journal article·2021-10-12Open access

Near-Infrared-Emitting CdxHg1–xSe-Based Core/Shell Nanoplatelets

Andrei Mitrofanov, Anatol Prudnikau, Francesco Di Stasio, Nelli Weiß, René Hübner, Anna Maria Dominic, Konstantin B. L. Borchert, Vladimir Lesnyak, Alexander Eychmüller

Chemistry of Materials· Volume 33· Issue 19

Abstract

The anisotropy in semiconductor nanoplatelets (NPLs) is reflected in the anisotropy of their crystal structure and organic ligand shell, which can be used for creating new semiconductor heterostructures. This work demonstrates the synthesis of core/shell NPLs containing zero-dimensional (0D) CdxHg1–xSe domains embedded in CdSe NPLs via cation exchange. The strategy is based on the different accessibility of definite regions of the NPLs for incoming cations upon time-limited reaction conditions. The obtained heterostructures were successfully overcoated with a CdyZn1–yS shell preserving their two-dimensional (2D) morphology. The NPLs exhibit bright photoluminescence in the range of 700–1100 nm with quantum yields up to 55%, thus making them a prospective material for light-emitting applications in the near-infrared spectral range.
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Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · Nanocluster Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Physical Chemistry, TU Dresden, Zellescher Weg 19, 01069 Dresden, Germany

Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany

Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504 St. Petersburg, Russia

Photonic Nanomaterials Group, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy

Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf e.V., Bautzner Landstrasse 400, 01328 Dresden, Germany

Department of Chemistry and Food Chemistry, TU Dresden, 01069 Dresden, Germany

Funding

Bundesministerium f??r Bildung und Forschung · Deutscher Akademischer Austauschdienst · Deutsche Forschungsgemeinschaft · H2020 European Research Council

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