Combustion synthesis of lead oxide nanopowders for the preparation of PMN–PT transparent ceramics
Source abstract
Abstract
Abstract We describe the preparation of lead oxide nanopowders by a combustion synthesis process in which nitric acid and glycine are used as oxidant and fuel reagents respectively. We observe that the fuel-to-oxidant ratio affects the phase formation, valence, yield, particle shape and size of lead oxide powders. 60 nm-diameter lead oxide particles, with a yield of 86%, were obtained for a 1.7 glycine-to-nitrate molar ratio. This process produces powders with greater uniformity and smaller particle size than commercially available and we illustrate the improvement that these nanopowders offer in the synthesis of (1− x )Pb(Mg 1/3 Nb 2/3 )O 3 – x PbTiO 3 (called PMN–PT) transparent ceramics by solid-state reaction.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Electronic and Structural Properties of Oxides
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. Optical characterization of Eu3+ and Tb3+ ions doped zinc lead borate glasses10.1016/j.saa.2006.02.060 ↗
2. Nanostructured PbO materials obtained in situ by spray solution technique for Li-ion batteries10.1016/j.jpowsour.2006.04.029 ↗
3. Electrochemical lithiation of Pb3O410.1016/0378-7753(91)80101-3 ↗
4. Synthesis of sub-micro and nanometer sized lead oxide by sol–gel pyrrolysis method and its application as cathode and anode of lead-acid batteries10.1016/S1452-3981(23)12826-4 ↗
5. First-principles study of the electro-optic effect in ferroelectric oxides10.1103/PhysRevLett.93.187401 ↗
6. Electro-optic ceramics and their display applications10.1016/0272-8842(95)96202-Z ↗
7. Electro-optical properties of PMN–xPT compounds: single crystals and transparent ferroelectric ceramics10.1134/S1063783410100203 ↗
8. Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics10.1038/35002022 ↗
9. Processing and electrical properties of (1−x)[(1−y)(Pb(Mg1/3Nb2/3)O3)−y(Pb(Yb1/2Nb1/2)O3)]−xPbTiO3 ceramics10.1016/j.matlet.2008.11.043 ↗
10. The synthesis of Er3+-doped PMN–PT transparent ceramic and its infrared luminescence10.1016/j.matlet.2011.10.034 ↗
11. Ferroelectric ceramics: history and Technology10.1111/j.1151-2916.1999.tb01840.x ↗
12. Synthesis of pyrochlore free 0.9Pb(Mg1/3Nb2/3)O3−0.1PbTiO3 ceramics via a soft mechanochemical route10.1111/j.1151-2916.1997.tb02929.x ↗
13. Synthesis and dielectric properties of sol–gel derived 0.9Pb(Mg1/3Nb2/3)O3−0.1PbTiO3 ceramics10.1111/j.1151-2916.1991.tb04292.x ↗
14. Dielectric properties of chemically co-precipitated tetragonal Pb(Mg1/3Nb2/3)0.65Ti0.35O310.1016/j.solidstatesciences.2010.06.004 ↗
15. Phase developments and dielectric/ferroelectric response in the PMN–PT system10.1016/S0955-2219(01)00278-3 ↗
16. Synthesis, dielectric and microstructure studies of lead magnesium niobate stabilized using lead titanate10.1080/00150199608213399 ↗
17. Effect of excess PbO on the sintering characteristics and dielectric properties of Pb (Mg1/3Nb2/3)O3–PbTiO3-based ceramics10.1111/j.1151-2916.1988.tb05038.x ↗
18. Effect of composition on the electromechanical properties of (1−x)Pb(Mg1/3Nb2/3)O3−xPbTiO310.1111/j.1151-2916.1997.tb02927.x ↗
19. Synthesis and structure of PMN–PT ceramic nanopowder free from pyrochlore phase10.1016/j.ceramint.2009.03.036 ↗
20. Transparent electro-optic ceramics and devices
21. The new pyrochlores Pb2(M0.5Sb1.5)O6.5 (M=Al, Sc, Cr, Fe, Ga, Rh)10.1016/0025-5408(85)90130-8 ↗
22. Crystal growth, crystal structure and chemical composition of a pyrochlore type compound in lead–magnesium–niobium–oxygen system10.1016/0025-5408(93)90082-O ↗
23. Influence of ceramic processing on dielectric properties of perovskite type compound: Pb(Mg1/3Nb2/3)O310.1016/0272-8842(83)90011-1 ↗
24. The role of excess magnesium oxide or lead oxide in determining the microstructure and properties of lead magnesium niobate10.1111/j.1151-2916.1990.tb05121.x ↗
25. Chemical synthesis of nano-sized particles of lead oxide and their characterization studies10.3923/jas.2012.398.401 ↗
26. Synthesis of lead oxide nanoparticles by Sonochemical method and its application as cathode and anode of lead-acid batteries10.1016/j.matchemphys.2007.09.045 ↗
27. Ionic conductivity of ceria/yttria stabilized zirconia electrolyte materials10.1016/S0167-2738(97)00306-8 ↗
28. Properties of sol–gel prepared Ce1–xSmxO2–x/2 solid electrolyte10.1016/S0167-2738(97)00309-3 ↗
29. In situ fabrication of morphology-controlled advanced ceramic materials by soft solution processing10.1016/S0167-2738(97)00103-3 ↗
30. Combustion synthesis of nanocrystalline yttria-doped ceria10.1557/jmr.2004.19.2.474 ↗
31. Preparation and characterization of Sr0.09Ce0.91O1.91, SrCeO3, and Sr2CeO4 by glycine-nitrate combustion: crucial role of oxidant-to-fuel ratio10.1557/JMR.2004.0411 ↗
32. Highly sinter-active nanocrystalline RE2O3 (RE=Gd, Eu, Dy) by a combustion process, and role of oxidant-to-fuel ratio in preparing their different crystallographic modifications10.1557/jmr.2007.0101 ↗
33. Effect of oxidant-to-fuel ratios on phase formation of PLZT powder; prepared by gel-combustion10.1016/j.jallcom.2010.12.177 ↗
34. A one-step process for the preparation of γ-Fe2O310.1007/BF01672056 ↗
35. Characteristics of lanthanum strontium chromite prepared by glycine nitrate process10.1016/S0167-2738(00)00402-1 ↗
36. Synthesis of hexagonal YMnO3 from precursor obtained by the glycine–nitrate process10.1016/j.ceramint.2012.10.002 ↗
37. Magnetic and structural studies of the Mn-doped Mg–Zn ferrite nanoparticles synthesized by the glycine nitrate process10.1016/j.jmmm.2012.06.009 ↗
38. Synthesis and magnetic properties of nanostructured spinel ferrites using a glycine–nitrate process10.1016/j.jmmm.2004.06.039 ↗
39. Glycine–nitrate combustion synthesis of oxide ceramic powders10.1016/0167-577X(90)90003-5 ↗
40. A low temperature path to the preparation of ultrafine ferrites
41. Low-temperature preparation of fine-particle cobaltites10.1016/0022-4596(87)90216-7 ↗
42. A novel combustion process for the synthesis of fine particle α-alumina and related oxide materials10.1016/0167-577X(88)90045-6 ↗