journal article·2025-07

Magnetite nanoparticles doped with rare earth ions: synthesis, structural, and magnetic properties

A. V. Rutkauskas, O. N. Lis, S. E. Kichanov, E. V. Lukin, B. A. Abdurakhimov, G. S. Rymski, A. L. Zhaludkevich, I. I. Makoed, D. P. Kozlenko, A. Mutali

Journal of Nanoparticle Research· Volume 27· Issue 7
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Iron oxide chemistry and applications · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (69)

Show source-provided references
1. Abdolrahimi M, Vasilakaki M, Slimani S et al (2021) Magnetism of nanoparticles: effect of the organic coating. Nanomaterials 11. https://doi.org/10.3390/nano1107178710.3390/nano11071787 ↗
2. Alina G, Butler P, Cho J, Doucet M, Kienzle P (2017) Sasview for small angle scattering analysis. https://www.sasview.org/
3. Ansari SAMK, Ficiarà E, Ruffinatti FA et al (2019) Magnetic iron oxide nanoparticles: synthesis, characterization and functionalization for biomedical applications in the central nervous system. Materials (Basel) 12. https://doi.org/10.3390/ma1203046510.3390/ma12030465 ↗
4. Ba-Abbad MM, Benamour A, Ewis D et al (2022) Synthesis of Fe3O4 nanoparticles with different shapes through a co-precipitation method and their application. JOM 74:3531–3539. https://doi.org/10.1007/s11837-022-05380-310.1007/s11837-022-05380-3 ↗
5. Beaucage G (1996) Small-angle scattering from polymeric mass fractals of arbitrary mass-fractal dimension. J Appl Crystallogr 29:134–146. https://doi.org/10.1107/S002188989501160510.1107/S0021889895011605 ↗
6. Burrows F, Parker C, Evans RFL et al (2010) Energy losses in interacting fine-particle magnetic composites. J Phys D Appl Phys 43:474010. https://doi.org/10.1088/0022-3727/43/47/47401010.1088/0022-3727/43/47/474010 ↗
7. Caizer C (2016) Nanoparticle size effect on some magnetic properties BT - handbook of nanoparticles. In: International S (ed) Aliofkhazraei M. Publishing, Cham, pp 475–519
8. Chen Y-T, Kolhatkar AG, Zenasni O et al (2017) Biosensing using magnetic particle detection techniques. Sensors 17. https://doi.org/10.3390/s1710230010.3390/s17102300 ↗
9. de Jesus Andrade Fidelis R, Pires M, de Resende DS et al (2025) Magnetite: properties and applications – a review. J Magn Magn Mater 614:172770. https://doi.org/10.1016/j.jmmm.2025.17277010.1016/j.jmmm.2025.172770 ↗
10. de Jesús Ibarra–Sánchez J, López–Luke T, Ramírez–García G et al (2018) Synthesis and characterization of Fe3O4:Yb3+:Er3+ nanoparticles with magnetic and optical properties for hyperthermia applications. J Magn Magn Mater 465:406–411. https://doi.org/10.1016/j.jmmm.2018.05.09110.1016/j.jmmm.2018.05.091 ↗
11. De Teresa JM, Fernández-Pacheco A, Morellon L et al (2007) Magnetotransport properties of Fe3O4 thin films for applications in spin electronics. Microelectron Eng 84:1660–1664. https://doi.org/10.1016/j.mee.2007.01.12010.1016/j.mee.2007.01.120 ↗
12. Deepak FL, Bañobre-López M, Carbó-Argibay E et al (2015) A systematic study of the structural and magnetic properties of Mn-, Co-, and Ni-doped colloidal magnetite nanoparticles. J Phys Chem C 119:11947–11957. https://doi.org/10.1021/acs.jpcc.5b0157510.1021/acs.jpcc.5b01575 ↗
13. Di Nunzio PE, Stefano M, Bitti RR (2005) Use of Monte Carlo methods in characterizing nanostructured materials by wide- and small-angle X-ray scattering. J Dispers Sci Technol 25:491–501. https://doi.org/10.1081/DIS-20002573510.1081/DIS-200025735 ↗
14. Fleet ME (1981) The structure of magnetite. Acta Crystallogr Sect B 37:917–920. https://doi.org/10.1107/S056774088100459710.1107/S0567740881004597 ↗
15. Grüttner C, Müller K, Teller J, Westphal F (2013) Synthesis and functionalisation of magnetic nanoparticles for hyperthermia applications. Int J Hyperth 29:777–789. https://doi.org/10.3109/02656736.2013.83587610.3109/02656736.2013.835876 ↗
16. Gubin SP (2009) Magnetic nanoparticles. John Wiley & Sons, Ltd, Chichester
17. Gürsoy E, Vonbun-Feldbauer GB, Meißner RH (2023) Oxidation-state dynamics and emerging patterns in magnetite. J Phys Chem Lett 14:6800–6807. https://doi.org/10.1021/acs.jpclett.3c0129010.1021/acs.jpclett.3c01290 ↗
18. Hajnorouzi A, Modaresi N (2020) Direct sono electrochemical method for synthesizing Fe3O4 nanoparticles. J Magn Magn Mater 505:166732. https://doi.org/10.1016/j.jmmm.2020.16673210.1016/j.jmmm.2020.166732 ↗
19. Hammouda B (2010) Analysis of the Beaucage model. J Appl Crystallogr 43:1474–1478. https://doi.org/10.1107/S002188981003385610.1107/S0021889810033856 ↗
20. Hu F, Wang D, Ma X et al (2023) Concurrent dual-contrast enhancement using Fe3O4 nanoparticles to achieve a CEST signal controllability. ACS Omega 8:24153–24164. https://doi.org/10.1021/acsomega.2c0700010.1021/acsomega.2c07000 ↗
21. Huan W, Cheng C, Yang Y et al (2012) A study on the magnetic and photoluminescence properties of Eu(n+) and Sm3+ doped Fe3O4 nanoparticles. J Nanosci Nanotechnol 12:4621–4634. https://doi.org/10.1166/jnn.2012.619010.1166/jnn.2012.6190 ↗
22. Hussein AK (2015) Applications of nanotechnology in renewable energies—a comprehensive overview and understanding. Renew Sustain Energy Rev 42:460–476. https://doi.org/10.1016/j.rser.2014.10.02710.1016/j.rser.2014.10.027 ↗
23. Issa B, Obaidat IM, Albiss BA, Haik Y (2013) Magnetic nanoparticles: surface effects and properties related to biomedicine applications. Int J Mol Sci 14:21266–21305. https://doi.org/10.3390/ijms14112126610.3390/ijms141121266 ↗
24. Jacobo SE, Duhalde S, Bertorello HR (2004) Rare earth influence on the structural and magnetic properties of NiZn ferrites. J Magn Magn Mater 272–276:2253–2254. https://doi.org/10.1016/j.jmmm.2003.12.56410.1016/j.jmmm.2003.12.564 ↗
25. Jain R (2023) Effect of gadolinium doping on the structural, magnetic, electrical, optical, and elastic properties of magnetite nanoparticles. Mater Sci Eng B 296:116631. https://doi.org/10.1016/j.mseb.2023.11663110.1016/j.mseb.2023.116631 ↗
26. Jain R, Luthra V, Gokhale S (2018) Probing influence of rare earth ions (Er3+, Dy3+ and Gd3+) on structural, magnetic and optical properties of magnetite nanoparticles. J Magn Magn Mater 456:179–185. https://doi.org/10.1016/j.jmmm.2018.02.02910.1016/j.jmmm.2018.02.029 ↗
27. Jiles D (2015) Introduction to magnetism and magnetic materials, 3rd edn. CRC Press, Taylor and Francis Group, NY10.1201/b18948-2 ↗
28. Jing X, Guo M, Li Z et al (2023) Study on structure and magnetic properties of rare earth doped cobalt ferrite: the influence mechanism of different substitution positions. Ceram Int 49:14046–14056. https://doi.org/10.1016/j.ceramint.2022.12.28610.1016/j.ceramint.2022.12.286 ↗
29. Ju S, Cai T-Y, Lu H-S, Gong C-D (2012) Pressure-induced crystal structure and spin-state transitions in magnetite (Fe3O4). J Am Chem Soc 134:13780–13786. https://doi.org/10.1021/ja305167h10.1021/ja305167h ↗
30. Kalantari S, Shokuhfar A (2024) On the diverse utility of Cu doped ZnS/Fe3O4 nanocomposites. Sci Rep 14:11669. https://doi.org/10.1038/s41598-024-62611-010.1038/s41598-024-62611-0 ↗
31. Kershi RM, Ali FM, Sayed MA (2018) Influence of rare earth ion substitutions on the structural, optical, transport, dielectric, and magnetic properties of superparamagnetic iron oxide nanoparticles. J Adv Ceram 7:218–228. https://doi.org/10.1007/s40145-018-0273-510.1007/s40145-018-0273-5 ↗
32. Koksharov YA (2009) Magnetism of nanoparticles: effects of size, shape, and interactions. In: Gubin SP (ed) Magnetic nanoparticles. John Wiley & Sons, Ltd, Chichester, pp 197–25410.1002/9783527627561.ch6 ↗
33. Kozlenko DP, Dubrovinsky LS, Kichanov SE et al (2019) Magnetic and electronic properties of magnetite across the high pressure anomaly. Sci Rep 9:1–9. https://doi.org/10.1038/s41598-019-41184-310.1038/s41598-019-41184-3 ↗
34. Kozlenko DP, Kichanov SE, Lukin EV, Savenko BN (2021) High-pressure neutron diffraction study of the crystal and magnetic structure of materials at the pulsed reactor IBR-2: current opportunities and prospects. Crystallogr Rep 66:303–31310.1134/S1063774521020073 ↗
35. Laha SS, Regmi R, Lawes G (2013) Structural origin for low-temperature relaxation features in magnetic nanoparticles. J Phys D Appl Phys 46:325004. https://doi.org/10.1088/0022-3727/46/32/32500410.1088/0022-3727/46/32/325004 ↗
36. Lak A, Disch S, Bender P (2021) Embracing defects and disorder in magnetic nanoparticles. Adv Sci 8:2002682. https://doi.org/10.1002/advs.20200268210.1002/advs.202002682 ↗
37. Langford JI, Wilson AJC (1978) Scherrer after sixty years: a survey and some new results in the determination of crystallite size. J Appl Crystallogr 11:102–113. https://doi.org/10.1107/S002188987801284410.1107/S0021889878012844 ↗
38. Lastovina TA, Bugaev AL, Kubrin SP et al (2016) Structural studies of magnetic nanoparticles doped with rare-earth elements. J Struct Chem 57:1444–1449. https://doi.org/10.1134/S002247661607020910.1134/S0022476616070209 ↗
39. Levish A, Joshi S, Winterer M (2023) Chemical vapor synthesis of nanocrystalline iron oxides. Appl Energy Combust Sci 15:100177. https://doi.org/10.1016/j.jaecs.2023.10017710.1016/j.jaecs.2023.100177 ↗
40. Li H, Kobayashi M, Kou S et al Noncollinear magnetism in Fe3O4 induced via site-selective rare-earth substitution boosting its saturation magnetization. Small n/a:2411133. https://doi.org/10.1002/smll.20241113310.1002/smll.202411133 ↗
41. Li Q, Kartikowati CW, Horie S et al (2017) Correlation between particle size/domain structure and magnetic properties of highly crystalline Fe3O4 nanoparticles. Sci Rep 7:9894. https://doi.org/10.1038/s41598-017-09897-510.1038/s41598-017-09897-5 ↗
42. Li T, Senesi AJ, Lee B (2016) Small angle X-ray scattering for nanoparticle research. Chem Rev 116:11128–11180. https://doi.org/10.1021/acs.chemrev.5b0069010.1021/acs.chemrev.5b00690 ↗
43. Licciardi M, Scialabba C, Fiorica C et al (2013) Polymeric nanocarriers for magnetic targeted drug delivery: preparation, characterization, and in vitro and in vivo evaluation. Mol Pharm 10:4397–4407. https://doi.org/10.1021/mp300718b10.1021/mp300718b ↗
44. Monalisa SS, Satyapal HK, Singh RK (2021) Correlation between lattice strain and magnetic properties enhancement of nanocrystalline cobalt ferrite with controlled annealing. J Mater Sci Mater Electron 32:23843–23853. https://doi.org/10.1007/s10854-021-06795-510.1007/s10854-021-06795-5 ↗
45. Monshi A, Foroughi MR, Monshi MR (2012) Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD. World J Nano Sci Eng 02:154–160. https://doi.org/10.4236/wjnse.2012.2302010.4236/wjnse.2012.23020 ↗
46. Nedelkoski Z, Kepaptsoglou D, Lari L et al (2017) Origin of reduced magnetization and domain formation in small magnetite nanoparticles. Sci Rep 7:45997. https://doi.org/10.1038/srep4599710.1038/srep45997 ↗
47. O’Neill HSC, Navrotsky A (1983) Simple spinels: crystallographic parameters, cation radii, lattice energies, and cation distribution. Am Mineral 68:181–194
48. Padalia D, Johri UC, Zaidi MGH (2012) Study of cerium doped magnetite (Fe3O4:Ce)/PMMA nanocomposites. Phys B Condens Matter 407:838–843. https://doi.org/10.1016/j.physb.2011.12.01610.1016/j.physb.2011.12.016 ↗
49. Paula FL de O (2019) SAXS analysis of magnetic field influence on magnetic nanoparticle clusters. Condens Matter 4:. https://doi.org/10.3390/condmat402005510.3390/condmat4020055 ↗
50. Pauw BR, Pedersen JS, Tardif S et al (2013) Improvements and considerations for size distribution retrieval from small-angle scattering data by Monte Carlo methods. J Appl Crystallogr 46:365–371. https://doi.org/10.1107/S002188981300129510.1107/S0021889813001295 ↗
51. Peng J, Hojamberdiev M, Xu Y et al (2011) Hydrothermal synthesis and magnetic properties of gadolinium-doped CoFe2O4 nanoparticles. J Magn Magn Mater 323:133–137. https://doi.org/10.1016/j.jmmm.2010.08.04810.1016/j.jmmm.2010.08.048 ↗
52. Polozhentsev OE, Kubrin SP, Butova VV et al (2016) Structure and magnetic properties of pure and samarium doped magnetite nanoparticles. J Struct Chem 57:1459–1468. https://doi.org/10.1134/S002247661607022210.1134/S0022476616070222 ↗
53. Rego GN de A, Mamani JB, Souza TKF et al (2019) Therapeutic evaluation of magnetic hyperthermia using Fe3O4-aminosilane-coated iron oxide nanoparticles in glioblastoma animal model. Einstein (Sao Paulo) 17:eAO4786. https://doi.org/10.31744/einstein_journal/2019AO478610.31744/einstein_journal/2019AO4786 ↗
54. Rodríguez-Carvajal J (1993) Recent advances in magnetic structure determination by neutron powder diffraction. Phys B Condens Matter 192:55–69. https://doi.org/10.1016/0921-4526(93)90108-I10.1016/0921-4526(93)90108-I ↗
55. Rosická D, Šembera J (2011) Influence of structure of iron nanoparticles in aggregates on their magnetic properties. Nanoscale Res Lett 6:527. https://doi.org/10.1186/1556-276X-6-52710.1186/1556-276X-6-527 ↗
56. Schneider CA, Rasband WS, Eliceiri KW (2012) NIH Image to ImageJ: 25 years of image analysis. Nat Methods 9:671–675. https://doi.org/10.1038/nmeth.208910.1038/nmeth.2089 ↗
57. Semaltianos NG, Karczewski G (2021) Laser synthesis of magnetic nanoparticles in liquids and application in the fabrication of polymer–nanoparticle composites. ACS Appl Nano Mater 4:6407–6440. https://doi.org/10.1021/acsanm.1c0071510.1021/acsanm.1c00715 ↗
58. Sonia LC, Kuldeep, Basheed GA, Phanjoubam S (2024) Influence of rare earth (RE = Y, La, Gd, Ho) substitution on the structural, magnetic and rheological properties of magnetite based ferrofluids. J Magn Magn Mater 592:171779. https://doi.org/10.1016/j.jmmm.2024.17177910.1016/j.jmmm.2024.171779 ↗
59. Srinoi P, Chen Y-T, Vittur V et al (2018) Bimetallic nanoparticles: enhanced magnetic and optical properties for emerging biological applications. Appl Sci 8. https://doi.org/10.3390/app807110610.3390/app8071106 ↗
60. Srivastava V, Singh P, Weng C, Sharma Y (2011) Economically viable synthesis of Fe3O4 nanoparticles and their characterization. Polish J Chem Technol 13:1–5. https://doi.org/10.2478/v10026-011-0015-810.2478/v10026-011-0015-8 ↗
61. Stevanović V, D’Avezac M, Zunger A (2010) Simple point-ion electrostatic model explains the cation distribution in spinel oxides. Phys Rev Lett 105:11–14. https://doi.org/10.1103/PhysRevLett.105.07550110.1103/PhysRevLett.105.075501 ↗
62. Svergun DI (1992) Determination of the regularization parameter in indirect-transform methods using perceptual criteria. J Appl Crystallogr 25:495–503. https://doi.org/10.1107/S002188989200166310.1107/S0021889892001663 ↗
63. Svergun DI (2010) Small-angle X-ray and neutron scattering as a tool for structural systems biology. 391:737–743. https://doi.org/10.1515/bc.2010.09310.1515/bc.2010.093 ↗
64. Tatarchuk T (2024) Studying the defects in spinel compounds: discovery, formation mechanisms, classification, and influence on catalytic properties. Nanomaterials 14. https://doi.org/10.3390/nano1420164010.3390/nano14201640 ↗
65. Upadhyay S, Parekh K, Pandey B (2016) Influence of crystallite size on the magnetic properties of Fe3O4 nanoparticles. J Alloys Compd 678:478–485. https://doi.org/10.1016/j.jallcom.2016.03.27910.1016/j.jallcom.2016.03.279 ↗
66. Wang Y, Liu X, Ma S et al (2023) Progress in cancer therapy with functionalized Fe3O4 nanomaterials. Front Mater Sci 17:230658. https://doi.org/10.1007/s11706-023-0658-410.1007/s11706-023-0658-4 ↗
67. Wei Y, Han B, Hu X et al (2012) Synthesis of Fe3O4 nanoparticles and their magnetic properties. Procedia Eng 27:632–637. https://doi.org/10.1016/j.proeng.2011.12.49810.1016/j.proeng.2011.12.498 ↗
68. Yang Y, Huang M, Qian J et al (2020) Tunable Fe3O4 nanorods for enhanced magnetic hyperthermia performance. Sci Rep 10:8331. https://doi.org/10.1038/s41598-020-65095-w10.1038/s41598-020-65095-w ↗
69. Zeng M, Thummavichai K, Chen W et al (2021) Study on the mechanism of tunable ferromagnetic composites with different rare earth ions. RSC Adv 11:37246–37253. https://doi.org/10.1039/D1RA07249H10.1039/D1RA07249H ↗