journal article·2014-03

Study of Electrospun Chitosan Nanofibrous Coated Webs

Mukesh Kumar Sinha, Biswa Ranjan Das, Anurag Srivastava, Arvind Kumar Saxena

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Abstract

Fabricated nanowebs are successfully coated with polypropylene spun bonded non-woven fabric with various coating density ranges from 0.25-1.2 gsm. This study describes an electrospinning coating process of pure Chitosan dissolved in TFA and DCM and its detailed characterizations. The optimal solution condition for electrospinning was studied and, thereby, the process was successfully established. The best optimal condition: 11 % Chitosan was successfully electrospun (superlative web structure) in the electric field of 75 KV, distance between spinning electrodes 135 mm and rotation of spinning electrode 5 rpm (throughput). Once it was determined the ideal condition for fabricating web thereafter under identical conditions electro coating process was done by varying collector speed. The resultant nanofibrous web was found to be uniformly coated having mean fiber diameter ranges from 1210-1221 nm. AFM microphotographs indicated the interconnected porous structure of the prepared Chitosan web. Fibrous break down at a solution concentration (2 & 5 %) was revealed by AFM and FESEM images. At higher concentration (14%) web spinability was poor in the form of lumps deposition. Morphology of spun web was greatly influenced by coating density. Thus, these nanofibrous coated membranes have great potential for using as a layer for developing futuristic antimicrobial, biomedical and filtration clothing. Moreover, the developed coated web has a significantly higher production rate (approx 0.25 g/m2min) is potential for commercial viability and could be translated into bulk production.
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Research context

OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Advanced Sensor and Energy Harvesting Materials · Silk-based biomaterials and applications

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Affiliations

Defence Materials and Stores Research and Development Establishment (DMSRDE)

References (19)

Show source-provided references
1. W.K. Son, J.H. Youk, W.H. Park, Antimicrobial Cellulose Acetate Nanofibers Containing Silver Nanoparticles, Carbohydr. Polym. 65 (2006) 430-434.10.1016/j.carbpol.2006.01.037 ↗
2. S.J. Kim, Y.S. Nam, D.M. Rhee, H.S. Park, W.H. Park, Preparation and Characterization of Antimicrobial Polycarbonate Nanofibrous Membrane, Eur. Polym. J. 43 (2007) 3146-3152.10.1016/j.eurpolymj.2007.04.046 ↗
3. S. Zhang, W.S. Shim, J. Kim, Design of Ultra-Fine Nonwovens via Electrospinning of Nylon 6: Spinning Parameters and Filtration Efficiency, Mater. Des. 30 (2009) 3659-3666.10.1016/j.matdes.2009.02.017 ↗
4. R. Sadeghian, S. Gangireddy, B. Minaie, K.T. Hsiao, Manufacturing Carbon Nanofibers Toughened Polyester/Glass Fiber Composites using Vacuum Assisted Resin Transfer Molding for Enhancing the Mode-I Delamination Resistance, Compos.: Part A 37 (2006).10.1016/j.compositesa.2005.09.010 ↗
5. S.J. Liua, Y.C. Kaua, C.Y. Choua, J.K. Chenc, R.C. Wud, W.L. Yehe, Electrospun PLGA/Collagen Nanofibrous Membrane as Early-Stage Wound Dressing, J. Membr. Sci. 355 (2010) 53-59.10.1016/j.memsci.2010.03.012 ↗
6. S.I. Jeong, M.D. Krebs, C.A. Bonino, J.A. Samorezov, S.A. Khan S. A, A. Eben, Electrospun Chitosan–Alginate Nanofibers with In Situ Polyelectrolyte Complexation for use as Tissue Engineering Scaffolds Tissue Engineering, Retrieved Oct 2013 from http: /bme. case. edu/libraries/Document/jeong. tissueengineering. 2010. pdf.10.1089/ten.tea.2010.0086 ↗
7. L. Martinov, D. Lubasova, Electrospun Chitosan based Nanofibers, Res. J. Text. Apparel 12 (2) (2008) 72 -79.10.1108/RJTA-12-02-2008-B009 ↗
8. X. Geng, O.H. Kwon, J. Jang, Electrospinning of Chitosan dissolved in concentrated Acetic Acid solution, Biomater. 2 (2005) 5427-5432.10.1016/j.biomaterials.2005.01.066 ↗
9. S.A.A.N. Nasreen, S. Sundarrajan, S.A.S. Nizar, R. Balamurugan, Advancement in Electrospun Nanofibrous Membranes modification and their application in water treatment, S. Ramakrishna, Membranes 3 (2013) 266- 284.10.3390/membranes3040266 ↗
10. C.K.S. Pillai, C.P. Sharma, Electrospinning of Chitin and Chitosan Nanofibres, Trends Biomater. Artif. Organs 22 (3) (2001) 179-201.
11. K. Sun, Z.H. Li, Preparations, Properties and Applications of Chitosan based Nanofibers Fabricated by Electrospinning, Express Polym. Lett. 5 (4) (2011) 342-361.10.3144/expresspolymlett.2011.34 ↗
12. R. Nawalakhe, Q. Shi, N. Vitchuli, J. Noar, J.M. Caldwell, F. Breidt, M.A. Bourham, X. Zhang, M.G. McCord, Novel Atmospheric Plasma Enhanced Chitosan Nanofiber/Gauze Composite Wound Dressings, J. Appl. Polym. Sci. DOI: 10. 1002/APP. 38804, (2013).10.1002/app.38804 ↗
13. I Uslu, H. Celikkan, O. Atakol, M.L. Aksu, Preparation of PVA/Chitosan Doped with Boron Composite Fibers and their Characterization, Hacettepe J. Biol. & Chem. 36 (2) ( 2008) 117-122.
14. M.A. Diab, A.Z. E Sonbati, M.M. Al-Halawany, D.M.D. Bader, Thermal Stability and degradation of Chitosan Modified by Cinnamic Acid, Open Journal of Poly. Chem., 2 (2012) 14-20.10.4236/ojpchem.2012.21003 ↗
15. M. Dasha, F. Chiellinia, R.M. Ottenbriteb, E. Chiellinia, Chitosan—A Versatile Semi-Synthetic Polymer in Biomedical Applications, Prog. Polym. Sci. 36 (8) (2011) 98-1014.10.1016/j.progpolymsci.2011.02.001 ↗
16. E.A.E. Hefian, S.E. Elgannoudi, A. Mainal, A.H. Yahaya, Characterization of Chitosan in Acetic Acid: Rheological and Thermal Studies, Turk. J. Chem. 34 (2010) 47-56.
17. R. Ramya, P.N. Sudha, J. Mahalakshmi, Preparation and Characterization of Chitosan Binary Blend, Int. J. Sci. Res. Publ. 2 (10) (2012) 1-9.
18. J.P. Chen, S.H. Chen, G.J. Lai, Preparation and Characterization of Biomimetic Silk Fibroin/Chitosan Composite Nanofibers by Electrospinning for Osteoblasts Culture Nanoscale, Res. Lett. 7 (170) (2012) 1-11.10.1186/1556-276x-7-170 ↗
19. K. Ohkawa, K.I. Minato, G. Kumagai, S. Hayashi, H. Yamamoto, Chitosan Nanofiber, Biomacromolecules 7 (2006) 3291-3294.10.1021/bm0604395 ↗