journal article·2021-11

Ion-exchanged LTA zeolite derived nepheline phase NaAlSiO4:Eu2+ ceramic phosphor for laser illumination

Yuxiao Fan, Hui Lin, Hongwei Liu, Linjing Zhang, Jiaying Wang, Qi Xie, Li Zhou, Ruijin Hong, Dawei Zhang, Yanna Tian, Jie Chen, Shengming Zhou

Ceramics International· Volume 47· Issue 21
Publisher page

Abstract

Abstract A reliable yellow phosphor converter that can be efficiently excited by a 405 nm bluish violet laser is in high demand for laser illumination applications. A NaAlSiO4:Eu2+ phosphor with a quantum efficiency reaching 92% was obtained using LTA zeolite as the raw material. NaAlSiO4:Eu2+ ceramics with suitable porosities for laser illumination were prepared from the phosphor powders via spark plasma sintering. The ceramics lost only 2% of the quantum efficiency compared to the powders, maintained good thermal quenching properties (30% drop at 150 °C), and showed good thermal conductivity (2.02 W‧m−1‧K−1). The NaAlSiO4:Eu2+ ceramic with 405 nm bluish violet lasers, with the increase in laser power density to 9.15 W/mm2, exhibited an increasing luminous flux (23.83–70.26 lm) and maintained a stable luminous efficacy (47.7–46.8 lm/W), and the temperature distribution of the ceramic remained uniform and stable under long-time laser irradiation. This indicates that the nepheline-phase NaAlSiO4:Eu2+ ceramic is a promising material for laser illumination.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Solid State Laser Technologies · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Highly thermally stable single-component white-emitting silicate glass for organic-resin-free white-light-emitting diodes[J]10.1021/am405228x ↗
2. Advanced red phosphors for white light-emitting diodes[J]10.1039/C6TC02695H ↗
3. Tunable white-light emission and energy transfer in single-phase Bi3+, Eu3+ co-doped Ba9Y2Si6O24 phosphors for UV w-LEDs[J]10.1016/j.jlumin.2019.05.057 ↗
4. A new‐generation color converter for high‐power white LED: transparent Ce3+: YAG phosphor-in-glass[J]10.1002/lpor.201300140 ↗
5. Light emitting diodes reliability review[J]10.1016/j.microrel.2011.07.063 ↗
6. Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition[J10.1038/s41377-019-0148-8 ↗
7. Site occupancy preference, enhancement mechanism, and thermal resistance of Mn4+ red luminescence in Sr4Al14O25: Mn4+ for warm WLEDs[J]10.1021/acs.chemmater.5b00226 ↗
8. Pressure-stimulated synthesis and luminescence properties of microcrystalline (Lu, Y)3Al5O12: Ce3+ garnet phosphors[J]10.1021/acsami.5b08411 ↗
9. Structure evolution and photoluminescence of Lu3(Al, Mg)2(Al, Si)3O12: Ce3+ phosphors: new yellow-color converters for blue LED-driven solid state lighting[J]10.1039/C6TC00966B ↗
10. Green emitting Ba1. 5Lu1. 5Al3. 5Si1. 5O12: Ce3+ phosphor with high thermal emission stability for warm WLEDs and FEDs[J]10.1016/j.ceramint.2019.11.037 ↗
11. Comparison between blue lasers and light‐emitting diodes for future solid-state lighting[J]10.1002/lpor.201300048 ↗
12. Efficiency droop in light‐emitting diodes: challenges and countermeasures[J]10.1002/lpor.201200025 ↗
13. β-Sialon: Eu phosphor-in-glass: a robust green color converter for high power blue laser lighting[J]10.1039/C5TC02236C ↗
14. CaAlSiN3: Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting[J]10.1039/C6TC02518H ↗
15. Ceramic phosphors for light conversion in LEDs[J]10.1149/2.023302jss ↗
16. Color conversion materials for high-brightness laser-driven solid-state lighting[J]10.1002/lpor.201800173 ↗
17. Unique color converter architecture enabling phosphor-in-glass (PiG) films suitable for high-power and high-luminance laser-driven white lighting[J]10.1021/acsami.8b03168 ↗
18. Down-conversion nitride materials for solid state lighting: recent advances and perspectives[J]10.1021/acs.chemrev.7b00284 ↗
19. Laser-based lighting: experimental analysis and perspectives[J]10.3390/ma10101166 ↗
20. Development of β-SiAlON:Eu2+ phosphor in glass for high-power LED- and LD-based lighting systems using original BaO-B2O3-ZnO-SiO2 (BBZS) composition glass[J]10.1016/j.jallcom.2019.04.203 ↗
21. Efficient and heat-conducting color converter of phosphor glass film printed on sapphire substrate for high-power white LEDs/LDs[J]10.1016/j.jnoncrysol.2019.04.026 ↗
22. High power and temperature luminescence of Y3Al5O12: Ce3+ bulky and pulverized single crystal phosphors by a floating-zone method[J]10.1016/j.jlumin.2015.08.045 ↗
23. Strong thermal stability of Lu3Al5O12: Ce3+ single crystal phosphor for laser lighting[J]10.1016/j.jlumin.2017.01.032 ↗
24. Ternary solid solution phosphors Ca1-x-yLixAl1-x-ySi1+x+yN3-yOy:Ce3+ with enhanced thermal stability for high-power laser lighting[J]10.1016/j.cej.2020.126575 ↗
25. Gd3Al3Ga2O12: Ce, Mg2+ transparent ceramic phosphors for high-power white LEDs/LDs[J]10.1016/j.ceramint.2020.11.140 ↗
26. Additive-free Y2O3: Eu3+ red-emitting transparent ceramic with superior thermal conductivity for high-power UV LEDs and UV LDs[J]10.1016/j.jeurceramsoc.2020.02.005 ↗
27. Transparent Ce: GdYAG ceramic color converters for high-brightness white LEDs and LDs[J]10.1016/j.optmat.2018.11.031 ↗
28. Energy of the first 4f7→4f65d transition of Eu2+ in inorganic compounds[J]10.1016/S0022-2313(03)00078-4 ↗
29. Emission color variation of M2SiO4:Eu2+ (M=Ba, Sr, Ca) phosphors for light-emitting diode[J]10.1016/j.ssc.2004.10.017 ↗
30. Structural and luminescence properties of yellow-emitting NaScSi2O6:Eu2+ phosphors: Eu2+ site preference analysis and generation of red emission by codoping Mn2+ for white-light-emitting diode applications[J]10.1021/jp4062225 ↗
31. New yellow-emitting whitlockite-type structure Sr1. 75Ca1. 25(PO4)2:Eu2+ phosphor for near-UV pumped white light-emitting devices[J]10.1021/ic500230v ↗
32. Structural evolution induced preferential occupancy of designated cation sites by Eu2+ in M5(Si3O9)2 (M=Sr, Ba, Y, Mn) phosphors[J]10.1039/C6RA11681G ↗
33. Control of NaAlSiO4:Eu2+ photoluminescence properties by charge-compensated aliovalent element substitutions[J]10.1080/15980316.2012.691079 ↗
34. Synthesis and photoluminescence properties of new NaAlSiO4: Eu2+ phosphors for near-UV white LED applications[J]10.1016/j.optmat.2011.10.004 ↗
35. The rheology of collapsing zeolites amorphized by temperature and pressure[J]10.1038/nmat963 ↗
36. Routes of synthesis of nepheline-type polymorphs: an influence of Na-LTA bulk composition on its thermal transformations[J]10.1016/j.jpcs.2013.03.019 ↗
37. Blue/red dual color up-conversion emission from Tm3+, Yb3+ co-activated nepheline particles derived from LTA zeolites[J]10.1088/2053-1591/aaf525 ↗
38. Composite phase ceramic phosphor of Al2O3-Ce: YAG for high efficiency light emitting[J]10.1364/OE.23.017923 ↗
39. Phase composition, microstructure and luminescent property evolutions in “light-scattering enhanced” Al2O3-Y3Al5O12:Ce3+ ceramic phosphors[J]10.1016/j.jeurceramsoc.2018.03.043 ↗
40. The synthesis and photoluminescence of a single-phased white-emitting NaAlSiO4:Ce3+, Mn2+ phosphor for WLEDs[J]10.1016/j.materresbull.2015.08.006 ↗
41. Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO4 modification[J]10.2138/am-1998-5-623 ↗
42. A carnegieite type red emitting NaAlSiO4: Eu3+ phosphor: concentration dependent time resolved photoluminescence and Judd-Ofelt analysis[J]10.1016/j.jlumin.2019.02.002 ↗
43. Ionic conductivity in low carnegieite compositions based on NaAlSiO4[J]10.1016/0025-5408(79)90101-6 ↗
44. Use of diffuse reflectance spectroscopy for optical characterization of un-supported nanostructures[J]
45. Metastable Sr0.5TaO3 perovskite oxides prepared by nanosheet processing[J]
46. Great emission enhancement of high-efficient broadband K3YSi2O7: Eu red phosphor via enhancing crystallinity[J]10.1016/j.jallcom.2020.157188 ↗
47. Lanthanide-activated phosphors based on 4f-5d optical transitions: theoretical and experimental aspects[J]10.1021/acs.chemrev.6b00691 ↗
48. Measured luminance and visual appearance of multi-color persistent phosphors[J]10.1364/OE.17.000358 ↗
49. Photoluminescent properties of ABaPO4: Eu (A= Na, K) phosphors prepared by the combustion‐assisted synthesis method[J]10.1111/j.1551-2916.2009.02996.x ↗
50. An empirical relation fitting the position in energy of the lower d-band edge for Eu2+ or Ce3+ in various compounds[J]10.1016/0022-2313(84)90036-X ↗
51. A novel wide-excitation and narrow-band blue-emitting phosphor with hafnium silicon multiple rings structure for photoluminescence and cathodoluminescence[J]10.1016/j.jallcom.2020.154825 ↗
52. Theory of concentration quenching in inorganic phosphors[J]10.1063/1.1740265 ↗
53. The structure, device physics, and material properties of thin film electroluminescent displays[J]10.1016/S0927-796X(97)00010-7 ↗
54. Temperature and Eu2+-doping induced phase selection in NaAlSiO4 polymorphs and the controlled yellow/blue emission[J]10.1021/acs.chemmater.7b02548 ↗