journal article·2016-11

Sol-gel synthesis of macro-mesoporous Al2O3-SiO2-TiO2 monoliths via phase separation route

Mingliang Sun, Tianbo Zhao, Zunfeng Li, Zhaofei Ma, Jia Wang, Fengyan Li

Ceramics International· Volume 42· Issue 14
Publisher page

Abstract

Abstract Monolithic Al 2 O 3 -SiO 2 -TiO 2 with multiscale porous structures has been prepared via a sol-gel process accompanied by phase separation. Poly(ethylene oxide) (PEO) is used to induce the phase separation and formamide (FA) to control the gelation of ternary system. The dried gel is amorphous. After heat treatment at 1050 °C, the gel transforms into the phase Al 4 Ti 2 SiO 12 . The interconnected macropores are well maintained and the meso-/micropores are disappeared. The homogeneous dispersion of Al, Si and Ti in the skeleton indicates that sol-gel technique could provide a very feasible way for the preparation of hierarchical monolithic composite materials.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Advanced ceramic materials synthesis · Aerogels and thermal insulation

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