Preparation of rod-like CuSbS2 particles by soft-template synthesis and electrochemical performance toward lithium storage
Source abstract
Abstract
CuSbS2 particles could be rapidly prepared by the microwave-assisted liquid phase method. Polyethylene glycol (PEG) was used as the directing agent for morphology and structure of CuSbS2 particles. Microwave irradiation could induce Cu2+, adsorbed on PEG chain structure, to reduce as Cu+. In the further reaction, the rod-like structure of CuSbS2 was formed. The results showed that the CuSbS2 particles prepared by the PEG400 structure directing agent had a higher first discharge specific capacity (~1499.6 mAh g−1) and excellent electronic and ionic conductivity. This method provides a new idea for the morphology control of anode materials for high energy density lithium batteries.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced battery technologies research · Copper-based nanomaterials and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (34)
Show source-provided references
1. Beaucage PA, Susca EM, Gruner SM et al (2017) Discovering synthesis routes to hexagonally ordered mesoporous niobium nitrides using poloxamer/pluronics block copolymers. Chem Mater 29(21):8973–897710.1021/acs.chemmater.7b03834 ↗
2. Behera C, Samal R, Rout CS et al (2019) Synthesis of CuSbS2 nanoplates and CuSbS2-Cu3SbS4 nanocomposite: effect of sulfur source on different phase formation. Inorg Chem 58(22):15291–1530210.1021/acs.inorgchem.9b02291 ↗
3. Dufton JT, Walsh A, Panchmatia PM et al (2012) Structural and electronic properties of CuSbS2 and CuBiS2: potential absorber materials for thin-film solar cells. Phys Chem Chem Phys 14(20):7229–723310.1039/c2cp40916j ↗
4. Fan Z, Yan J, Ning G et al (2013) Porous graphene networks as high performance anode materials for lithium ion batteries. Carbon 60:558–56110.1016/j.carbon.2013.04.053 ↗
5. García RGA, Cerdán-Pasarán A, Perez EAR et al (2020) Phase pure CuSbS2 thin films by heat treatment of electrodeposited Sb2S3/Cu layers. J Solid State Electrochem 24(1):185–19410.1007/s10008-019-04475-3 ↗
6. Ghorpade Uma V, Suryawanshi MP, Shin SW et al (2018) Unassisted visible solar water splitting with efficient photoelectrodes sensitized by quantum dots synthesized via an environmentally friendly eutectic solvent-mediated approach. J Mater Chem A 6(45):22566–2257910.1039/C8TA05901B ↗
7. Han M, Jia J, Wang W (2017) A novel CuSbS2 hexagonal nanobricks@TiO2 nanorods heterostructure for enhanced photoelectrochemical characteristics. J Alloys Comp 705:356–36210.1016/j.jallcom.2017.02.185 ↗
8. Li X, Liang H, Liu X et al (2021) Ion-exchange strategy of CoS2/Sb2S3 hetero-structured nanocrystals encapsulated into 3D interpenetrating dual-carbon framework for high-performance Na+/K+ batteries. Chem Eng J 425:13065710.1016/j.cej.2021.130657 ↗
9. Liu H, He Y, Cao K et al (2021) Stimulating the reversibility of Sb2S3 anode for high-performance potassium-ion batteries. Small 17(10):200813310.1002/smll.202008133 ↗
10. Ma J, Duan X, Lian J et al (2010) Sb2S3 with various nanostructures: controllable synthesis, formation mechanism, and electrochemical performance toward lithium storage. Chemistry 16(44):13210–1321710.1002/chem.201000962 ↗
11. Mahmoud MA, O’Neil D, El-Sayed MA (2013) Hollow and solid metallic nanoparticles in sensing and in nanocatalysis. Chem Mater 26(1):44–5810.1021/cm4020892 ↗
12. Malho J-M, Morits M, Löbling TI et al (2016) Rod-like nanoparticles with striped and helical topography. ACS Macro Letters 5(10):1185–119010.1021/acsmacrolett.6b00645 ↗
13. Mane GP, Talapaneni SN, Lakhi KS et al (2017) Highly ordered nitrogen-rich mesoporous carbon nitrides and their superior performance for sensing and photocatalytic hydrogen generation. Angew Chem Int Ed Engl 56(29):8481–848510.1002/anie.201702386 ↗
14. Manimozhi T, Archana J, Navaneethan M et al (2019) Morphology and phase controlled synthesis of PVP-assisted copper antimony sulfide microstructures using solvothermal method and their properties. Mater Sci Semiconductor Process 103:10460610.1016/j.mssp.2019.104606 ↗
15. Marino C, Block T, Pöttgen R et al (2017) CuSbS2 as a negative electrode material for sodium ion batteries. J Power Sources 342:616–62210.1016/j.jpowsour.2016.12.100 ↗
16. McCarthy CL, Cottingham P, Abuyen K et al (2016) Earth abundant CuSbS2 thin films solution processed from thiol–amine mixtures. J Mater Chem C 4(26):6230–623310.1039/C6TC02117D ↗
17. Qu B, Zhang M, Lei D et al (2011) Facile solvothermal synthesis of mesoporous Cu2SnS3 spheres and their application in lithium-ion batteries. Nanoscale 3(9):3646–365110.1039/c1nr10401b ↗
18. Roberts AD, Li X, Zhang H (2014) Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials. Chem Soc Rev 43(13):4341–435610.1039/C4CS00071D ↗
19. Shu B, Han Q (2016) Studies on structural, optical and electrical properties of CuSbS2 nanoparticles. Chalcogenide Lett 13:46–53
20. Shulga Y M, Rubtsov V, Vasilets V, et al. EELS, XPS and IR study of C60·2S8 compound. Synthetic Metals, 1995, 70(1-3): 1381-2.10.1016/0379-6779(94)02887-5 ↗
21. Takafuji Y, Jo J-i, Tabata Y (2011) Simple PEG modification of DNA aptamer based on copper ion coordination for tumor targeting. J Biomater Sci Polymer Edition 22(9):1179–1195
22. Tian H, Tan X, Xin F et al (2015) Micro-sized nano-porous Si/C anodes for lithium ion batteries. Nano Energy 11:490–49910.1016/j.nanoen.2014.11.031 ↗
23. Wu P, Liu Z, Ruan M et al (2019) Cobalt-phosphate modified Fe-Zn0.2Cd0.8S/CuSbS2 heterojunction photoanode with multiple synergistic effect for enhancing photoelectrochemical water splitting. Appl Surf Sci 476:716–72310.1016/j.apsusc.2019.01.150 ↗
24. Xie J, Xia J, Yuan Y et al (2019) Sb2S3 embedded in carbon–silicon oxide nanofibers as high-performance anode materials for lithium-ion and sodium-ion batteries. J Power Sources 435:22676210.1016/j.jpowsour.2019.226762 ↗
25. Yang B, Wang L, Han J et al (2014) CuSbS2 as a promising earth-abundant photovoltaic absorber material: a combined theoretical and experimental study. Chem Mater 26(10):3135–314310.1021/cm500516v ↗
26. Yin H, Hui KS, Zhao X et al (2020) Eco-friendly synthesis of self-supported N-doped Sb2S3-carbon fibers with high atom utilization and zero discharge for commercial full lithium-ion batteries. ACS Appl Energy Mater 3(7):6897–690610.1021/acsaem.0c00984 ↗
27. Zakaznova-Herzog VP, Harmer SL, Nesbitt HW et al (2006) High resolution XPS study of the large-band-gap semiconductor stibnite (Sb2S3): structural contributions and surface reconstruction. Surf Sci 600(2):348–35610.1016/j.susc.2005.10.034 ↗
28. Zhang Z, Zhou C, Liu Y et al (2013) CuSbS2 nanobricks as electrode materials for lithium ion batteries. Int J Electrochem Sci 8(10059):10067
29. Zhang Z, Fu Y, Zhou C et al (2014) Facile synthesis of CuSbS2 blocks, and their lithium ion storage performance. J Electron Mater 44(1):252–25710.1007/s11664-014-3499-1 ↗
30. Zhang J, Li W, Li Y et al (2017) Self-optimizing bifunctional CdS/Cu2S with coexistence of light-reduced Cu0 for highly efficient photocatalytic H2 generation under visible-light irradiation. Appl Catal B: Environ 217:30–3610.1016/j.apcatb.2017.05.074 ↗
31. Zhang Y, Huang J, Yan C et al (2019) High open-circuit voltage CuSbS2 solar cells achieved through the formation of epitaxial growth of CdS/CuSbS2 hetero-interface by post-annealing treatment. Prog Photovoltaics: Res Appl 27(1):37–4310.1002/pip.3061 ↗
32. Zhang Q, Zeng Y, Wang X et al (2021) Sb2S3 nanoparticles anchored on N-doped 3D carbon nanofibers as anode material for sodium ion batteries with improved electrochemical performance. J Alloys Comp 881:16059410.1016/j.jallcom.2021.160594 ↗
33. Zhou J, Dou Q, Zhang L et al (2020) A novel and fast method to prepare a Cu-supported α-Sb2S3@CuSbS2 binder-free electrode for sodium-ion batteries. RSC Advances 10(49):29567–2957410.1039/D0RA05623E ↗
34. Zou Y, Zhou X, Ma J et al (2020) Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications. Chem Soc Rev 49(4):1173–120810.1039/C9CS00334G ↗