journal article·2010-02-09

Using Neutron Spin−Echo To Investigate Proton Dynamics in Proton-Conducting Perovskites

Maths Karlsson, Dennis Engberg, Mårten E. Björketun, Aleksandar Matic, Göran Wahnström, Per G. Sundell, Pedro Berastegui, Istaq Ahmed, Peter Falus, Bela Farago, Lars Börjesson, Sten Eriksson

Chemistry of Materials· Volume 22· Issue 3
Publisher page

Abstract

The intermediate scattering function, I(Q,t), of proton-conducting hydrated BaZr0.90Y0.10O2.95 is explored for temperatures in the range 473−650 K and momentum transfers Q = 0.15−0.3 Å−1. The exponential decay of I(Q,t) suggests that the long-range self-diffusion of protons, which occurs as a series of proton transfers between neighboring oxygens and reorientational motion of the −OH group in between such transfers, is observed.
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Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Solid-state spectroscopy and crystallography · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

European Spallation Source Scandinavia, Lund University, 221 00 Lund, Sweden

Department of Applied Physics, Chalmers University of Technology, 412 96 Göteborg, Sweden

Department of Inorganic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden

Department of Chemical and Biological Engineering, Chalmers University of Technology, 412 96 Göteborg, Sweden

Institut Laue-Langevin, 38042 Grenoble Cedex 9, France

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