DataVXChemistry of MaterialsPaper
journal article·2023-02-28Open access

Monitoring the Formation of Nickel-Poor and Nickel-Rich Oxide Cathode Materials for Lithium-Ion Batteries with Synchrotron Radiation

Bixian Ying, Jack R. Fitzpatrick, Zhenjie Teng, Tianxiang Chen, Tsz Woon Benedict Lo, Vassilios Siozios, Claire A. Murray, Helen E. A. Brand, Sarah Day, Chiu C. Tang, Robert S. Weatherup, Michael Merz, Peter Nagel, Stefan Schuppler, Martin Winter, Karin Kleiner

Chemistry of Materials· Volume 35· Issue 4
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Source abstract

Abstract

High Resolution Image Download MS PowerPoint Slide The syntheses of Ni-poor (NCM111, LiNi 1/3 Co 1/3 Mn 1/3 O 2 ) and Ni-rich (NCM811 LiNi 0.8 Co 0.1 Mn 0.1 O 2 ) lithium transition-metal oxides (space group R 3̅m) from hydroxide precursors (Ni 1/3 Co 1/3 Mn 1/3 (OH) 2, Ni 0.8 Co 0.1 Mn 0.1 (OH) 2 ) are investigated using in situ synchrotron powder diffraction and near-edge X-ray absorption fine structure spectroscopy. The development of the layered structure of these two cathode materials proceeds via two utterly different reaction mechanisms. While the synthesis of NCM811 involves a rock salt-type intermediate phase, NCM111 reveals a layered structure throughout the entire synthesis. Moreover, the necessity and the impact of a preannealing step and a high-temperature holding step are discussed.
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Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

MEET, Battery Research Center, University of Muenster, Corrensstr. 46, 48149Münster, Germany

Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, White City Campus, 82 Wood Lane, W12 0BZLondon, U.K.

Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hunghom, 999077Kowloon, Hong Kong, China

Diamond Light Source Ltd, Harwell Science & Innovation Campus, Didcot, OX11 0DEOxfordshire, U.K.

Australian Synchrotron ANSTO, 800 Blackburn Rd., Clayton, 3168Victoria, Australia

Department of Materials, University of Oxford, Parks Road, OX1 3PHOxford, U.K.

Institute for Quantum Materials and Technologies, Karlsruhe Institute of Technology, 76021Karlsruhe, Germany

Karlsruhe Nano Micro Facility (KNMFi), Karlsruhe Institute of Technology (KIT), 76344Eggenstein-Leopoldshafen, Germany

Helmholtz-Institute Münster, Forschungszentrum Jülich GmbH, 48149Muenster, Germany

Funding

Bundesministerium f?r Bildung und Forschung · Diamond Light Source

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