journal article·2018-11

An investigation of Mn4+ doped BeAl2O4 single crystal for WLEDs application

Jianxu Hu, Yun Zhao, Baojiu Chen, Haiping Xia, Yuanpeng Zhang, Huanqing Ye

Ceramics International· Volume 44· Issue 16
Publisher page

Abstract

Abstract A novel red-emitting Mn4+ doped BeAl2O4 single crystal is synthesized by a Czochralski technique. Narrow red emission is observed from the Mn4+ ions occupying Al3+ sites in distorted octahedrons. Crystal field parameter Dq, Racah parameters B and C are determined to be 2392, 1423 and 3332 cm−1, respectively. The value of Dq/B indicates that Mn4+ ions are in a weak crystal field. The quenching temperature and activation energy are calculated from the temperature-dependent measurement for emission intensity and decay time. A detailed discussion of thermal quenching mechanism reveals that the crossover via the 4T2 level is the main quenching route in the prepared material.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Microwave Dielectric Ceramics Synthesis · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. A revolution in lighting10.1038/nmat4270 ↗
2. Advances in phosphors for light-emitting diodes10.1021/jz2002452 ↗
3. Preparation of CaAlSiN3: Eu2+ phosphors by the self-propagating high-temperature synthesis and their luminescent properties10.1021/cm070623c ↗
4. A double substitution of Mg2+–Si4+/Ge4+ for Al(1)3+–Al(2)3+ in Ce3+-doped garnet phosphor for white LEDs10.1021/ic501063j ↗
5. A novel phosphor for glareless white light-emitting diodes10.1038/ncomms2138 ↗
6. Solid-state light sources getting smart10.1126/science.1108712 ↗
7. Temperature quenching of yellow Ce3+ luminescence in YAG:Ce10.1021/cm8030768 ↗
8. Insight into the thermal quenching mechanism for Y3Al5O12:Ce3+ through thermoluminescence excitation spectroscopy10.1021/acs.jpcc.5b08828 ↗
9. Status and future of high-power light-emitting diodes for solid-state lighting10.1109/JDT.2007.895339 ↗
10. Hydrothermal synthesis, morphology and photoluminescent properties of an Mn4+-doped novel red fluoride phosphor elpasolite K2LiAlF610.1039/C6TC01366J ↗
11. Photoluminescence tuning of Ca5(PO4)3Cl:Ce3+/Eu2+,Tb3+/Mn2+ phosphors: structure refinement, site occupancy, energy transfer and thermal stability10.1039/C5TC03482E ↗
12. Wide color gamut backlight for liquid crystal displays using three-band phosphor-converted white light-emitting diodes10.1143/APEX.2.022401 ↗
13. Site occupancy preference, enhancement mechanism, and thermal resistance of Mn4+ red luminescence in Sr4Al14O25:Mn4+ for warm WLEDs10.1021/acs.chemmater.5b00226 ↗
14. Near-ultraviolet light excited deep blue-emitting phosphor for solid-state lighting10.1016/j.jallcom.2009.04.038 ↗
15. Structural and optical properties of BaMgAl10O17:Eu2+ phosphor10.1021/cm020592f ↗
16. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes10.1038/ncomms5312 ↗
17. Warm-white light-emitting diode with yellowish orange SiAlON ceramic phosphor10.1364/OL.29.002001 ↗
18. Narrow-band red-emitting Sr[LiAl3N4]:Eu2+ as a next-generation LED-phosphor material10.1038/nmat4012 ↗
19. Electronic structure descriptor for the discovery of narrow-band red-emitting phosphors10.1021/acs.chemmater.6b01496 ↗
20. Yellow-orange-emitting CaAlSiN3:Ce3+ phosphor: structure, photoluminescence, and application in white LEDs10.1021/cm801669x ↗
21. Preparation of CaAlSiN3:Eu2+ phosphors by the self-propagating high-temperature synthesis and their luminescent properties10.1021/cm070623c ↗
22. Comparative analysis of crystal field effects and optical spectroscopy of six-coordinated Mn4+ ion in the Y2Ti2O7 and Y2Sn2O7 pyrochlores10.1016/j.optmat.2011.05.008 ↗
23. A red phosphor BaTiF6:Mn4+: reaction mechanism, microstructures, optical properties, and applications for white LEDs10.1039/C4DT00781F ↗
24. Synthesis of K2SiF6:Mn4+ phosphor from SiO2 powders via redox reaction in HF/KMnO4 solution and their application in warm-white LED10.1111/jace.12533 ↗
25. Hydrothermal synthesis and photoluminescence properties of red phosphor BaSiF6:Mn4+ for LED applications10.1039/c3tc31878h ↗
26. Narrow red emission band fluoride phosphor KNaSiF6:Mn4+ for warm white light-emitting diodes10.1021/acsami.6b01905 ↗
27. Waterproof alkyl phosphate coated fluoride phosphors for optoelectronic materials10.1002/anie.201504791 ↗
28. Synthesis of Na2SiF6:Mn4+ red phosphors for white LED applications by co-precipitation10.1039/C4TC02062F ↗
29. The design and preparation of the thermally stable, Mn4+ ion activated, narrow band, red emitting fluoride Na3GaF6: Mn4+ for warm WLED applications10.1039/C7TC00011A ↗
30. CaMg2Al16O27:Mn4+-based red phosphor: a potential color converter for high-powered warm W-LED10.1021/am507316b ↗
31. Fluorescence properties of Mn4+ in CaAl12O19 compounds as red-emitting phosphor for white LED10.1016/j.jlumin.2005.01.003 ↗
32. A novel efficient Mn4+ activated Ca14Al10Zn6O35 phosphor: application in red-emitting and white LEDs10.1021/ic501641q ↗
33. Highly efficient and stable narrow-band red phosphor Cs2SiF6:Mn4+ for high-power warm white LED applications10.1021/acsphotonics.7b00852 ↗
34. Enhanced luminescence performances of tunable Lu3–xYxAl5O12:Mn4+ red phosphor by ions of Rn+(Li+, Na+, Ca2+, Mg2+, Sr2+, Sc3+)10.1021/acs.inorgchem.6b02647 ↗
35. Robust thermal performance of Sr2Si5N8:Eu2+: an efficient red emitting phosphor for light emitting diode based white lighting10.1063/1.3666785 ↗
36. Novel La3GaGe5O16:Mn4+ based deep red phosphor: a potential color converter for warm white light10.1039/C5RA18163A ↗
37. The luminescence of tetravalent manganese in CaZrO3:Mn10.1016/0022-1902(81)80325-9 ↗
38. A review on Mn4+ activators in solids for warm white light-emitting diodes10.1039/C6RA19584A ↗
39. Spectroscopic properties of Mn4+ ions in SrLaAlO410.1016/j.optmat.2013.04.028 ↗
40. Radiative and nonradiative processes in LiGa5O8:Mn4+10.1016/0921-4526(93)90192-9 ↗
41. Dependence of the optical properties of Mn4+ activated A2Ge4O9 (A= K, Rb) on temperature and chemical environment10.1016/j.jlumin.2016.04.046 ↗
42. Luminescence properties of SrSi2O2N2 doped with divalent rare earth ions10.1016/j.jlumin.2005.11.008 ↗
43. Multiple-phonon nonradiative relaxation: experimental rates in fluoride crystals doped with Er3+ and Nd3+ ions and a theoretical model10.1103/PhysRevB.49.3821 ↗
44. Quenching of the red Mn4+ luminescence in Mn4+-doped fluoride LED phosphors10.1038/s41377-018-0013-1 ↗