journal article·2008-08

Synthesis and characterization of myristic acid capped silver nanoparticles

P. K. Khanna, Deepti Kulkarni, Rupinder K. Beri

Journal of Nanoparticle Research· Volume 10· Issue 6
Publisher page

Abstract

Reduction of silver myristate (AgMy) under mild thermal reaction conditions in a dipolar aprotic solvent i.e. N, N-dimethylformamide (DMF) has been carried out. UV–visible absorption measurements of dried and re-dispersible brown flocculants showed broad features of surface plasmon resonance (SPR) due to silver nanoparticles. The freshly isolated particles showed absorption bands at 414 and 485 nm, respectively, due to inter-particle coupling or clustering of silver ions and silver atoms. X-ray diffraction (XRD) pattern of fcc zero-valent silver resulted in crystallite size of about 10 nm. Scanning electron microscopy (SEM) revealed formation of rod shaped silver with increasing reaction temperature. Thermal analysis (TGA) showed about 10% weight loss due to organic capping.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Nanomaterials for catalytic reactions · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Brust M, Walker M, Bethell D, Schiffrin DJ, Whyman R (1994) Synthesis of thiol-derivatized gold nanoparticles in a two-phase liquid–liquid system. J Chem Soc Chem Commun: 801–80210.1039/C39940000801 ↗
2. Charan S, Singh N, Khanna PK, Patil KR (2006) Direct synthesis of nano-crystalline silver from the reaction between silver carboxylates and n-trioctyl phosphine. J Nanosci Nanotechnol 6:2095–210210.1166/jnn.2006.339 ↗
3. Chou K-S, Ren C-Y (2000) Synthesis of nanosized silver particles by chemical reduction method. Mater Chem Phys 64:241–24610.1016/S0254-0584(00)00223-6 ↗
4. de Barros RA, Martins CR, de Azevedo WM (2005) Writing with conducting polymer. Synth Metals 155:35–3810.1016/j.synthmet.2005.05.014 ↗
5. Duff DG, Baiker A, Edwards PP (1993) A new hydrosol of gold clusters. J Chem Soc Chem Commun 1:96–9810.1039/c39930000096 ↗
6. Ershov BG, Henglein A (1998) Time-resolved Investigation of early process in the reduction of Ag+ on polyacrylate in aqueous solution. J Phys Chem B 102:10667–1067110.1021/jp981907a ↗
7. Giersig M, Pastoriza-Santos I, Liz-Marzan LM (2004) Evidence of an aggregative mechanism during the formation of silver nanowire in DMF. J Mater Chem 14:607–61010.1039/B311454F ↗
8. Gould IR, Lenhard JR, Muenter AA, Godleski SA, Farid S (2000) Two-electron sensitization: a new concept for silver halide photography. J Am Chem Soc 122:11934–1194310.1021/ja002274s ↗
9. Green M, Allsop N, Wakefield G, Dobson PJ, Hutchison JL (2002) Trialkylphosphine oxide/amine stabilised silver nanocrystals—the importance of steric factors and Lewis basicity in capping agents. J Mater Chem 12:2671–267410.1039/B203974E ↗
10. Jin R, Cao YW, Mirkin CA, Kelly KL, Schatz GC, Zheng JG (2001) Photoinduced conversion of silver nanospheres to nanoprisms. Science 294:1901–190310.1126/science.1066541 ↗
11. Khanna PK, Subbarao VVVS (2003) Nanosized silver powder via reduction of silver nitrate by sodium formaldehyde sulfoxylate in acidic pH medium. Mater Lett 57:2242–224510.1016/S0167-577X(02)01203-X ↗
12. Lee G-J, Shin S-I, Kim Y-C, Oh S-G (2004) Preparation of silver nanorods through the control of temperature and pH of reaction medium. Mater Chem Phys 84:197–20410.1016/j.matchemphys.2003.11.024 ↗
13. Pastoriza-Santos I, Liz-Marzan LM (1999) Formation and stabilization of silver nanoparticles through reduction by N,N-dimethylformamide. Langmuir 15:948–95110.1021/la980984u ↗
14. Pastoriza-Santos I, Liz-Marzan LM (2002a) Formation of PVP protected metal nanoparticles in DMF. Langmuir 18:2888–289410.1021/la015578g ↗
15. Pastoriza-Santos I, Liz-Marzán LM (2002b) Synthesis of silver nanoprisms in DMF. Nano Lett 2(8):903 –90510.1021/nl025638i ↗
16. Pillai ZS, Kamat PV (2004) What factors control the size and shape of silver nanoparticles in the citrate ion reduction method? J Phys Chem B 108:945–95110.1021/jp037018r ↗
17. Rao CNR (1994) Chemical approaches to the synthesis of inorganic materials. Wiley, New York10.1016/B978-1-4832-8382-1.50158-0 ↗
18. Saponjic ZV, Csencsits R, Rajh T, Dimitrijevic NM (2003) Self-assembly of TOPO-derivatized silver nanoparticles into multilayered film. Chem Mater 15:4521–452610.1021/cm030381q ↗
19. Yamamoto M, Nakamoto M (2003) Novel preparation of mono-dispersed silver nanoparticles via amine adducts derived from insoluble silver myristate in alkylamine. J Mater Chem 13:2064–206510.1039/b307092a ↗
20. Yamamoto T, Wada Y, Sakata T, Mori H, Goto M, Hibino S, Yanagida S (2004) Microwave-assisted preparation of silver nanoparticles. Chem Lett 33:158–15910.1246/cl.2004.158 ↗
21. Wang Y, Toshima N (1997) Preparation of Pd–Pt bimetallic colloids with controllable core/shell structures. J Phys Chem B 101:5301–530610.1021/jp9704224 ↗