journal article·2014-04-08

Large Thermoelectric Power Factor in Pr-Doped SrTiO3−δ Ceramics via Grain-Boundary-Induced Mobility Enhancement

Arash Mehdizadeh Dehkordi, Sriparna Bhattacharya, Taghi Darroudi, Jennifer W. Graff, Udo Schwingenschlögl, Husam N. Alshareef, Terry M. Tritt

Chemistry of Materials· Volume 26· Issue 7
Publisher page

Abstract

We report a novel synthesis strategy to prepare high-performance bulk polycrystalline Pr-doped SrTiO 3 ceramics. A large thermoelectric power factor of 1.3 W m –1 K –1 at 500 °C is achieved in these samples. In-depth investigations of the electronic transport and microstructure suggest that this significant improvement results from a substantial enhancement in carrier mobility originating from the formation of Pr-rich grain boundaries. This work provides new directions to higher performance oxide thermoelectrics as well as possibly other properties and applications of this broadly functional perovskite material.
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Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Ferroelectric and Piezoelectric Materials · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634, United States

Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634, United States

Electron Microscope Facility, Clemson Research Park, Clemson University, Clemson, South Carolina 29634, United States

King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

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