journal article·2008-05

Optical linearity and nonlinearity of ZnSe nanocrystals embedded in epoxy resin matrix investigated by Z-scan technique

Jianping Li, Minqiang Wang, Zhonghai Lin, Xiao Huo, Guangmei Zhai

Ceramics International· Volume 34· Issue 4
Publisher page

Abstract

The ZnSe nanocrystals were synthesized by hydrothermal method. Through mixed with epoxy resin in vacuum at high temperature environment, the nanocrystals embedded in an epoxy resin matrix structure were obtained. This nanocomposite sample was characterized by transmission electron microscope (TEM) and electron beam diffraction, showing the nanocrystals were dispersed homogeneously and their structures were zinc blende structure. The nanocomposite structure was also confirmed by the blue-shift of the absorption edge. The nonlinear refraction index and two-photon absorption (TPA) coefficient were measured by the Z-scan technique, using a single Gaussian beam of Nd:YAG laser (532 nm). The result shows that ZnSe nanocrystals embedded in epoxy resin matrix have higher nonlinear refraction index and lower TPA coefficient than that of bulk ZnSe.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nonlinear Optical Materials Studies · Quantum Dots Synthesis And Properties · Nonlinear Optical Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Interband absorption of light in a semiconductor sphere Sov
2. Quantum-size effects of interacting electrons and holes in semiconductor microcrystals with spherical shape10.1103/PhysRevB.38.9797 ↗
3. Theory of the linear and nonlinear optical properties of semiconductor microcrystallites10.1103/PhysRevB.35.8113 ↗
4. Theory of optically excited intrinsic semiconductor quantum dots10.1103/PhysRevB.42.1713 ↗
5. Non-resonant optical nonlinearities of semiconductor nanocrystals10.1080/000187398243537 ↗
6. Below-band-gap third-order optical nonlinearity of nanometer-size semiconductor crystallites10.1103/PhysRevLett.68.1200 ↗
7. Linear and non-linear optical properties of capped CdTe nanocrystals prepared by mechanical alloying10.1016/j.optmat.2004.06.005 ↗
8. Optical nonlinearity of Bi2O3 nanoparticles studied by Z-scan technique10.1063/1.366189 ↗
9. Preparation and optical properties of sol–gel derived ZnSe crystallites doped in glass films10.1063/1.355970 ↗
10. In situ growth and spectral characterization of zinc selenide nanocrystalline in silica xerogel10.1007/BF03184276 ↗
11. Low-temperature elemental-direct-reaction route to II-VI semiconductor nanocrystalline ZnSe and CdSe10.1021/ic0100424 ↗
12. Morphological stability and crystal structure of CVD-grown zinc selenide10.1007/BF00549871 ↗
13. Optical transmission of ZnSe crystals grown by solid phase recrystallization10.1016/S0022-0248(98)00773-8 ↗
14. Structural properties of ZnSe films grown by migration enhanced epitaxy10.1063/1.353035 ↗
15. Growth and excitonic properties of single fractional monolayer CdSe/ZnSe structures10.1063/1.367130 ↗
16. Electron–electron and electron–hole interactions in small semiconductor crystallites: The size dependence of the lowest excited electronic state10.1063/1.447218 ↗
17. Sensitive measurement of optical nonlinearities using a single beam10.1109/3.53394 ↗
18. Energy band-gap dependence of two-photon absorption10.1364/OL.10.000490 ↗
19. W. Laser-beam deflection measurements and modeling of pulsed laser ablation rate and near-surface plume densities in vacuum10.1007/s003400050866 ↗
20. Theoretical study on the closed-aperture Z-scan curves in the materials with nonlinear refraction and strong nonlinear absorption10.1016/S0030-4018(01)01406-7 ↗
21. Determination of bound-electronic and free-carrier nonlinearities in ZnSe, GaAs, CdTe, and ZnTe10.1364/JOSAB.9.000405 ↗