journal article·2018-02

Controllable Growth of ZnO Microstructures via a Solution Route

Xiao Long Li, Shu Ping Hou, Li Cheng Zhang, Bin Wang, Ren Xing Xiao, Xi Feng Liu

Publisher page

Abstract

A facile method has been developed to fabricate ZnO microstructures by a solution route at an 80°C. The microstructures with various morphologies were fabricated in water or anhydrous ethanol by using polyvinylpyrrolidone and cetyltrimethylammonium bromide as surfactants. ZnO rods with aspect ratios up to 30 have been created successfully in water through a hydrothermal process, while novel shuttle-like ZnO microstructures were fabricated in anhydrous ethanol using a similar procedure. ZnO rods revealed wurtzite-type crystal structure according to their X-ray diffraction (XRD) patterns. The morphologies of ZnO microstructures were adjusted conveniently by changing solvents and surfactants. In addition, the sizes of ZnO microstructures decreased under a long reaction time. This morphological evolution of ZnO microstructures indicated that the growth of ZnO is susceptive to reaction time due to the reaction between ZnO and aqueous ammonia. The facile strategy described here would be utilizable for the preparation of various metal oxide microstructures.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: ZnO doping and properties · Copper-based nanomaterials and applications · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shandong Academy of Building Research

References (29)

Show source-provided references
1. AHMAD M. and ZHU J., J. Mater. Chem., 21 (2011), 599.10.1039/C0JM01645D ↗
2. PARK W. II., KIM J. S., YI G.C., BAE M. H. and LEE H. J., Appl. Phys. Lett., 85 (2004), 5052.10.1063/1.1821648 ↗
3. BAXTER J. B. and AYDIL E. S., Appl. Phys. Lett., 86 (2005), 053114.10.1063/1.1861510 ↗
4. FAN Z. Y. and LU J. G., Appl. Phys. Lett., 86 (2005), 123510.10.1063/1.1883715 ↗
5. YAO B. D., CHAN Y. F. and WANG N., Appl. Phys. Lett., 81 (2002), 757.10.1063/1.1495878 ↗
6. GAO P. X., DING Y., MAI W., HUGHES W. L., LAO C. and WANG Z. L., Science, 309 (2005), 1700.10.1126/science.1116495 ↗
7. PARK W. I., KIM D. H., JUNG S. W. and YI G. C., Appl. Phys. Lett., 80 (2002), 4232.10.1063/1.1482800 ↗
8. LIU F., CAO P. J., ZHANG H. R., SHEN C. M., WANG Z., LI J. Q. and GAO H. J., J. Cryst. Growth, 274 (2005), 126.10.1016/j.jcrysgro.2004.09.080 ↗
9. PARK J. Y., LEE D. J. and KIM S. S., Nanotechnology, 16 (2005), (2044).10.1088/0957-4484/16/10/010 ↗
10. VANHEUSDEN K., WARREN W. L., SEAGER C. H., TALLANT D. R., VOIGT J. A. and GNADE B. E., J. Appl. Phys., 79 (1996), 7983.10.1063/1.362349 ↗
11. GUO L., JI Y. L., XU H., SIMON P. and WU Z., J. Am. Chem. Soc., 124 (2002), 14864.10.1021/ja027947g ↗
12. WU G. S., XIE T., YUAN X. Y., LI Y., YANG L., XIAO Y. H. and ZHANG L. D., Solid State Commun., 134 (2005), 485.10.1016/j.ssc.2005.02.015 ↗
13. VAYSSIERES L., KEIS K., LINDQUIST S. and HAGFELDT A., J. Phys. Chem. B, 105 (2001), 3350.10.1021/jp010026s ↗
14. VAYSSIERES L., KEIS K., HAGFELDT A. and LINDQUIST S. E., Chem. Mater., 13 (2001), 4395.10.1021/cm011160s ↗
15. CHENG J., GUO R. and WANG Q., Appl. Phys. Lett., 85 (2004), 5140.10.1063/1.1825067 ↗
16. DAI Y., ZHANG Y., LI Q. K. and NAN C. W., Chem. Phys. Lett., 358 (2002), 83.10.1016/S0009-2614(02)00582-1 ↗
17. ZHANG H., YANG D., JI Y., MA X., XU J. and QUE D., J. Phys. Chem. B, 108 (2004), 3955.10.1021/jp036826f ↗
18. GUI Z., LIU J., WANG Z., SONG L., HU Y., FAN W. and Chen D., J. Phys. Chem. B, 109 (2005), 1113.10.1021/jp047088d ↗
19. TANG Q., ZHOU W. J., SHEN J. M., ZHANG W., KONG L. F. and QIAN Y. T., Chem. Commun.,712 (2004).10.1039/b313387g ↗
20. HOU H., XIONG Y., XIE Y., LI Q., ZHANG J. and TIAN X., J. Solid State Chem., 177 (2004), 176.10.1016/S0022-4596(03)00395-5 ↗
21. Shi R, Yang P, Wang J, et al. Growth of flower-like ZnO via surfactant-free hydrothermal synthesis on ITO substrate at low temperature, CrystEngComm, 2012, 14(18): 5996-6003.10.1039/c2ce25606a ↗
22. SUN X. M., CHEN X., DENG Z. X. and LI Y. D., Mater. Chem. Phys., 78 (2002), 99.10.1016/S0254-0584(02)00310-3 ↗
23. Mo M. S., Yu J. C., Zhang L. Z. and Li S. A., Adv. Mater., 17 (2005), 756.10.1002/adma.200401477 ↗
24. Cheng B, Samulski E T. Hydrothermal synthesis of one-dimensional ZnO nanostructures with different aspect ratios, Chem Commun, 2004, 8: 986-987.10.1039/b316435g ↗
25. Wang Y L, Jiang X C, Xia Y N. A Solution-phase, precursor route to polycrystalline SnO2 nanowires that can be used for gas sensing under ambient conditions, J Am Chem Soc, 2003, 125(52): 16176-16177.10.1021/ja037743f ↗
26. ZHANG H., YANG D. R., LI D. S., MA X. Y., LI S. Z. and QUE D. L., Cryst. Growth Des., 5 (2005), 547.10.1021/cg049727f ↗
27. WEN B., HUANG Y. and BOLAND J. J., J. Phys. Chem. C, 112 (2008), 106.10.1021/jp076789i ↗
28. WANG C., SHEN E., WANG E., GAO L., KANG Z., TIAN C., LAN Y. and ZHANG C., Mater. Lett., 59 (2005), 2867.10.1016/j.matlet.2005.04.031 ↗
29. WEI S. F., LIAN J. S. and JIANG Q., Appl. Surf. Sci., 255 (2009), 6978.10.1016/j.apsusc.2009.03.023 ↗