journal article·2016-05

Oxidation behavior of β-SiAlON powders fabricated by combustion synthesis

Zhongmin Li, Zhanjun Wang, Mengguang Zhu, Jinfu Li, Zuotai Zhang

Ceramics International· Volume 42· Issue 6
Publisher page

Abstract

Abstract The present study presents the effect of addition of diluents on the crystal morphologies and the impact on the oxidation resistance of β-SiAlON powders obtained from combustion synthesis method. Pure β-SiAlON were synthesized with diluents. It was observed by SEM that the diluents resulted in the transformation from large hexagonal column-shaped crystals to fine isotropic grains. Oxidation experiments were conducted by thermogravimetric analysis (TGA) in the temperature range from 1200 °C to 1400 °C. The TGA results indicated that oxidation was controlled by mixed chemical reaction and diffusion process. The chemical reaction step was found to be rate-controlling at low oxidation temperatures (1200 °C and 1300 °C), while at high temperature (1400 °C), diffusion was found to control the reaction rate. Oxidation products were investigated by X-ray Diffraction (XRD) analysis and found to be made up of SiO 2 , Al 2 O 3 . This research aims to provide guidance for the fabrication of β-SiAlON by combustion synthesis, thus facilitating its further application in high temperature industry.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. α-SiAlON ceramics10.1038/274880a0 ↗
2. Porous silicon nitride ceramics fabricated by carbothermal reduction–reaction bonding10.1080/10426914.2010.515640 ↗
3. Shape deformation and texture development of consolidated Ca-α-SiAlON ceramics prepared by hot-forging10.1016/j.materresbull.2007.02.035 ↗
4. Reaction mechanism for combustion synthesis of β-SiAlON by using Si, Al and SiO2 as raw materials10.1016/j.jallcom.2013.01.170 ↗
5. Sialons and related nitrogen ceramics-review10.1007/BF02396649 ↗
6. Combustion synthesis of singe-phase β-sialons (z=2–4)10.1016/j.jeurceramsoc.2010.02.022 ↗
8. Reaction characteristics of combustion synthesis of β-SiAlON using different additives10.1016/j.cej.2013.12.030 ↗
9. Pressureless sintering of β-SiAlON with improved green strength by using metallic Al powder10.1016/S0167-577X(03)00073-9 ↗
10. Carbothermal synthesis of β-SiAlON from mechanochemically activated precursors10.1016/j.jeurceramsoc.2004.10.004 ↗
11. Synthesis of prismatic beta-sialon from the precursor of SBA-15 incorporated with Al(NO3)3 via carbothermal reduction nitridation10.1016/j.ceramint.2006.04.026 ↗
12. Combustion synthesis of sialon ceramic powders: a review10.1080/10426914.2012.718471 ↗
13. Oxidation of Ca- α-SiAlON powders prepared by combustion synthesis10.3390/ma8115394 ↗
14. Synthesis of β-SiAlON: a combined method using sol–gel and SHS processes10.1016/j.ceramint.2007.02.017 ↗
15. Recycling of industrial and natural wastes to Sialons
16. Fabrication of dense β-SiAlON by a combination of combustion synthesis (CS) and spark plasma sintering (SPS)10.1016/j.intermet.2009.10.004 ↗
17. Effect of diluents on high purity β-SiAlONs by mechanically activated combustion synthesis10.2109/jcersj2.117.777 ↗
18. Effects of starting compositions on the phase composition and microstructure of Yb-α-SiAlON prepared by combustion synthesis
19. Morphology control of β-SiAlON via salt-assisted combustion synthesis10.1016/j.ceramint.2013.07.082 ↗
20. Effect of diluents and NH4F additive on the combustion synthesis of Yb α-SiAlON10.1016/j.jeurceramsoc.2004.08.021 ↗
21. Reactions in the solid state at high temperature10.1002/zaac.19271630102 ↗
22. Comparison of the diffusion control models for isothermal oxidation of SiAlON powders10.1111/j.1551-2916.2008.02631.x ↗
23. Kinetic model for solid-state reactions10.1063/1.1731812 ↗
24. A new approach to interpreting the parabolic and non-parabolic oxidation behavior of hot-pressed β-SiAlON ceramics10.1016/j.corsci.2012.02.004 ↗
25. Morphological development and oxidation of elongated β-Sialon materials10.1016/j.corsci.2011.01.056 ↗
26. Early-stage thermal oxidation of carbothermal beta-sialon powder10.1111/j.1151-2916.1998.tb02331.x ↗
27. Thermal oxidation of carbothermal β-sialon powder: reaction sequence and kinetics10.1039/a604354b ↗
28. Some new perspectives on oxidation kinetics of SiAlON materials10.1016/j.jeurceramsoc.2007.09.041 ↗
29. A kinetic model for oxidation of Si–Al–O–N materials10.1111/j.1551-2916.2006.00959.x ↗
30. Study on oxidation dynamics of different Z-value β-sialon
31. Dense single-phase β-Sialon ceramics by glass-encapsulated hot isostatic pressing10.1007/BF01105715 ↗
32. Fabrication of one-dimensional rod-like α-SiAlON powders in large scales by combustion synthesis10.1016/j.jallcom.2007.01.009 ↗
33. Investigation on resistance of bauxite-based β-SiAlON powders with different particle size
34. Kinetic studies of oxidation of γ-AlON-TiN composites10.1016/j.jallcom.2004.04.111 ↗
35. General diffusion-kinetic model of metallic oxidation10.1016/S0010-938X(01)00127-5 ↗