Raman spectra and ferromagnetism of nanocrystalline Fe-doped Li0.43Nb0.57O3+

Abstract Nanocrystalline undoped LiNbO 3 and LiNbO 3 doped with x % Fe ( x =0.5, 1, 2, 3, 5) were synthesized via a combustion method. Fe-doped LiNbO 3 with a 1 mol% doping concentration exhibited a room-temperature ferromagnetism of 0.06 emu/g. There was an abrupt change in properties when the doping concentration of Fe reached 2 mol%, where the lattice contracted obviously and the saturation magnetization ( M s ) increased an order of magnitude to 0.275 emu/g; M s slightly increased to its maximum value of 1.18 emu/g when the doping concentration was further increased to 5 mol%. Raman spectra showed that the substitution of Li by Fe occurred at small doping concentrations and the substitution of Nb at the Nb site occurred at higher doping concentrations. The results suggest that Fe 3+ replaced Nb Li 4+ first and the weaker ferromagnetism is due to the minor fraction of Nb Li 4+ in LiNbO 3 . Then, Fe 3+ substituted Li + , resulting in large lattice distortion and much stronger spin coupling of Fe–Nb. Finally, the excess Fe 3+ started to replace Nb 5+ at the Nb sites, where the spin coupling of Fe–Nb is weaker than that at the Li site. An analysis of the experimental results suggests that the congruent Fe-doped LiNbO 3 is a promising room-temperature single-phase multiferroic material.