journal article·2022-03

Thermal behavior, structure, crystallization and solubility of the melt-derived SiO2–P2O5–Na2O–F-MO (M = Ca, Sr, Zn) glasses

Cui Li, Lidan Liu, Xi He, Zhenhai Bo, Taoyong Liu, Anxian Lu

Ceramics International· Volume 48· Issue 6
Publisher page

Abstract

Abstract In this work, phospho-silicate glasses with SiO2–P2O5–Na2O–F-MO (M = Ca, Sr, Zn) composition were prepared by using the conventional melt quenching technology. Structural, physical, and chemical property tests were used to analyze the effects of different SrO and ZnO content on the structure and properties of the glasses. The results showed that the glass stability varied nonlinearly as CaO was replaced by SrO, which was mainly related to the different positions of Sr2+ and Ca2+ ions breaking the network connection in the network structure, and the substitution of ZnO for CaO led to a continuous decrease in the stability of the glasses. The immersion experiment showed that SrO doping was more feasible than ZnO doping to improve the biological activity of the glasses, and the doping of ZnO promoted the dissolution of ions in the glasses. The obtained results indicated that the glass samples prepared in this paper have potential biological activity, which has potential applications in dental treatment.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Bone Tissue Engineering Materials · Glass properties and applications · Dental materials and restorations

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Facile synthesis of hollow mesoporous bioactive glasses with tunable shell thickness and good monodispersity by micro-emulsion method10.1016/j.matlet.2016.12.004 ↗
2. Biodegradable borosilicate bioactive glass scaffolds with a trabecular microstructure for bone repair10.1016/j.msec.2013.12.023 ↗
3. Bioactive glass ions as strong enhancers of osteogenic differentiation in human adipose stem cell10.1016/j.actbio.2015.04.017 ↗
4. Evaluation of zinc and magnesium doped 45S5 mesoporous bioactive glass system for the growth of hydroxyl apatite layer10.1016/j.jnoncrysol.2014.09.050 ↗
5. Surface nitridation improves bone cell response to melt-derived bioactive silicate/borosilicate glass composite scaffolds10.1016/j.actbio.2015.10.006 ↗
6. In vitro bioactivity evaluation, mechanical properties and microstructural characterization of Na2O–CaO–B2O3–P2O5 glasses10.1016/j.saa.2015.02.076 ↗
7. Enhanced bioactivity, biocompatibility and mechanical behavior of strontium substituted bioactive glasses10.1016/j.msec.2016.06.070 ↗
8. Influence of ZnO addition on the structural, in vitro behavior and antimicrobial activity of sol–gel derived CaO–P2O5–SiO2 bioactive glasses10.1016/j.ceramint.2015.10.090 ↗
9. B2O3–MgO–SiO2–Na2O–CaO–P2O5–ZnO bioactive system for bone regeneration applications10.1016/j.ceramint.2015.11.029 ↗
10. Reprint of: review of bioactive glass: from Hench to hybrids10.1016/j.actbio.2015.07.019 ↗
11. Bioactivity characterization of 45S5 bioglass using TL, OSL and EPR: comparison with the case of 58S sol-gel bioactive glass10.1016/j.msec.2016.09.051 ↗
12. Role of magnesium oxide and strontium oxide as modifiers in silicate-based bioactive glasses: effects on thermal behaviour, mechanical properties and in-vitro bioactivity10.1016/j.msec.2016.11.110 ↗
13. The future of bioactive ceramics10.1007/s10856-015-5425-3 ↗
14. Sol-gel synthesis and laser fusion of Tibonding porcelain hybrid coatings on titanium10.1007/s10971-017-4327-x ↗
15. Review of bioactive glass: from Hench to hybrids10.1016/j.actbio.2012.08.023 ↗
16. Individual and combined effects of the elements Zn, Mg and Sr on the surface reactivity of a SiO2–CaO–Na2O–P2O5 bioglass system10.1016/j.jnoncrysol.2013.11.038 ↗
17. Characterization and fracture property of different strontium-containing borate-based glass coatings for Ti6Al4V substrates10.1016/j.jnoncrysol.2016.12.010 ↗
18. F-substituted hydroxyapatite nanopowders: thermal stability, sintering behaviour and mechanical properties10.1016/j.ceramint.2009.09.007 ↗
19. Crystallisation kinetics, glass forming ability and thermal stability in glassy Se100–x Inx chalcogenide alloys10.1016/j.jnoncrysol.2011.07.033 ↗
20. Glass-forming ability, sinter-crystallization behavior and microwave dielectric properties of MgO-B2O3-(Al2O3)-SiO2 glass-ceramics10.1016/j.jnoncrysol.2016.03.014 ↗
21. Characterization of structure and properties of MgO-Al2O3-SiO2-B2O3-Cr2O3 glass-ceramics10.1016/j.jnoncrysol.2020.120154 ↗
22. Elastic properties and structural studies on some zinc-borate glasses derived from ultrasonic, FT-IR and X-ray techniques10.1016/j.jallcom.2008.07.114 ↗
23. Influence of magnesia on the structure and properties of bioactive glasses10.1016/j.jnoncrysol.2009.04.074 ↗
24. Preparation, crystallization kinetics and microwave dielectric properties of CaO-ZnO-B2O3-P2O5-TiO2 glass-ceramics10.1016/j.ceramint.2019.01.126 ↗
25. Effect of replacement of B2O3 by ZnO on preparation and properties of transparent cordierite-based glass-ceramics10.1016/j.jnoncrysol.2015.10.017 ↗
26. Nitrogen coordination in oxynitride glasses10.1111/j.1151-2916.1984.tb18834.x ↗
27. Transformation range viscosity of fluorozirconate glasses10.1111/j.1151-2916.1984.tb19183.x ↗
28. Model quasi-molecule Si2O as an approach in the IR spectra description glassy and crystalline framework silicates10.1016/0022-2860(95)08658-I ↗
29. The influence of Na+ and Ca2+ ions on the SiO2–AlPO4 materials structure-IR and Raman studies10.1016/S0022-2860(01)00708-6 ↗
30. Infrared spectroscopy of different phosphates structures10.1016/j.saa.2010.08.044 ↗
31. Melt-derived bioactive glass based on SiO2-CaO-Na2O-P2O5 system fabricated at lower melting temperature10.1016/j.jallcom.2017.10.235 ↗
32. Fourier transform infrared spectroscopic characterization of kaolinite from Assam and Meghalaya, Northeastern India10.4236/jmp.2010.14031 ↗
33. Free volume and structure of Gd2O3 and Y2O3 Co-doped silicate glasses10.1016/j.jnoncrysol.2013.08.003 ↗
34. The evolution of the network structure in tin-fluoro-phosphate glass with increasing temperature10.1016/j.jnoncrysol.2018.03.052 ↗
35. Structural investigations of phosphate glasses: a detailed infrared study of the x(PbO)-(1-x) P2O5 vitreous system10.1007/BF00356615 ↗
36. Effect of compositional changes on the structure and properties of alkali-alumino borosilicate glasses10.1007/s10854-005-5139-2 ↗
37. Analysis of structure evolution and performance in alkali-free glass substrates via XPS and infrared: boron-aluminum anomaly10.1016/j.jnoncrysol.2020.120531 ↗
38. Glass forming, crystallization, and physical properties of MgO-Al2O3-SiO2-B2O3 glass-ceramics modified by ZnO replacing MgO10.1016/j.jeurceramsoc.2018.10.002 ↗
39. Melt-derived bioactive glass scaffolds produced by a gel-cast foaming technique10.1016/j.actbio.2010.11.041 ↗
40. Mineral formation on dentin induced by nano-bioactive glass10.1016/j.cclet.2016.03.030 ↗
41. Preparation and biocompatibility evaluation of bioactive glass–forsterite nanocomposite powder for oral bone defect treatment applications10.1016/j.msec.2015.07.002 ↗
42. The mechanism of borosilicate glass corrosion revisited10.1016/j.gca.2015.02.039 ↗
43. Reactivity kinetics of 52S4 glass in the quaternary system SiO2–CaO–Na2O–P2O5: influence of the synthesis process: melting versus sol–gel10.1016/j.jnoncrysol.2012.10.013 ↗
44. Physico-chemical and in vitro biological evaluation of strontium/calcium silicophosphate glass10.1007/s10856-009-3920-0 ↗
45. Effect of MgO on bioactivity, hardness, structural and optical properties of SiO2-K2O-CaO-MgO glasses10.1016/j.ceramint.2015.08.128 ↗
46. Sr-containing bioglass fabricated by sol-gel method and its solubility
47. Influence of strontium and the importance of glass chemistry and structure when designing bioactive glasses for bone regeneration10.1016/j.actbio.2010.01.006 ↗
48. The effect of zirconium incorporation on the physiochemical and biological properties of mesoporous bioactive glasses scaffolds10.1016/j.micromeso.2011.03.007 ↗
49. Preparation and in vitro bioactivity of zinc containing sol–gel-derived bioglass materials10.1002/jbm.a.20070 ↗