Properties of Porous TiO2 Films Electrodeposited from Ti(IV)-Alkoxide Solution10.1021/jp803743k ↗
25. Highly textural lamellar mesostructured magnesium hydroxide via a cathodic electrodeposition process10.1016/j.matlet.2006.07.172 ↗
26. Formation mechanism for planes (011) and (001) oriented Mg(OH)2 films electrodeposited on SnO2 coating glass10.1039/c0ce00728e ↗
27. Mg(OH)2 supported nanoscale zero valent iron enhancing the removal of Pb(II) from aqueous solution10.1021/am509184e ↗