Supramolecular Network Conducting the Formation of Uniaxially Oriented Molecular Crystal of Cyano Substituted Oligo(p-phenylene vinylene) and Its Amplified Spontaneous Emission (ASE) Behavior

The supramolecular interactions are of importance for inducing the molecular orientation and constructing functional materials with high performance. In this manuscript we report uniaxially oriented molecular crystal of a cyano substituted oligo( p -phenylene vinylene) 1,4-bis(α-cyano-4-diphenylaminostyryl)-2,5-diphenylbenzene (CNDPASDB) with high luminescence under the driving force of the three-dimensional supramolecular interaction networks. Amplified spontaneous emission (ASE) with a low threshold value of 30.5 kW/cm 2 was observed from a high-quality slab-like CNDPASDB crystal and verified by the variable pump stripe method. The net gain coefficient with 55 cm −1 is also measured. The tip of CNDPASDB crystal exhibits polarized self-waveguided emission due to the propagation of polarized light emitted from the uniaxially oriented CNDPASDB molecules along crystal surface.