journal article·2018-04

Morphology, structure and photowettability of TiO2 coatings doped with copper and fluorine

Anna Sobczyk-Guzenda, Sławomir Owczarek, Mateusz Fijalkowski, Damian Batory, Maciej Gazicki-Lipman

Ceramics International· Volume 44· Issue 5
Publisher page

Abstract

Abstract The work reports synthesis, structure and properties of doubly doped titanium dioxide coatings activated by ultraviolet and visible light. Copper within a concentration range of 0.4–3.4 at% and fluorine within a concentration range of 1.7–9.4 at% were introduced as dopants. The coatings were prepared with the help of radiofrequency plasma enhanced chemical vapor deposition technique with a single precursor compound providing both dopants and titanium (IV) chloride being a source of titanium. Elemental composition and chemical bonding analyses of the coatings were carried out with the help of X-ray photoelectron spectroscopy. The results indicate that both admixtures are chemically bound to the TiO2 matrix – a notion confirmed by Fourier transform infrared spectroscopy. Phase composition studies, performed with a low angle X-ray diffraction method, revealed a presence of a threshold concentration of the dopants affecting the coatings crystallinity. Surface morphology and its topography were studied with the help of scanning electron microscopy and atomic force microscopy. Several coatings exhibited a superhydrophilic effect upon relatively short time of illumination.
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Research context

OpenAlex topics: ZnO doping and properties · TiO2 Photocatalysis and Solar Cells · Gas Sensing Nanomaterials and Sensors

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References (46)

Show source-provided references
1. Visible and near infrared light active photocatalysis based on conjugated polymers10.1016/j.jiec.2017.03.022 ↗
2. Environmental applications of semiconductor photocatalysis10.1021/cr00033a004 ↗
3. Fast purification of air from dimethyl sulfide with nanosized TiO2 aerosol10.1016/j.apcatb.2012.09.019 ↗
4. Adsorption performance of titanium dioxide (TiO2) coated air filters for volatile organic compounds10.1016/j.jhazmat.2012.10.042 ↗
5. Ballast water treatment using UV/TiO2 advanced oxidation processes: an approach to invasive spieces prevention10.1016/j.cej.2013.12.082 ↗
6. Effect of binder on the physical stability and bactericidal property of titanium dioxide (TiO2) nanocoatings on food contact surfaces10.1016/j.foodcont.2015.04.009 ↗
7. Bactericidal activity of titanium dioxide ultraviolet-induced films10.1016/j.msec.2015.10.021 ↗
8. Antifungal capability of TiO2 coated film on moist wood10.1016/j.buildenv.2008.07.018 ↗
9. TiO2-based photocatalytic disinfection of microbes in aqueous media: a review10.1016/j.envres.2017.01.018 ↗
10. recent progress in biomedical applications of titanium dioxide10.1039/c3cp43938k ↗
11. Synthesis and characterization of TiO2 and Fe/TiO2 nanoparticles and their performance for photocatalytic degradation of 1,2-dichloroethane10.1016/j.apsusc.2008.07.079 ↗
12. Influence of Se/N codoping on the structural, optical, electronic and photocatalytic properties of TiO210.3390/molecules22030414 ↗
13. Synthesis and Structural Analysis of Different CuO Nano Particles
14. Cu2O/TiO2 heterostructures for CO2 reduction through a direct Z-scheme: protecting Cu2O from photocorrosion10.1016/j.apcatb.2017.05.058 ↗
15. Electronic and optical properties of Cu, CuO and Cu2O studied by electron spectroscopy
16. Hydrothermal vs. electrodeposited CuxO for photocatalytic applications under simulated solar illumination10.1016/j.matchemphys.2012.05.046 ↗
17. TiO2-CuO three-dimensional heteostructure obtained using short time photochemical deposition of copper oxide inside a porous nanocrystalline TiO2 layer10.1016/j.micromeso.2007.06.004 ↗
18. Photocatalytic removal of phenol from refinery wastewater: catalytic activity of Cu-doped titanium dioxide10.1016/j.jwpe.2015.09.004 ↗
19. Photocatalytic degradation of 4-chlorophenol on titanium dioxide modified with Cu(II) or Cr(III) ion under visible light irradiation10.1016/j.apcata.2016.09.001 ↗
20. Preparation and characterization of Cu2O-TiO2: efficient photocatalytic degradation of methylene blue10.1016/j.materresbull.2008.01.026 ↗
21. Synthesis of Cu loaded TiO2 nanoparticles for the improved photocatalytic degradation of Rhodamine B10.1142/S0219581X16600024 ↗
22. The photocatalytic and antibacterial activity of Cu-doped TiO2 thin films
23. Visible-light photocatalysis in nitrogen-doped titanium oxides10.1126/science.1061051 ↗
24. Effects of acceptor-donor complexes on electronic structure properties in co-doped TiO2: a first-principles study10.1016/j.physe.2016.03.016 ↗
25. Photocatalytic activities of Fe-Cu/TiO2 on the mineralization of oxalic acid and formic acid under visible light irradiation10.1016/j.powtec.2014.06.061 ↗
26. Improved visible light photocatalytic activity of TiO2 co-doped with vanadium and nitrogen10.1016/j.apcatb.2012.06.030 ↗
27. Preparation by sonophotodeposition method of bematallicphotocatalysts PD-Cu/TiO2 for sustainable gaseous selective oxidation of methanol to methyl formate10.1016/j.molcata.2015.10.031 ↗
28. A Cu-Au bimetallic co-catalysis for the improved photocatalytic activity of TiO2 under visible light radiation10.1016/j.solener.2017.07.084 ↗
29. Immobilization of visible light-sensitive (N, Cu) co-doped TiO2 onto rectorite for photocatalytic degradation of p-chlorophenol in aqueous solution10.1016/j.clay.2016.10.010 ↗
30. Enhanced photocatalytic activity of TiO2-Cu/C with regulation and matching of energy levels by carbon and copper for photoreduction of CO2 into CH410.1039/C6CE00117C ↗
31. Cu-S coped TiO2 nanophotocatalyst for the degradation of environmental and industrial pollutants10.2174/1876214X01205010021 ↗
32. Highly efficient F, Cu doped TiO2 anti-bacterial visible light active photocatalytic coatings to combat hospital-acquired infections10.1038/srep24770 ↗
33. Role of dopant concentration, crystal phase and particle size on microbial inactivation of Cu-doped TiO2 nanoparticles10.1088/0957-4484/22/41/415704 ↗
34. Bogatu · Ceram. Int. · 2017 · 43 · 796310.1016/j.ceramint.2017.03.054 ↗
35. The effect of thermal annealing on Fe/TiO2 coatings deposited with the help of RF PECVD method. Part I. Chemical and phase composition10.1016/j.ceramint.2016.11.105 ↗
36. Visible light photocatalysis of nitrogen-doped titanium oxide films prepared by plasma-enhanced chemical vapor deposition10.1149/1.2165773 ↗
37. Infrared spectroscopy of titania sol-gel coatings on 316L stainless steel
38. Structural, optical, and photoelectrochemical properties of Mn+-TiO2 model thin film photocatalysts10.1021/jp0484938 ↗
39. Stability and surface reactivity of anatase TiO2 films10.1149/2.0041508jss ↗
40. Photocatalytic and antimicrobial activities of fluorine doped TiO2-carbon nano cones and disc composites10.1016/j.mssp.2014.12.052 ↗
41. Controlled synthesis of hierarchical CuO nanostructures for electrochemical capacitor electrodes10.1016/S1452-3981(23)12916-6 ↗
42. Fluorine doped TiO2 films deposited by plasma enhanced chemical vapour deposition
43. Transparent thin films of Cu-TiO2 with visible light photocatalytic activity10.1039/c4pp00271g ↗
44. The effect of thermal annealing on Fe/TiO2 coatings deposited with the help of RF PECVD method. Part II. Optical and photocatalyticproperties10.1016/j.ceramint.2016.12.108 ↗
45. Analysis of the refractive indices of TiO2, TiOF2, and TiF4: concept of optical channel as a guide to understand and design optical materials10.1021/ic048259w ↗
46. Photocatalytic activity and photoinducedhydrophlicity of titanium dioxide coated glass10.1016/S0040-6090(99)00205-9 ↗