DataVXChemistry of MaterialsPaper
journal article·2016-12-27

LaMn3Ni2Mn2O12: An A- and B-Site Ordered Quadruple Perovskite with A-Site Tuning Orthogonal Spin Ordering

Yun-Yu Yin, Min Liu, Jian-Hong Dai, Xiao Wang, Long Zhou, Huibo Cao, Clarina dela Cruz, Chien-Te Chen, Yuanji Xu, Xi Shen, Richeng Yu, José Antonio Alonso, Angel Muñoz, Yi-Feng Yang, Changqing Jin, Zhiwei Hu, Youwen Long

Chemistry of Materials· Volume 28· Issue 24
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Source abstract

Abstract

A new oxide, LaMn 3 Ni 2 Mn 2 O 12, was prepared by high-pressure and high-temperature synthesis methods. The compound crystallizes in an AA′ 3 B 2 B′ 2 O 12 -type A-site and B-site ordered quadruple perovskite structure. The charge combination is confirmed to be LaMn 3+ 3 Ni 2+ 2 Mn 4+ 2 O 12, where La and Mn 3+ are 1:3 ordered at the A and A′ sites and the Ni 2+ and Mn 4+ are also distributed at the B and B′ sites in an orderly fashion in a rocksalt-type manner, respectively. A G-type antiferromagnetic ordering originating from the A′-site Mn 3+ sublattice is found to occur at T N ≈ 46 K. Subsequently, the spin coupling between the B-site Ni 2+ and B′-site Mn 4+ sublattices leads to an orthogonally ordered spin alignment with a net ferromagnetic component near T C ≈ 34 K. First-principles calculations demonstrate that the A′-site Mn 3+ spins play a crucial role in determining the spin structure of the B and B′ sites. This LaMn 3 Ni 2 Mn 2 O 12 provides a rare example that shows orthogonal spin ordering in the B and B′ sites assisted by ordered A-site magnetic ions in perovskite systems.
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Research context

Electronic materials

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Quantum Condensed Matter Division, Neutron Scattering Science Directorate, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States

National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan, ROC

Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, Madrid E-28049, Spain

Universidad Carlos III, Avenida Universidad 30, E-28911 Leganés-Madrid, Spain

Collaborative Innovation Center of Quantum Matter, Beijing 100190, China

Max Planck Institute for Chemical Physics of Solids, Dresden 01187, Germany

Funding

Ministry of Science and Technology of the People's Republic of China · Basic Energy Sciences · Ministerio de Economía y Competitividad · National Natural Science Foundation of China · Chinese Academy of Sciences

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