journal article·2014-01

Spectroscopic and structural features of Eu3+-doped zinc pyrophosphate ceramic

Lin Qin, Chuanyan Xu, Yanlin Huang, Sun Il Kim, Hyo Jin Seo

Ceramics International· Volume 40· Issue 1
Publisher page

Abstract

Abstract Eu3+-doped pyrophosphate ceramic SrZnP2O7 was prepared by the solid-state reaction method. The ceramic was investigated by XRD, SEM, photoluminescence excitation and emission spectra, and decay curves. The red luminescence only arises from the 5D0 level of Eu3+ ions. The microstructure was investigated by the luminescence probe of Eu3+ ion. There are two kinds of Eu3+ luminescence centers, which occupy both Sr2+ and Zn2+ sites. The energy transfers could only be detected from the Eu3+ ions doped on Zn2+-sites to those on Sr2+-sites. The possible defects and charge compensation mechanisms were discussed on the base of crystal structure and luminescence properties. Besides, the reason why the luminescence of Eu3+ doped on Zn2+-sites is quenched at room-temperature was analyzed.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · Microwave Dielectric Ceramics Synthesis

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References (38)

Show source-provided references
1. Luminescence improvement of Y2O2S:Tb3+, Sr2+, Zr4+ white-light long-lasting phosphor via Eu3+ addition10.1016/j.ceramint.2013.02.064 ↗
2. Multiwavelength excited white-emitting Dy3+ doped Sr3Bi(PO4)3 phosphor10.1016/j.ceramint.2013.02.044 ↗
3. White light emission from Eu3+ co-activated Ca2Gd8Si6O26:Dy3+ nanophosphors by solvothermalsynthesis10.1016/j.ceramint.2013.01.057 ↗
4. Synthesis and electrical properties of co-doping with La3+, Nd3+, Y3+, and Eu3+ citric acid-nitrate prepared samarium-doped ceria ceramics10.1016/j.ceramint.2012.10.230 ↗
5. Polyacrylamide gel synthesis and sintering of Mg2SiO4:Eu3+ nanopowder10.1016/j.ceramint.2013.01.056 ↗
6. Structural and spectroscopic properties of Nd3+:Y2Si2O7 phosphors10.1016/j.ceramint.2013.01.017 ↗
7. Effect of sintering atmosphere and lithium ion co-doping on photoluminescence properties of NaCaPO4:Eu2+ phosphor10.1016/j.ceramint.2012.04.082 ↗
8. Synthesis and optical characterization of novel Sr3Ga2O6:Eu3+ phosphor10.1016/j.ceramint.2012.05.075 ↗
9. Crystal structure of alpha-calcium pyrophosphate10.1021/ic50065a019 ↗
10. Crystallographic character of the Sr2−xMgxP2O7 system10.1149/1.2410902 ↗
11. SrMgP2O7
12. The crystal structure of alpha-Sr2P2O710.3891/acta.chem.scand.22-1419 ↗
13. Luminescent properties of Sr2P2O7:Eu, Mn phosphor under near UV excitation10.1016/j.materresbull.2007.07.039 ↗
14. White light emitting diode by using α-Ca2P2O7:Eu2+, Mn2+ phosphor10.1063/1.2752725 ↗
15. Magnetic properties of isostructural BaCoP2O7, BaNiP2O7, and BaCuP2O7 studied with dc and ac magnetization and specific heat10.1021/ic050938z ↗
16. Synthesis, crystal structure, and magnetic investigations of FePb1−xBaxP2O7 (0≤x<1)10.1016/j.matlet.2004.05.018 ↗
17. Synthesis and characterization of new copper (II) mixed diphosphates (M,Cu)2P2O7 with M=Mg, Ca, Sr, and Ba10.1016/0022-4596(90)90026-T ↗
18. Microwave dielectric properties of BaTiO3–SrZnP2O7 composite ceramics for tunable microwave applications10.1088/0022-3727/42/22/225404 ↗
19. Murashova · Russian Journal of Inorganic Chemistry · 1991 · 36 · 481
20. Coactivation of α-Sr(PO3)2 and SrM(P2O7) (M=Zn, Sr) with Eu2+ and Mn2+10.1021/cm702292x ↗
21. Rietveld refinement and photoluminescent properties of a new blue-emitting material: Eu2+ activated SrZnP2O710.1016/j.jssc.2007.09.023 ↗
22. Luminescence and energy transfer of Eu2+, Mn2+ in SrZnP2O710.1088/0256-307X/24/7/085 ↗
23. Luminescence and energy transfer of Ce3+, Tb3+ in SrZnP2O7
24. Luminescence of the europium (3+) ion in zirconium (4+) compounds10.1021/cm00018a018 ↗
25. Quantum efficiencies of luminescent Eu3+ centers in CaO10.1016/S0022-4596(05)80264-6 ↗
26. Luminescence of CaSO4:Bi3+, a small-offset case10.1016/0022-4596(92)90329-T ↗
27. Luminescence of rare-earth ions in Ca3(BO3)210.1016/0254-0584(92)90195-E ↗
28. Blasse · 1994
29. Diffusion and transfer of optical excitation in YF3:Yb, Ho10.1103/PhysRevB.6.1584 ↗
30. Influence of energy transfer by the exchange mechanism on donor luminescence10.1063/1.1697063 ↗
31. Eu2+ activation in some alkaline earth strontium phosphate compounds10.1149/1.2411331 ↗
32. Site-selective emission spectra of Eu3+:Ca5(PO4)3F10.1016/S0925-8388(00)00612-5 ↗
33. Photoluminescence and local structure of Eu(III)-doped zirconium silicates10.1016/j.jallcom.2003.11.089 ↗
34. Highly luminescent europium(III) complexes with naphtoiltrifluoroacetone and dimethyl sulphoxide10.1080/0026897021000046898 ↗
35. Jørgensen · Progress in Inorganic Chemistry · 1962 · 4 · 7310.1002/9780470166055.ch2 ↗
36. Unusual fluorescent properties of Eu3+ in oxyapatites10.1016/0022-2313(87)90036-6 ↗
37. The effects of sequential annealing in air atmosphere on luminescence properties of PbWO4 single crystal10.1016/S0368-2048(03)00140-3 ↗
38. Phonon-assisted energy transfer between trivalent rare earth ions10.1143/JPSJ.32.1577 ↗