journal article·2023-03Open access

Development of yttria-stabilized zirconia and graphene coatings obtained by suspension plasma spraying: Thermal stability and influence on mechanical properties

Antonio Mulone, Satyapal Mahade, Stefan Björklund, Dennis Lundström, Björn Kjellman, Shrikant Joshi, Uta Klement

Ceramics International· Volume 49· Issue 6

Abstract

This study investigated the feasibility of depositing graphene nanoplatelet (GNP)-reinforced yttria-stabilized zirconia (YSZ) composite coatings. The coatings were deposited from an ethanol-based mixed YSZ and GNP suspension using suspension plasma spraying (SPS). Raman spectroscopy confirmed the presence of GNPs in the YSZ matrix, and scanning electron microscopy (SEM) analysis revealed a desired columnar microstructure with GNPs distributed predominantly in the inter-columnar spacing of the YSZ matrix. The as-deposited YSZ-GNP coatings were subjected to different isothermal treatments—400, 500, and 600 °C for 8 h—to study the thermal stability of the GNPs in the composite coatings. Raman analysis showed the retention of GNPs in specimens exposed to temperatures up to 500 °C, although the defect concentration in the graphitic structure increased with increasing temperature. Only a marginal effect on the mechanical properties (i.e., hardness and fracture toughness) was observed for the isothermally treated coatings.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Diamond and Carbon-based Materials Research · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

Show source-provided references
1. Mechanical properties of graphene and graphene-based nanocomposites10.1016/j.pmatsci.2017.07.004 ↗
2. Designing reduced graphene oxide/zinc rich epoxy composite coatings for improving the anticorrosion performance of carbon steel substrate10.1016/j.matdes.2019.107694 ↗
3. Electrical property of graphene and its application to electrochemical biosensing
4. Thermal properties of graphene: fundamentals and applications10.1557/mrs.2012.203 ↗
5. Graphene: a new emerging lubricant10.1016/j.mattod.2013.12.003 ↗
6. Robust ultra-low-friction state of graphene via moiré superlattice confinement10.1038/ncomms13204 ↗
7. Markandan
8. Graphene reinforced metal matrix composite (GRMMC): a review10.1016/j.proeng.2014.12.381 ↗
9. Du
10. Measurement of the elastic properties and intrisic strength of monolayer graphene10.1126/science.1157996 ↗
11. Walker
12. Toughening of zirconia/alumina composites by the addition of graphene platelets10.1016/j.jeurceramsoc.2012.07.007 ↗
13. Preparation of graphene nanosheet/alumina composites by spark plasma sintering10.1016/j.materresbull.2010.11.005 ↗
14. Unoxidized graphene/alumina nanocomposite: fracture-and wear-resistance effects of graphene on alumina matrix
15. Fracture toughness and toughening mechanisms in graphene platelet reinforced Si3N4 composites10.1016/j.scriptamat.2012.02.009 ↗
16. Nanocomposites-a new material design concept10.1016/j.stam.2004.06.002 ↗
17. Structural ceramic nanocomposites: a review of properties and powders' synthesis methods10.3390/nano5020656 ↗
18. The beneficial effect of graphene nanofillers on the tribological performance of ceramics10.1016/j.carbon.2013.04.102 ↗
19. Sintering behavior of spark plasma sintered alumina with graphene nanoplatelet reinforcement10.1016/j.ceramint.2015.01.027 ↗
20. Dense graphene nanoplatelet/yttria tetragonal zirconia composites: processing, hardness and electrical conductivity10.1016/j.ceramint.2017.06.007 ↗
21. Toughening mechanisms and mechanical properties of graphene nanosheet-reinforced alumina10.1016/j.matdes.2015.09.125 ↗
22. Synthesis and properties of bulk graphene nanoplatelets consolidated by spark plasma sintering10.1016/j.carbon.2012.04.054 ↗
23. Graphene nano- platelets reinforced ZrO2 consolidated by spark plasma sintering10.1166/sam.2016.2485 ↗
24. Graphene for tough and electroconductive alumina ceramics10.1016/j.jeurceramsoc.2013.07.007 ↗
25. Enhanced properties of nanostructured ZrO2–graphene composites rapidly sintered via high-frequency induction heating10.1016/j.ceramint.2014.08.042 ↗
26. Thermal stability of graphite oxide10.1016/j.cplett.2009.01.050 ↗
27. Graphene: a multipurpose material for protective coatings10.1039/C5TA01010A ↗
28. Beyond traditional coatings: a review on thermal-sprayed functional and smart coatings10.1007/s11666-019-00857-1 ↗
29. Alumina-graphene nanocomposite coatings fabricated by suspension high velocity oxy-fuel thermal spraying for ultra-low-wear10.1016/j.jeurceramsoc.2017.10.022 ↗
30. Defects in graphene: generation, healing, and their effects on the properties of graphene: a review10.1016/j.jmst.2014.11.019 ↗
31. A novel approach to incorporate graphene nanoplatelets to Cr2O3 for low-wear coatings10.1016/j.matlet.2020.128283 ↗
32. A facile approach to deposit graphenaceous composite coatings by suspension plasma spraying10.3390/coatings9030171 ↗
33. Novel suspension route to incorporate graphene nano-platelets in HVAF-sprayed Cr3C2–NiCr coatings for superior wear performance10.1016/j.jmrt.2021.04.096 ↗
34. Functional performance of Gd2Zr2O7/YSZ multi-layered thermal barrier coatings deposited by suspension plasma spray10.1016/j.surfcoat.2016.12.062 ↗
35. Characterization of graphene-nanoplatelets structure via thermogravimetry10.1021/acs.analchem.5b00228 ↗
36. Novel wear resistant carbide-laden coatings deposited by powder-suspension hybrid plasma spray: characterization and testing10.1016/j.surfcoat.2020.126147 ↗
37. Fracture toughness determinations by indentation10.1111/j.1151-2916.1976.tb10991.x ↗
38. Incorporation of graphene nano platelets in suspension plasma sprayed alumina coatings for improved tribological properties10.1016/j.apsusc.2021.151227 ↗
39. Wear performance of graphene nano platelets incorporated WC-Co coatings deposited by hybrid high velocity oxy fuel thermal spray
40. Perspectives on carbon nanotubes and graphene Raman spectroscopy10.1021/nl904286r ↗
41. Structural changes of thermal sprayed graphene nano platelets film into amorphous carbon under sliding wear10.1016/j.apsusc.2020.146315 ↗
42. Plasma sprayed carbon nanotube and graphene nanoplatelets reinforced alumina hybrid composite coating with outstanding toughness10.1016/j.jallcom.2017.08.160 ↗
43. The key process parameters influencing formation of columnar microstructure in suspension plasma sprayed zirconia coatings10.1016/j.surfcoat.2014.08.078 ↗
44. Column formation in suspension plasma-sprayed coatings and resultant thermal properties10.1007/s11666-011-9632-2 ↗
45. Advanced microscopic study of suspension plasma-sprayed zirconia coatings with different microstructures10.1007/s11666-015-0310-7 ↗
46. Heat and hydrothermal treatments on the microstructure evolution and mechanical properties of plasma sprayed hydroxyapatite coatings reinforced with graphene nanoplatelets10.1016/j.jmbbm.2019.103418 ↗
47. Phase stability of zirconia
48. Dense yttria stabilized zirconia: sintering and microstructure10.1016/S0272-8842(02)00099-8 ↗
49. Obtaining highly dense YSZ nanoceramics by pressureless, unassisted sintering10.1179/1743280415Y.0000000005 ↗
50. Thermal conductivity and thermal cyclic fatigue of multilayered Gd2Zr2O7/YSZ thermal barrier coatings processed by suspension plasma spray10.1016/j.surfcoat.2015.11.009 ↗
51. Erosion performance of suspension plasma spray thermal barrier coatings — a comparison with state of art coatings10.1016/j.surfcoat.2022.128311 ↗
52. Evolution of porosity in suspension thermal sprayed YSZ thermal barrier coatings through neutron scattering and image analysis techniques10.1016/j.jeurceramsoc.2021.04.020 ↗