Fabrication and Characterization of P-Type Semiconducting Copper Oxide-Based Thin-Film Photoelectrodes for Solar Water Splitting
Source abstract
Abstract
Solar light-driven hydrogen by photocatalytic water splitting over a semiconductor photoelectrode has been considered a promising green energy carrier. P-type semiconducting copper oxides (Cu2O and CuO) have attracted remarkable attention as an efficient photocathode for photoelectrochemical (PEC) water splitting because of their high solar absorptivity and optical band gaps. In this study, CuO thin films were prepared using the sol-gel spin coating method to investigate the effects of aging time and layer dependency. Electrodeposition was also applied to fabricate Cu2O thin films. Cu2O thin films annealed at 300 °C are a hetero-phase system composed of Cu2O and CuO, while those at 400 °C are fully oxidized to CuO. Thin films are characterized using atomic force microscopy (AFM), scanning electron microscopy (SEM), ultraviolet-visible spectroscopy (UV-VIS), Fourier transform infrared spectroscopy (FTIR), spectroscopic ellipsometry (SE), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman microscopy. The hetero-phase thin films increase the photoconversion efficiency compared to Cu2O. Fully oxidized thin films annealed at 400 °C exhibit a higher efficiency than the hetero-phase thin film. We also verified that CuO thin films fabricated using electrodeposition show slightly higher efficiency than the spin coating method. The highest photocurrent of 1.1 mA/cm2 at 0.10 V versus RHE was measured for the fully oxidized CuO thin film under one-sun AM1.5G illumination. This study demonstrates a practical method to fabricate durable thin films with efficient optical and photocatalytic properties.
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Research context
OpenAlex topics: Copper-based nanomaterials and applications · ZnO doping and properties · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Photonics, National Yang Ming Chiao Tung University, Tainan 71150, Taiwan
Clean Energy Conversion Research Center, Institute for Advanced Engineering, Yongin 17180, Korea
Funding
Ministry of Science and Technology of Taiwan · Ministry of SMEs and Startups
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