Preparation and Characterization of Epoxidized-30% Poly(methyl methacrylate)-grafted Natural Rubber Polymer Electrolyte
Source abstract
Abstract
In this study, a freestanding thin film composed of lithium triflate (LiTf) salt (30-40 wt.%) and epoxidized-30% poly (methyl methacrylate)-grafted natural rubber (EMG30) (50, 54.6, 62.3 mol %) were prepared by a solvent cast technique. The EMG30 were found to increase the ionic conductivity of EMG30-LiTf by one order of magnitude compared to MG30-LiTf. The highest ionic conductivity achieved was 5.584 x10-3 Scm-1 at room temperature when 40 wt.% of LiTf salts were introduced into 62.3 mol % EMG30. The ionic conduction mechanisms in EMG30-LiTf electrolytes obey Arrhenius rule in which the ion transport in these materials is thermally assisted.
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Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Conducting polymers and applications · Fuel Cells and Related Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Universiti Teknologi MARA
Universiti Pertahanan Nasional Malaysia
References (20)
Show source-provided references
1. Hofmanna, A., Schulza, M., Hanemanna, T., (2013) Electrochimica Acta 89: 823–831.10.1016/j.electacta.2012.10.144 ↗
2. Gupta, V. K., Jain, A.K., Pal, M.K., Bharti, A.K., (2012) 80: 316-325.10.1016/j.electacta.2012.07.026 ↗
3. Babu, K. F., Siva Subramanian, S. P., Anbu Kulandainathan, M., (2013) Carbohydrate Polymers 94: 487–495.10.1016/j.carbpol.2013.01.021 ↗
4. Su'ait, M.S., Ahmad, A., Hamzah, H., Rahman, M.Y.A., (2011) Electrochimica Acta 57: 123-131.10.1016/j.electacta.2011.06.015 ↗
5. Di Noto, V., Lavina, S., Giffin, G.A., Negro, E., (2011) Electrochimica Acta 57: 4-13.10.1016/j.electacta.2011.08.048 ↗
6. Asmara, S.N., Kufian, M.Z., Majid, S.R., Arof, A.K., (2011) Electrochimica Acta 57: 91-97.10.1016/j.electacta.2011.06.045 ↗
7. Voigt, N., Van Wüllen, L., (2012) Solid State Ionics 208: 8–16.10.1016/j.ssi.2011.11.031 ↗
8. Ramesh, S., Wen Liew, C., Morris, E., Durairaj, R., (2010) Thermochimica Acta 511: 140-146.10.1016/j.tca.2010.08.005 ↗
9. Li, H., Chen, Y., Ma, X., LS, Jun., KZ, B., PZ, Li (2011) 379: 397-402.10.1016/j.memsci.2011.06.008 ↗
10. Kufian, M.Z., Aziz, M.F., Shukur, M.F., Rahim, A.S., Ariffin, N.E., Shuhaimi, N.E.A., Majid, S.R., Yahya, R., Arof A.K., (2012) Solid State Ionics 208: 36–42.10.1016/j.ssi.2011.11.032 ↗
11. Latif, F., Aziz, M., Katun, N., Ali, A.M.M., Yahya M.Z.A., (2006) Journal of Power Sources 159: 1401-1404.10.1016/j.jpowsour.2005.12.007 ↗
12. Latif, F. A (2006) PhD thesis, Universiti Teknologi Malaysia, Faculty of Science.
13. A.M.M. Ali , M.Z. A Yahya, H. Baharon, R.H.Y. Subban (2006), Ionics 12: 303-307.10.1007/s11581-006-0052-0 ↗
14. K.S. Yap, L.P. Teo, L.N. Sim, S.R. Majid, A.K. Arof (2012) Pysica B 407: 2421-2428.10.1016/j.physb.2012.03.039 ↗
15. K. Kumutha, Y. Alias and R, Said, Ionics II , 472-476 (2005).10.1007/BF02430270 ↗
16. A.M.M. Ali , M.Z. A Yahya, H. Baharon, R.H.Y. Subban, A.S. Kamisan (2013) Journal of Power Sources 1-5.
17. H. Hashim, N. I. Adam, N.H.M. Zaki, Z.S. Mahmud, C.M.S. Said M. Z. A. Yahya and A. M. M. Ali., International Conference on Science and Social Research, Kuala Lumpur, Malaysia, December 5-7, (2010).
18. Shin, J. H., Henderson, W.A., Passerini, S., (2005) Electrochem. Solid-State Lett. V 8, 2: 125-127.10.1149/1.1850387 ↗
19. Aziz, A.F., Ayub, S.F., Nazir, K. Zakaria, R., Yahya, M.Z.A., Ali, A.M.M., IEEE Colloquium on Humanities, Science & Engineering Research, (CHUSER 2012), December 3-4, 2012, Kota Kinabalu, Sabah, Malaysia 978-1-4673-4617.
20. R. Yoksan (2008): Nat. Sci 42: 325-332.