journal article·2019-10-02Open access

Effect of Substrate Temperature on the Optical and Electrical Properties of Nitrogen-Doped NiO Thin Films

Yuan Tian, Lianguo Gong, Xueqian Qi, Yibiao Yang, Xiaodan Zhao

Coatings· Volume 9· Issue 10

Abstract

NiO is a widely used p-type semiconductor. The desired optical and electrical properties of NiO vary in different application fields. To modulate the properties of NiO, nitrogen (N)-doped NiO thin films were synthesized by reactive radio-frequency magnetron sputtering on ITO-coated glass substrates. The influence of substrate temperature on the properties of NiO was investigated. XRD studies indicated a cubic structure. With the increase of the substrate temperature, the average transmittance in the visible region gradually reduced from 90% to 50%. The bandgap energy narrowed from 3.5 to 3.08 eV. The intensity of the PL spectra weakened, and the electrical conductivity rose. Overall, changing the substrate temperature is an effective method to modulate the optical and electrical properties of N-doped NiO thin films.
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Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · ZnO doping and properties · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Lab of Advanced Transducers and Intelligent Control System, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024, China

First Design and Research Institute, China Wuzhou Engineering Group Corporation LTD, Beijing 100053, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Shanxi Province

References (35)

Show source-provided references
1. Preparation of transparent and semiconducting NiO films10.1016/S0042-207X(02)00299-3 ↗
2. Studies on electrochromic properties of nickel oxide thin films prepared by reactive sputtering10.1016/j.jallcom.2007.08.066 ↗
3. Opto-structural, electrical and electrochromic properties of crystalline nickel oxide thin films prepared by spray pyrolysis10.1016/S0921-4526(01)01024-9 ↗
4. The electrochromic properties of nickel oxide thin films prepared by chemical vapor deposition10.1016/0927-0248(93)90145-S ↗
5. High conductivity nickel oxide thin films by a facile sol-gel method10.1016/j.matlet.2012.10.109 ↗
6. Optoelectronic and electrochemical properties of nickel oxide (NiO) films deposited by DC reactive magnetron sputtering10.1016/j.physb.2008.08.014 ↗
7. Preparation and characterization of nanostructured nickel oxide thin films by spray pyrolysis10.1007/s13204-012-0152-2 ↗
8. Facile synthesis of porous-structured nickel oxide thin film by pulsed laser deposition
9. Nickel vacancy behavior in the electrical conductance of nonstoichiometric nickel oxide film10.1063/1.4742993 ↗
10. Effect of oxygen partial pressure on the electrical and optical properties of highly (200) oriented p-type Ni1−xO films by DC sputtering
11. Transparent conducting p-type NiO thin films prepared by magnetron sputtering10.1016/0040-6090(93)90636-4 ↗
12. Enhanced p-type conductivity and band gap narrowing in heavily Al doped NiO thin films deposited by RF magnetron sputtering
13. Nitrogen doping on NiO by reactive magnetron sputtering: A new pathway to dynamically tune the optical and electrical properties10.1016/j.apsusc.2017.02.229 ↗
14. Crystallography and domain walls in antiferromagnetic NiO crystals10.1063/1.1735895 ↗
15. Neutron and optical studies of domains in NiO10.1063/1.1735486 ↗
16. Electrochromic Properties of NiOx Films Deposited by DC Magnetron Sputtering10.1166/jnn.2018.15263 ↗
17. Combustion synthesis and characterization of NiO nanoparticles10.1016/j.mssp.2015.06.017 ↗
18. Metal oxides modified NiO catalysts for oxidative dehydro genation of ethaneto ethylene10.1016/j.cattod.2013.11.061 ↗
19. Structural and magnetic properties of nickel oxide nanopowder
20. Rapid microwave-assisted green synthesis of 3D hierarchical flower-shaped NiCo2O4 microsphere for high-performance supercapacitor10.1021/am404765y ↗
21. Nanostructured mesoporous nickel oxide thin films10.1088/0957-4484/18/11/115613 ↗
22. Visible-light photocatalysis in nitrogen-doped titanium oxides10.1126/science.1061051 ↗
23. Characterization of N, C-codoped TiO2 films prepared by reactive DC magnetron sputtering10.1016/j.apsusc.2009.09.027 ↗
24. Electron-, X-ray-, and ion-stimulated decomposition of nitrate salts10.1021/j100399a045 ↗
25. N-doped titanium monoxide nanoparticles with TiO rock-salt structure, low energy band gap, and visible light activity10.1021/cm100653q ↗
26. Modeling the reactive sputter deposition of N-doped TiO2 for application in dye-sensitized solar cells: Effect of the O2 flow rate on the substitutional N concentration10.1016/j.apsusc.2012.10.048 ↗
27. Electrical properties of Li-doped NiO thin films10.1016/j.jeurceramsoc.2009.05.041 ↗
28. Zhang, S., and Ali, N. (2007). Nanocomposite Thin Films and Coatings: Processing, Properties and Performances, Imperial College Press.10.1142/9781860949975 ↗
29. Ellipsometric and XPS characterization of transparent nickel oxide thin films deposited by reactive HiPIMS10.1016/j.surfcoat.2014.02.014 ↗
30. Synthesis of band-gap-reduced p-type ZnO films by Cu incorporation10.1063/1.2756517 ↗
31. TiO2 thin film electrodes: Correlation between photocatalytic activity and electrochemical properties10.1021/jp807655a ↗
32. Fogler, H.S. (1992). Elements of Chemical Reaction Engineering, Prentice-Hall. [2nd ed.].
33. Preparation and photoluminescence of ZnO complex structures with controlled morphology10.1016/j.matlet.2005.11.056 ↗
34. Vertically aligned and interconnected nickel oxide nanowalls fabricated by hydrothermal route10.1002/crat.200800583 ↗
35. Offer a novel method for size appraise of NiO nanoparticles by PL analysis: Synthesis by sonochemical method10.1016/j.jscs.2012.06.009 ↗