Effect of TiO2 on glass structure control of self-crystallized Ba2LaF7 glass-ceramics
Source abstract
Abstract
The structural regulations of Ba2LaF7 self-crystallized glass-ceramics were successfully analyzed by adjusting the concentration of the doped TiO2. Increasing the doping concentration of TiO2 tightened the internal structure of the glass and depleted the self-crystallization of Ba2LaF7. Further analysis revealed that TiO2 acts as a nucleating agent in the glass-ceramics. However, the number of the crystal nuclei increased, and the growth of the crystal grains was reduced. The change in the internal structure of the glass-ceramics was due to the varying self-crystallization process of Ba2LaF7 in the glass-ceramics and was not directly caused by the incorporation of TiO2.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Glass properties and applications · Microwave Dielectric Ceramics Synthesis · Luminescence Properties of Advanced Materials
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References (25)
Show source-provided references
1. Catalyzed crystallization of glass in theory and practice10.1021/ie50595a022 ↗
2. Enhanced emissions in self-crystallized oxyfluoride scintillating glass ceramics containing KTb_2F_7 nanocrystals10.1364/OME.6.002201 ↗
3. Optical thermometry based on up-conversion luminescence behavior of self-crystallized K3YF6:Er3+ glass ceramics10.1016/j.snb.2015.10.087 ↗
4. Ce3+ dopants-induced spectral conversion from green to red in the Yb/Ho: NaLuF4 self-crystallized nano-glass-ceramics10.1016/j.jallcom.2015.09.146 ↗
5. Tunable upconversion luminescence in self-crystallized Er3+:K(Y1-xYbx)3F10 nano-glass-ceramics10.1039/C4CP05706F ↗
6. Lanthanide-doped KGd3F10 nanocrystals embedded glass ceramics: self-crystallization, optical properties and temperature sensing10.1016/j.jallcom.2018.07.165 ↗
7. Eu3+ and Er3+ doped NaLu1-xYbxF4 (x=01) solid-solution self-crystallization nano-glass-ceramics: microstructure and optical spectroscopy10.1016/j.jeurceramsoc.2015.05.031 ↗
8. Self-crystallized Ba2LaF7:Nd3+/Eu3+ glass ceramics for optical thermometry10.1016/j.ceramint.2017.08.013 ↗
9. Rare-earth-doped transparent glass ceramics
10. Transparent oxyfluoride glass ceramics10.1016/j.jfluchem.2015.01.009 ↗
11. Suppression of crystalline fluctuations by competing structures in a supercooled liquid10.1103/PhysRevE.96.042602 ↗
12. Structural fluctuations in glass-forming liquids: Mössbauer spectroscopy on iron in glycerol10.1103/PhysRevB.43.3345 ↗
13. Effect of melting temperature on the structure of self-crystallized Ba2LaF7 glass-ceramics10.1016/j.jnoncrysol.2019.119579 ↗
14. Progress in Materials Science Transparent glass-ceramics functionalized by dispersed crystals10.1016/j.pmatsci.2018.02.006 ↗
15. Ali · 2017
16. Tiwari · 2009 · vol. 404 · 47
17. Raman study of b -irradiated glasses10.1016/S0022-3093(98)00822-9 ↗
18. Structural roles of boron and silicon in the CaO-SiO2 -B2O3 glasses using FTIR, Raman, and NMR spectroscopy10.1007/s11663-015-0374-2 ↗
19. Sio · 2015 · vol. 420 · 26
20. Hemley · 2000 · vol. 57 · 2
21. The influence of silica nanoparticles addition on the physical, mechanical, thermo-mechanical as well as microstructure of Mag-Dol refractory composites10.1016/j.ceramint.2017.09.073 ↗
22. Structural characterisation of Er – Si – Al – O – N glasses by Raman spectroscopy10.1016/j.jeurceramsoc.2006.04.058 ↗
23. Infrared and Raman spectra of calcium alumino - silicate glasses10.1016/S0022-3093(98)00688-7 ↗
24. Li · 2018
25. Optimization of La 2 O 3 -containing diopside based glass-ceramic sealants for fuel cell applications10.1016/j.jpowsour.2009.01.013 ↗