LaSr₂AlO₅, a Versatile Host Compound for Ce³⁺-Based Yellow Phosphors: Structural Tuning of Optical Properties and Use in Solid-State White Lighting

Cerium-doped lanthanum strontium aluminum oxide LaSr 2 AlO 5:Ce 3+ has recently been identified by us as a viable yellow phosphor that in conjunction with a blue-emitting diode can be used in solid-state white lighting sources. In this study, we present the energy level structure relevant to the luminescence process within LaSr 2 AlO 5:Ce 3+, based on crystal structure determination by powder X-ray diffraction and the peak deconvolution of excitation and emission spectra. We also establish the versatility of the phosphor host LaSr 2 AlO 5 by examining isovalent substitutions of all three cation types in the structure; Gd or Tb for La, Ca or Ba for Sr, and B or Ga for Al. All the above cation substitutions/solid solution are achieved to the full extent except when Ca (for Sr) or B (for Al) are chosen as substituent. Optical properties of the prepared Ce 3+ phosphors are found to depend on the rare-earth metal−oxygen distances and the lattice ionicity. Among the compounds studied here, excitation maxima range between 435 and 453 nm and emission maxima between 552 and 577 nm, which are promising for delicate color control in InGaN-based blue-pumped, yellow-emitting phosphors for solid-state white lighting. Prototype light-emitting diodes have been fabricated by formulating various phosphor compositions obtained in this study, and their electroluminescence properties are presented.