journal article·2023-09-12

Interfacial Engineering of Two-Dimensional Metal–Organic Framework Thin Films for Biomimetic Photoadaptative Sensors

Haoyong Yang, Qihao Sun, Zhongquan Liao, Mike Hambsch, Xuerong Liu, Daheng Wu, Birgit Jost, Yuejun Zhang, Stefan C. B. Mannsfeld, Qunji Xue, Xinliang Feng, Xiaojian Zhu, Tao Zhang

Chemistry of Materials· Volume 35· Issue 17
Publisher page

Abstract

Porphyrin-based two-dimensional metal–organic frameworks (2D MOFs) are of high interest for extraordinary optoelectronic devices due to their well-ordered architecture and appealing photochemical properties. However, the high-throughput synthesis of 2D MOF thin films for device applications remains challenging because of the slow nucleation and crystallization process in classical interfacial synthesis. Here, we report a microwave-assisted interfacial methodology for the rapid construction (∼3 min) of highly crystalline 2D MOF thin films and demonstrate their promising potential in biomimetic optical sensors. The resultant 2D MOF films exhibit a lateral size of up to ∼23 cm 2 and controllable thickness in the range of 2–40 nm. The crystal domain size of the 2D MOF can be up to ∼4 μm, which boasts a long-range molecular ordering and appealing optical responsive properties. The 2D MOF films enable the fabrication of biomimetic optical sensors with light intensity-dependent autonomous photoadaptation without the assistance of voltage gating. Furthermore, an artificial machine vision system consisting of a 4 × 8 2D MOF-sensor array is developed to implement adaptive image recognition under bright- and dim-light stimuli with an accuracy of over 90%.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · 2D Materials and Applications · Nanoplatforms for cancer theranostics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Research Center for Advanced Interdisciplinary Sciences, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

CAS Key Laboratory of Magnetic Materials and Devices, Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Fraunhofer Institute for Ceramic Technologies and Systems (IKTS), Maria-Reiche-Strasse 2, 01109 Dresden, Germany

Center for Advancing Electronics Dresden (CFAED) and Faculty of Electrical and Computer Engineering, Technische Universität Dresden, 01062 Dresden, Germany

Faculty of Electrical Engineering and Computer Science, Ningbo University, Ningbo 315201, China

Faculty of Chemistry and Food Chemistry and Center for Advancing Electronics Dresden (CFAED), Technische Universität Dresden, 01062 Dresden, Germany

Funding

National Natural Science Foundation of China · Excellent Youth Foundation of Zhejiang Province

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