journal article·2019-10

Luminescent CH3NH3PbBr3/β‐Cyclodextrin Core/Shell Nanodots with Controlled Size and Ultrastability through Host‐Guest Interactions

Sihui Huang, Ting Zhang, Chunli Jiang, Ruijuan Qi, Chunhua Luo, Ye Chen, Hechun Lin, Jadranka Travas‐sejdic, Hui Peng

ChemNanoMat· Volume 5· Issue 10
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Abstract

Abstract Luminescent lead halide perovskite nanocrystals (LHP NCs) have attracted great attention. This work reports the synthesis of well‐defined core/shell structured CH3NH3PbBr3/β‐cyclodextrin (MAPbBr3/β‐CD) nanodots via host‐guest interaction between β‐cyclodextrin and hexylamine. The MAPbBr3/β‐CD nanodots show high luminescence with photoluminescence quantum yields (PLQYs) of 89.7% in solution and 38.0% in solid state. The MAPbBr3/β‐CD nanodots have superior stability in water, under heat and UV light exposure due to the formation of a β‐CD shell, which gives them great potential for optoelectrical and biological applications.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Layered Double Hydroxides Synthesis and Applications · Luminescence Properties of Advanced Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Polar Materials and Devices (MOE) Department of Electronics School of Physics and Electronic Science East China Normal University Shanghai 200241 China

Collaborative Innovation Center of Extreme Optics Shanxi University Taiyuan Shanxi 030006 China

National Laboratory for Infrared Physics Shanghai Institute of Technical Physics Chinese Academy of Sciences 500 Yu Tian Road Shanghai 200083 China

Polymer Electronics Research Centre (PERC) School of Chemical Sciences The University of Auckland 23 Symonds Street Auckland New Zealand

Funding

Natural Science Foundation of Shanghai · China Postdoctoral Science Foundation

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