journal article·2010-05-25

Remarkable Oxygen Intake/Release Capability of BaYMn2O5+δ: Applications to Oxygen Storage Technologies

Teruki Motohashi, Taku Ueda, Yuji Masubuchi, Makoto Takiguchi, Tohru Setoyama, Kazunori Oshima, Shinichi Kikkawa

Chemistry of Materials· Volume 22· Issue 10
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Abstract

Here, we report the remarkable oxygen intake/release capability of a double perovskite BaYMn 2 O 5+δ . This oxide rapidly stores/releases a large amount of oxygen (>3.7 wt %) at moderate temperatures in a perfectly reversible manner. The oxygen intake/release behaviors of BaYMn 2 O 5+δ are clearly beyond those of any conventional oxides in terms of the magnitude and sharpness of the processes. It also appeared that this oxide exhibits a significant catalytic activity for flameless combustions of hydrocarbons, presumably owing to its oxygen-storage ability.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan

Mitsubishi Chemical Group, Science and Technology Research Center, Inc., Yokohama 227-8502, Japan

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