journal article·2018-12

Porosity induced thermoelectric performance optimization for antimony telluride

Yixi Gu, Xiaowei Liu, Shan Huang, Jingjing Guo, Peng Bi, Jing Shi, Wenwen Zheng, Ziyu Wang, Rui Xiong

Ceramics International· Volume 44· Issue 17
Publisher page

Abstract

Abstract Sb 2 Te 3 bulks with various porosities are synthesized via applying different pressures and processes. Pores defect variations are demonstrated by positron annihilation spectroscopy measurement. Through tuning sintering temperature and pressure exerted in one step or two steps, pores and interfaces of the materials are tailored, which enhances the Seebeck coefficient, simultaneously maintains high electrical conductivity and remarkably reduces thermal conductivity. A maximum ZT of 1.17 is obtained at 523 K for Sb 2 Te 3 samples compacted in two steps under 10 kN, increasing by 54.1% as compared to corresponding sample under 1 kN. Lattice thermal conductivity calculation by modified BET model combining with effective medium theory fits with experiments data, revealing porosity manipulation plays a significant role in reducing thermal conductivity.
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Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Thermal properties of materials · Thermal Radiation and Cooling Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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