journal article·2018-08

A Hybrid Organogel of a Low Band Gap Diketopyrrolopyrrole with PC71BM: Phase Separated Morphology and Enhanced Photoconductivity

Samrat Ghosh, Satyajit Das, Akinori Saeki, Vakayil K. Praveen, Shu Seki, Ayyappanpillai Ajayaghosh

ChemNanoMat· Volume 4· Issue 8
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Abstract

Abstract Organogels based on self‐assembled low band gap organic semiconductors are of great interest in the field of optoelectronics, although there are not many such systems known. Herein, we report a diketopyrrolopyrrole derivative (DPP‐Amide) with H‐bonding terminal groups that promote one‐dimensional (1D) assembly. This design leads to the formation of an organogelator having a low band gap of 1.5 eV, and near‐infrared (NIR) emission in the self‐assembled state. Furthermore, in the film state self‐assembled DPP‐Amide showed enhanced intrinsic photoconductivity when compared to isolated molecules upon the addition of different weight ratio of phenyl‐C71‐butyric acid methyl ester (PC71BM).
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Research context

OpenAlex topics: Supramolecular Self-Assembly in Materials · Polydiacetylene-based materials and applications · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Photosciences and Photonics Section Chemical Sciences and Technology Division CSIR-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST) Thiruvananthapuram- 695019 India

Academy of Scientific and Innovative Research (AcSIR) CSIR-NIIST Campus Thiruvananthapuram- 695019 India

Department of Applied Chemistry Graduate School of Engineering Osaka University 2-1 Yamadaoka, Suita Osaka 565-0871 Japan

Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku, Kyoto 615-8510 Japan

Funding

Department of Science and Technology, Government of India · Government of India for a Young Scientist Fellowship

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