journal article·2019-06

Dispersion and gelation properties of alumina systems with Isobam assisted by dicarboxylic acids

Yuju Lu, Ke Gan, Jie Xu, Lin Lv, Wenlong Huo, Jingjing Liu, Xiaoyan Zhang, Jinlong Yang

Ceramics International· Volume 45· Issue 9
Publisher page

Abstract

Abstract Isobam, a copolymer of isobutylene and maleic anhydride, is a newly developed gelling agent for ceramic colloidal forming. However, the Isobam system exposes a weakness of high viscosity when solids loading exceeds 54 vol%. Suitable additives to effectively decrease viscosity and have minimal impact on gelation strength were discovered from various dicarboxylic acids through investigation on zeta potential, viscosity of suspensions, shear modulus during gelation and yield stress and modulus of elasticity of wet green bodies. Alumina ceramics with flexural strength of 442 ± 49 MPa and a Weibull modulus of 10.8 were produced from 54 vol% suspensions with 0.5 wt% Isobam assisted by 0.04 wt% phthalic acid and 0.03 wt% oxalic acid after pressureless sintering.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Injection Molding Process and Properties · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. Recent developments in gelcasting of ceramics10.1016/j.jeurceramsoc.2010.12.035 ↗
3. Gelcasting: from laboratory development toward industrial production10.1016/S0955-2219(96)00147-1 ↗
4. Alumina gelcasting by using HEMA system10.1016/j.jeurceramsoc.2004.04.024 ↗
5. Gelcasting performance of alumina aqueous suspensions with glycerol monoacrylate: a new low-toxicity acrylic monomer10.1111/j.1551-2916.2007.01556.x ↗
6. Protein forming a novel shaping technique for ceramics10.1016/S0955-2219(00)00136-9 ↗
7. Gelatin gelcasting of ceramic components10.1016/S0924-0136(02)00862-2 ↗
8. Alumina bodies with near-to-theoretical density by aqueous gelcasting using concentrated agarose solutions10.1016/j.ceramint.2004.06.007 ↗
9. Gelcasting of alumina suspension using gellan gum as gelling agent10.1016/j.ceramint.2013.11.010 ↗
10. Room-temperature gelcasting of alumina with a water-soluble copolymer10.1557/jmr.2013.132 ↗
11. Dispersion and gelation behavior of alumina suspensions with Isobam10.1016/j.ceramint.2018.03.185 ↗
12. Fabrication of transparent Y2O3 ceramics via aqueous gelcasting10.1016/j.ceramint.2014.01.106 ↗
13. Spontaneous gelcasting of translucent alumina ceramics10.1364/OME.3.001000 ↗
14. Gelcasting of transparent YAG ceramics by a new gelling system10.1016/j.ceramint.2014.04.125 ↗
15. Aqueous gelcasting of the transparent MgAl2O4 spinel ceramics10.1016/j.jallcom.2015.05.275 ↗
16. The microstructure and mechanical properties of porous silicon nitride ceramics prepared via novel aqueous gelcasting10.1111/ijac.12424 ↗
17. Fabrication of porous SiC ceramics through a modified gelcasting and solid state sintering10.1016/j.msea.2015.12.061 ↗
18. Near-net-shape processed ZnS ceramics by aqueous casting and pressureless sintering10.1016/j.ceramint.2016.04.074 ↗
19. Direct coagulation casting of silicon carbide components10.1111/j.1151-2916.1999.tb01886.x ↗
20. Rapid coagulation of silicon carbide slurry via direct coagulation casting10.1016/S0272-8842(03)00125-1 ↗
21. A method for gelcasting high-strength alumina ceramics with low shrinkage10.1557/jmr.2013.381 ↗
22. Direct coagulation casting of alumina suspension from calcium citrate assisted by pH shift10.1111/jace.12835 ↗
24. Influence of TAC on dispersion of aqueous nano alumina suspension10.1007/BF02835047 ↗
25. Shear modulus of colloidal suspensions: comparing experiments with theory10.1016/j.jcis.2008.12.034 ↗
26. In situ coagulation moulding: a new route for high quality, net-shape ceramics10.1016/j.ceramint.2004.12.006 ↗