Synthesis and properties of lanthanum hexaaluminate ceramic La1−xCaxAl11−y−zMgyTizO18

Abstract The aim of the present work is to obtain ceramic materials with a hexagonal structure and high density, hardness and mechanical strength at lower synthesis temperature. Ceramic samples with nominal composition La 1− x Ca x Al 11− y − z Mg y Ti z O 18 ( x =0–1; y =0–3; z =0–3,5) are prepared. The samples are sintered at temperature 1500 °C by one-stage and two-stage ceramic technology. By X-ray diffraction and scanning electron microscopy, predominant phase LaAl 11 O 18 and second phases LaAlO 3 and α-Al 2 O 3 are identified. Ceramic materials are characterized with high physico-mechanical properties and may be find application for production of mill bodies and materials for immobilization of nuclear waste.