Simultaneous Photoluminescence and Photothermal Investigation of Individual CH₃NH₃PbBr₃ Microcrystals

The photoluminescence (PL) of CH 3 NH 3 PbBr 3 (MAPbBr 3 ), from thin films to nanoparticles, has been widely studied, providing information about charge carrier dynamics. However, the other energy dissipative channel, nonradiative relaxation, has not been thoroughly investigated due to a lack of proper technology. In this work, we simultaneously investigated the PL and photothermal (PT) properties of single MAPbBr 3 microcrystals (MCs) by a home-built PL and PT microscope. In addition to the direct observation of the heterogeneity of the PL and PT images and kinetics of different MCs, we demonstrated the variation in the absorption of single MAPbBr 3 MCs, which was believed to be constant. We also proved that more absorbed energy dissipated from the nonradiative channel at higher heating power. These results show that PL and PT microscopy is an effective and convenient method to investigate the charge carrier behaviors of optoelectronic materials at the single particle level for a deep understanding of their photophysical processes.