Novel development of low-loss MnZn ferrites by sintering process optimisation and CaTiO3 doping
Source abstract
Abstract
Renewable energy systems such as solar inverters increasingly require efficient and compact components. This drives the need for MnZn ferrites with low power loss and high permeability at high frequencies. This study addresses this challenge by optimising the sintering process and introducing CaTiO 3 through a novel doping method. A higher heating rate and shorter sintering period refined the grain size, which was further enhanced by CaTiO 3 doping. This microstructural improvement reduced eddy current loss and increased cut-off frequency. With the addition of 1200 ppm CaTiO 3 , MnZn ferrites achieved minimal power loss of under 130 mW/cm 3 at 1 MHz/30 mT and 300 mW/cm 3 at 3 MHz/10 mT over the temperature range of -20 °C to 100 °C. Sintering temperature was successfully lowered to 1150 °C with only 30 minutes of holding time, promoting energy savings and sustainability. The combined sintering and doping strategy effectively improved electromagnetic properties, offering a scalable route for producing high-performance MnZn ferrites suitable for next-generation high-frequency applications.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Electromagnetic wave absorption materials · Multiferroics and related materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (86)
Show source-provided references
1. Feasibility-sustainability study of power generation using solar energy at an industrial site: a case study from Egypt
2. Advancing thermal energy storage: unravelling the optimal orientation of annular phase change material containers within the tank10.1016/j.csite.2025.105931 ↗
3. Smart industrial internet of things framework for composites manufacturing10.3390/s24154852 ↗
4. Assessing the vulnerability of solar inverters to EMPs: port testing, PCI modeling, and protection strategies10.1016/j.measurement.2023.113931 ↗
5. A novel overall efficiency index for a single phase standalone solar PV hybrid inverters
6. Performance assessment of solar energy driven cascaded H-bridge multilevel inverters10.1007/s00542-024-05748-2 ↗
7. Porous macroradical epoxy-based supercapacitors10.1016/j.polymer.2022.125356 ↗
8. Unidirectional hybrid three-phase rectifier with boost converter and coupled inductor10.3390/electronics13101864 ↗
9. Minimization of leakage current in a maximum boost control impedance source transformer-less inverter10.1016/j.matpr.2022.06.127 ↗
10. Grain refinement and high-frequency properties of spark plasma sintered MnZn ferrite10.1016/j.jmmm.2023.171487 ↗
11. MnZn-ferrites: targeted material design for new emerging application products
12. Co-doping strategies for low-loss MnZn ferrites: experimental investigations and genetic algorithm-assisted optimisation10.1016/j.ceramint.2025.11.348 ↗
13. Improved core-loss calculation for magnetic components employed in power electronic systems10.1109/TPEL.2011.2162252 ↗
14. Enhancing thermal energy storage system efficiency: geometric analysis of phase change material integrated wedge-shaped heat exchangers10.1016/j.applthermaleng.2024.125268 ↗
15. Atomistic theory of ostwald ripening and disintegration of supported metal particles under reaction conditions10.1021/ja3087054 ↗
16. Phase-field simulation of solid state sintering10.1016/j.actamat.2018.10.021 ↗
17. Specific surface areas of porous Cu manufactured by lost carbonate sintering: measurements by quantitative stereology and cyclic voltammetry10.1016/j.matchemphys.2015.06.031 ↗
18. Preparation of densified fine-grain high-frequency MnZn ferrite using the cold sintering process10.3390/ma16093454 ↗
19. Diffusional viscosity of a polycrystalline solid10.1063/1.1699681 ↗
20. Nucleation and pinning of magnetic domains at Co7Sm2 precipitates in Co5Sm crystals10.1002/pssa.2210560219 ↗
21. Temperature stable MnZn ferrites for applications in the frequency region of 500kHz10.1016/j.ceramint.2016.01.176 ↗
22. Concurrent core loss suppression and high permeability by introduction of highly insulating intergranular magnetic inclusions to MnZn ferrite10.1109/LMAG.2017.2771391 ↗
23. Processing bulk insulating CaTiO3 into a high-performance thermoelectric material
24. Ab initio calculations of the atomic and electronic structure of CaTiO3 (001) and (011) surfaces10.1103/PhysRevB.78.155420 ↗
25. Low temperature synthesis and thermal expansion study of nanocrystalline CaTiO310.1016/j.matlet.2022.133627 ↗
26. Tailoring the crystal structure of CaTiO3 by multielement doping for photo-assisted activation of NO10.1016/j.cej.2022.138255 ↗
27. Magnetic and dielectric properties of low-temperature sintered NiCuZn/CaTiO3 composite dual-performance materials10.1016/j.jallcom.2022.164906 ↗
28. Effect of CaCu3Ti4O12 dopant on the magnetic and dielectric properties of high-frequency MnZn power ferrites10.1016/j.jmmm.2020.167095 ↗
29. Ultra-low core losses at high frequencies and temperatures in MnZn ferrites with nano-BaTiO3 additives10.1016/j.jallcom.2019.153573 ↗
30. Grain growth in polycrystalline materials: current understanding and future research directions
31. Evaluation of grain growth exponent by monte carlo simulation in polycrystalline materials
32. Austenite grain growth and its equation in the austenitizing process for 700 MPa grade high-strength steel10.1007/s12666-023-03031-y ↗
33. Study of grain growth in a Ni-Based superalloy by experiments and cellular automaton model10.3390/ma14226922 ↗
34. High-frequency MnZn soft magnetic ferrite by engineering grain boundaries with multiple-ion doping10.1016/j.jmst.2020.12.009 ↗
35. Temperature dependence of core loss in Co-substituted MnZn ferrites10.1063/1.1557952 ↗
36. Effect of CaCO3 and V2O5 composite additives on the microstructure and magnetic property of MnZn ferrites
37. Temperature and frequency characteristics of low-loss MnZn ferrite in a wide temperature range10.1063/1.3583551 ↗
38. Analysis of losses in NiO doped MnZn ferrites10.1016/j.jallcom.2007.12.099 ↗
39. Crystal-like microstructural Finemet/FeSi compound powder core with excellent soft magnetic properties and its loss separation analysis10.1016/j.matdes.2020.108769 ↗
40. Revisiting andrews method and grain boundary resistivity from a computational multiscale perspective10.1016/j.mechmat.2024.105115 ↗
41. Accounting for the resistivity contribution of grain boundaries in metals: critical analysis of reported experimental and theoretical data for Ni and Cu10.1140/epjp/s13360-021-01303-4 ↗
42. Understanding grain boundary electrical resistivity in Cu: the effect of boundary structure10.1021/acsnano.1c06367 ↗
43. Approaches to measure the resistivity of grain boundaries in metals with high sensitivity and spatial resolution: a case study employing Cu10.1021/acsaelm.0c00311 ↗
44. Correlation between the microstructure and permeability stability of ferrite materials10.1016/j.ceramint.2017.10.196 ↗
45. Pinning and roughening of domain walls in ising systems due to random impurities10.1103/PhysRevLett.54.2708 ↗
46. Fine grained Mn–Zn ferrite for high frequency driving10.1063/1.367765 ↗
47. Effects of grain size on the residual loss of Mn–Zn ferrites10.1063/1.1447506 ↗
48. MnZn power ferrite with high Bs and low core loss10.1016/j.ceramint.2016.03.005 ↗
49. Effect of MoO3 addition on the magnetic properties and complex impedance of Mn–Zn ferrites with High Bsand High initial permeability10.1007/s10948-017-4002-z ↗
50. Improving soft magnetic properties of Mn-Zn ferrite by rare earth ions doping
51. Two-step doping of SiO2 and CaO for high-frequency MnZn power ferrites10.1016/j.jeurceramsoc.2023.01.009 ↗
52. Correlating the microstructure with magnetic properties of Ti-doped high-frequency MnZn ferrite10.1016/j.jeurceramsoc.2023.05.030 ↗
53. A large domain wall pinning effect on the magnetic properties of ZrO2 added Mn–Zn ferrites10.1016/j.ceramint.2013.10.127 ↗
54. Fabrication and magnetic property analysis of monodisperse manganese–zinc ferrite nanospheres10.1016/j.jmmm.2009.05.049 ↗
55. The effect of calcium perovskite and newly developed magnetic CaFe2O4/CaTiO3 perovskite nanocomposite on degradation of toxic dyes under UV–Visible radiation
56. Superparamagnetic La Doped Mn-Zn Nano Ferrites: dependence on Dopant Content and Crystallite Size10.1088/2053-1591/3/7/075001 ↗
57. Effects of TiO2 and Co2O3 combination additions on the elemental distribution and electromagnetic properties of Mn–Zn power ferrites10.1016/j.jmmm.2015.02.020 ↗
58. Effect of Y2O3-doping on the electromagnetic properties of ni-zn-co ferrite10.1016/j.jmmm.2023.170533 ↗
59. Reversible Fe3+/Fe2+ and Ti4+/Ti3+ redox couple in Fe-substituted LiTi2O4 ramsdellite and its electrochemical properties as electrode material in lithium ion batteries10.1016/j.jallcom.2023.172027 ↗
60. Effect of Ti4+ substitution on the magnetic behavior, physicochemical properties and heating ability of the manganese ferrite10.1016/j.ceramint.2025.09.141 ↗
61. Development of Mn-Zn power ferrite with low losses over a broad temperature range for applications in the high frequency region of 0.5-3 MHz10.1016/j.ceramint.2021.04.152 ↗
62. Infrared Spectra and magnetic studies of trivalent Doped Li-Ferrites10.1002/1521-396X(200108)186:3<415::AID-PSSA415>3.0.CO;2-P ↗
63. Effect of Sm3+-Gd3+ co-doping on dielectric properties of Mn-Zn ferrites synthesized via combustion route10.1016/j.matpr.2016.04.124 ↗
64. Effect of sintering temperature on the microstructure and electrical properties of zirconium doped barium titanate ceramics10.1007/s10854-013-1460-3 ↗
65. Kinetics of Nb incorporation into barium titanate10.1016/S0022-3697(00)00211-0 ↗
66. Synthesis of barium titanate by electrostatic levitation10.1016/j.jcrysgro.2004.09.096 ↗
67. Microstructure, electrical, and magnetic properties of ZrO added MnZn ferrites10.1109/TMAG.2008.2000809 ↗
68. Synthesis and characterization of nanocrystalline CoFe2O4-zirconia via propylene oxide aided sol-gel method10.1016/j.ceramint.2018.02.102 ↗
69. Influence of ultrasonic impact treatment and working current on microstructure and mechanical properties of 2219 aluminium alloy wire arc additive manufacturing parts10.1016/j.jmrt.2022.09.055 ↗
70. Grain boundary engineering towards high-figure-of-merit Nd-Ce-Fe-B sintered magnets: synergetic effects of (Nd, Pr)Hx and Cu co-dopants10.1016/j.actamat.2020.116529 ↗
71. Preparation and properties of CaO-added Mn-Zn ferrite ceramic10.1016/j.ceramint.2023.08.353 ↗
72. Analysis of the complex permeability of NiCuZn ferrites up to 1GHz with regard to Cu content and sintering temperature10.1016/j.ceramint.2013.06.010 ↗
73. Study on the contribution of magnetization mechanisms in NiZn ferrites
74. Influence of zinc concentration on structure, complex permittivity and permeability of Ni–Zn ferrites at high frequency10.1016/j.jmmm.2015.10.003 ↗
75. Temperature dependence of core losses at high frequency for MnZn ferrites10.1016/j.physb.2009.10.047 ↗
76. Microstructure and magnetic properties of Sn-substituted MnZn ferrites10.1016/j.jmmm.2009.04.053 ↗
77. Low power loss manganese ferrites with the addition of Ta2O5 for MHz applications10.1016/j.jmmm.2022.169699 ↗
78. Effect of a YIG nanoparticle additive on the magnetic properties of MnZn ferrites for MHz frequency applications
79. Engineering the Maxwell–Wagner polarization effect10.1016/j.apsusc.2009.03.030 ↗
80. Correlating the microstructure and magnetic properties of MnZn power ferrites via Co2O3 and MoO3 co-doping for MHz applications10.1016/j.jmmm.2021.168324 ↗
81. New views on the dissipation in soft magnetic ferrites10.1016/S0304-8853(98)00732-X ↗
82. Low loss MnZn ferrites for applications in the frequency region of 1–3 MHz10.1016/j.jmmm.2018.06.056 ↗
83. The effect of BaTiO3 on the magnetic behavior of MnZn ferrites at frequencies > 5 MHz10.1016/j.jmmm.2024.172101 ↗
84. Co2O3 and SnO2 doped MnZn ferrites for applications at 3–5 MHz frequencies10.1016/j.ceramint.2019.03.193 ↗
85. Relation between grain size and domain size in MnZn ferrite studied by neutron depolarisation10.1016/0304-8853(91)90039-D ↗
86. Low temperature sintered MnZn ferrites for power applications at the frequency of 1 MHz10.1016/j.jeurceramsoc.2021.05.013 ↗