journal article·2022-04-25Open access

An In-Depth Analysis of CdTe Thin-Film Deposition on Ultra-Thin Glass Substrates via Close-Spaced Sublimation (CSS)

Nowshad Amin, Mohammad Rezaul Karim, Zeid Abdullah ALOthman

Coatings· Volume 12· Issue 5

Abstract

This study evaluated the impact of the deposition pressure on the formation of cadmium telluride (CdTe) thin films on ultra-thin (100 µm) Schott glass substrate at high temperature (T > 450 °C) by Close-Spaced Sublimation (CSS) technique. CdTe thin films were grown under the pressure range of 1 Torr to 200 Torr to explore the impact of deposition pressure on CdTe thin-film properties. The microstructural, compositional and optoelectrical characteristics were examined. X-ray Diffraction (XRD) analysis revealed the cubic phase crystallite CdTe films with (111) preferential orientation. Scanning Electron Microscopy (SEM) demonstrated that the CdTe morphology and grain size could be regulated via the deposition pressure, whereby maximum grain growth was detected at low pressure (1–5 Torr). The thickness of CdTe films was reduced from 6 µm to 1.5 µm with the rise in deposition pressure. Moreover, the optical direct energy gap was derived in the range of 1.65–1.69 eV for the pressure value of 200 Torr to 1 Torr. Carrier density and resistivity were found to be in the order of 1013 cm−3 and 104 Ω cm, respectively. The experimental results suggest that the pressure range of 1–5 Torr may be ideal for CSS-grown CdTe films on flexible ultra-thin glass (UTG) substrates.
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Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Advanced Semiconductor Detectors and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Engineering, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Selangor, Malaysia

Institute of Sustainable Energy, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Selangor, Malaysia

Center of Excellence for Research in Engineering Materials (CEREM), Deanship of Scientific Research (DSR), College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia

K.A.CARE Energy Research and Innovation Center, Riyadh 11451, Saudi Arabia

Chemistry Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia

Funding

King Abdulaziz City for Science and Technology

References (60)

Show source-provided references
1. Fabrication of high efficiency sputtered CdS: O/CdTe thin film solar cells from window/absorber layer growth optimization in magnetron sputtering10.1016/j.solmat.2017.08.020 ↗
2. Influence of deposition time in CdTe thin film properties grown by Close-Spaced Sublimation (CSS) for photovoltaic application10.1016/j.rinp.2019.102371 ↗
3. Past, present and future of the thin film CdTe/CdS solar cells10.1016/j.solener.2018.01.018 ↗
4. Lo, P.Y., Ding, J.M., Hu, J.P., Chan, Y.J., Garner, S., He, M., Lin, J., Li, X., Sorensen, M., and Li, J. (2011). 29.2: Flexible glass substrates for organic TFT active matrix electrophoretic displays. SID Symposium Digest of Technical Papers, Blackwell Publishing Ltd.10.1889/1.3621331 ↗
5. Amin, N., and Rahman, K.S. (2017). Close-Spaced Sublimation (CSS): A Low-Cost, High-Yield Deposition System for Cadmium Telluride (CdTe) Thin Film Solar Cells. Mod. Technol. Creat. Thin-Film. Syst. Coat., 361.10.5772/66040 ↗
6. The growth of CdTe thin film by close space sublimation system10.1002/pssa.200306691 ↗
7. Influence of grain boundary scattering on the electrical properties of platinum nanofilms10.1063/1.2338885 ↗
8. Control of grain size in sublimation-grown CdTe, and the improvement in performance of devices with systematically increased grain size10.1016/j.solmat.2010.02.034 ↗
9. Influence of deposition parameters on the properties of CdTe films deposited by close spaced sublimation10.1590/S1516-14392006000100010 ↗
10. Large grain size CdTe films grown on glass substrates10.1063/1.340254 ↗
11. Effect of bending test on the performance of CdTe solar cells on flexible ultra-thin glass produced by MOCVD10.1016/j.solmat.2020.110552 ↗
12. 14%-efficient flexible CdTe solar cells on ultra-thin glass substrates10.1063/1.4870834 ↗
13. Effect of electron irradiation on the properties of CdTe/CdS solar cells10.1016/j.solmat.2007.12.002 ↗
14. Lateral heterojunction photodetector consisting of molecular organic and colloidal quantum dot thin films10.1063/1.3075577 ↗
15. Stress in thin films and coatings: Current status, challenges, and prospects10.1116/1.5011790 ↗
16. Bergman, T.L., Incropera, F.P., DeWitt, D.P., and Lavine, A.S. (2011). Fundamentals of Heat and Mass Transfer, John Wiley & Sons.
17. Highly efficient CdS/CdTe solar cells investigated by cathodoluminescence spectroscopy10.4028/www.scientific.net/SSP.78-79.111 ↗
18. Diffusion length in CdTe by measurement of photovoltage spectra in CdS/CdTe solar cells10.1063/1.1332418 ↗
19. Physical basis for the design of CdS/CdTe thin film solar cells10.1016/j.solmat.2005.04.004 ↗
20. Physics and chemistry of CdTe/CdS thin film heterojunction photovoltaic devices: Fundamental and critical aspects10.1039/C3EE41981A ↗
21. Application of composition controlled nickel-alloyed iron sulfide pyrite nanocrystal thin films as the hole transport layer in cadmium telluride solar cells10.1039/C7TC00948H ↗
22. Oxygen incorporation into CdS/CdTe thin film solar cells10.1007/s11082-015-0122-5 ↗
23. Salavei, A., Artegiani, E., Piccinelli, F., Di Mare, S., Menossi, D., Bosio, A., Romeo, N., and Romeo, A. (2015, January 14–18). Flexible CdTe solar cells on polyimide and flexible glass substrates. Proceedings of the 31st European Photovoltaic Solar Energy Conference, Hamburg, Germany.
24. Raman scattering study of the properties and removal of excess Te on CdTe surfaces10.1063/1.95367 ↗
25. Thermal treatment effect on structural features of mechano-synthesized fluorapatite-titania nanocomposite: A comparative study10.1007/s40145-014-0090-4 ↗
26. Hodges, D.R., Palekis, V., Bhandaru, S., Singh, K., Morel, D.L., and Stefanakos, L. (2009). Mechanical properties and adhesion of CdTe/CdS thin film solar cells deposited on flexible foil substrates. MRS Proc., 1165.10.1557/PROC-1165-M02-09 ↗
27. Optimization of bending durability of Ti-ZnO thin films on flexible glass substrates with highly enhanced optoelectronic characteristics by atomic layer deposition10.7567/1347-4065/ab1cf4 ↗
28. Mechanistic study on highly crystalline (002) plane bounded ZnO nanofilms prepared via direct current magnetron sputtering10.1016/j.matlet.2015.08.067 ↗
29. Characterization of nanostructured CdTe synthesized by solid state microwave-plasma process
30. Impact of CdTe thin film thickness in ZnxCd1− xS/CdTe solar cell by RF sputtering10.1016/j.solener.2019.01.019 ↗
31. Influence of substrate bias and post-deposition Cl treatment on CdTe film grown by RF magnetron sputtering for solar cells10.1039/c3ra44831b ↗
32. Gessert, T., and Ali, S. (2012). 1.19-cadmium telluride photovoltaic thin film: CdTe. Comprehensive Renewable Energy, Elsevier.10.1016/B978-0-08-087872-0.00122-0 ↗
33. Early stage growth mechanisms of CdTe thin films deposited by close space sublimation for solar cells10.1016/j.solmat.2011.05.002 ↗
34. Effect of Annealing on the density of defects in epitaxial CdTe (211)/GaAs10.1007/s11664-018-6352-0 ↗
35. Influence of the CdCl2 Solution Concentration on the Properties of CdTe Thin Films
36. Garner, S.M. (2017). Flexible Glass: Enabling Thin, Lightweight, and Flexible Electronics, John Wiley & Sons.10.1002/9781118946404 ↗
37. Direct observation of electrical properties of grain boundaries in sputter-deposited CdTe using scan-probe microwave reflectivity based capacitance measurements10.1063/1.4932952 ↗
38. Losses due to polycrystallinity in thin-film solar cells10.1016/S0927-0248(98)00045-2 ↗
40. Temperature difference in close-spaced sublimation (CSS) growth of CdTe thin film on ultra-thin glass substrate10.1016/j.rinp.2020.103213 ↗
41. CdCl2 treatment concentration evolution of physical properties correlation with surface morphology of CdTe thin films for solar cells10.1016/j.materresbull.2017.08.038 ↗
42. Baines, T., Papageorgiou, G., Hutter, O.S., Bowen, L., Durose, K., and Major, J.D. (2018). Self-Catalyzed CdTe Wires. Nanomaterials, 8.10.3390/nano8050274 ↗
43. Temperature dependence of the optical properties of CdTe10.1103/PhysRevB.56.4786 ↗
44. Effects of growth temperatures on the structural and optoelectronic properties of sputtered zinc sulfide thin films for solar cell applications10.1007/s11082-019-1994-6 ↗
45. Enhancement of optical and structural properties of vacuum evaporated CdTe thin films10.1016/j.matchemphys.2016.10.024 ↗
46. Influence of CdCl2 treatment on structural and optical properties of vacuum evaporated CdTe thin films10.1016/j.solmat.2005.04.006 ↗
47. Effects of substrate temperature and post-deposition anneal on properties of evaporated cadmium telluride films10.1016/j.tsf.2006.08.026 ↗
48. Effect of annealing on properties of electrochemically deposited CdTe thin films10.1016/j.jpcs.2006.09.018 ↗
49. Compounds. Effect of film thickness on microstructure parameters and optical constants of CdTe thin films10.1016/j.jallcom.2009.04.033 ↗
50. Copper iodide nanoparticles as a hole transport layer to CdTe photovoltaics: 5.5% efficient back-illuminated bifacial CdTe solar cells10.1016/j.solmat.2021.111451 ↗
51. Influence of temperature and pressure on CdTe: Ag thin film10.1080/02670844.2017.1401278 ↗
52. Impact of Urbach energy on open-circuit voltage deficit of thin-film solar cells10.1016/j.solmat.2020.110502 ↗
53. Energy band gap, intrinsic carrier concentration, and Fermi level of CdTe bulk crystal between 304 and 1067 K10.1063/1.2899087 ↗
54. Sze, S.M. (2008). Semiconductor Devices: Physics and Technology, John Wiley & Sons.
55. Properties of the CdCl2 air-annealed CSS CdTe thin films10.1016/j.egypro.2013.12.013 ↗
56. Robust passivation of CdSeTe based solar cells using reactively sputtered magnesium zinc oxide10.1016/j.solmat.2021.111388 ↗
57. Kumar, R., and Singh, R. (2021). Thermoelectricity and Advanced Thermoelectric Materials, Woodhead Publishing.
58. A new method for CdSexTe1-x band grading for high efficiency thin-absorber CdTe solar cells10.1016/j.solmat.2021.111081 ↗
59. Li, J., Chen, J., and Collins, R.W. (2008, January 11–16). Analysis of the dielectric functions of CdS and CdTe for grain size, stress, and temperature: Potentialities for on-line monitoring. Proceedings of the 2008 33rd IEEE Photovoltaic Specialists Conference, San Diego, CA, USA.10.1109/PVSC.2008.4922466 ↗
60. Real time spectroscopic ellipsometry of sputtered CdTe, CdS, and CdTe1− x Sx thin films for photovoltaic applications10.1002/pssa.200777892 ↗