journal article·2018-10

Improving the electrochemical property of Li-S batteries by using CoS2 as substrate materials

Jianna Deng, Jianqiang Guo, Jing Li, Min Zeng, Daoyu Gong

Ceramics International· Volume 44· Issue 14
Publisher page

Abstract

Abstract Metal sulfide CoS2 is prepared and used as host materials for Li-S batteries. The CoS2 particle could immobilize the polysulfide by catalyzing the redox reactions of soluble polysulfide to insoluble polysulfide. Besides, the employment of vapor growth carbon fiber (VGCF) interlayer between CoS2/S cathode and separator has a positive effect on physically adsorbing polysulfide. Consequently, the chemical and physical adsorption could exist in one Li-S battery system at the same time. As a result, the initial discharge capacity of CoS2/S composite cathode with VGCF interlayer is 1278 mAh g−1 at the rate of 0.1 C. After 200 cycles, the capacity still remains as high as 701 mAh g−1, which is better than the battery without CoS2, showing excellent electrochemical performance.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Thermostable gel polymer electrolyte based on succinonitrile and ionic liquid for high-performance solid-state supercapacitors10.1016/j.jpowsour.2016.08.032 ↗
2. Carbonized cellulose paper as an effective interlayer in lithium-sulfur batteries10.1016/j.apsusc.2016.10.208 ↗
3. Improving lithium–sulfur battery performance by using ternary hybrid cathode material10.1039/C6RA01722C ↗
4. Synthesis of sulfur/FePO4 /graphene oxide nanocomposites for lithium–sulfur batteries10.1016/j.ceramint.2016.04.017 ↗
5. High rate and stable cycling of lithium-sulfur batteries with carbon fiber cloth interlayer10.1016/j.electacta.2016.05.092 ↗
6. Free-standing sulfur cathodes composited with carbon nanorods arrays for Li-S batteries application10.1016/j.materresbull.2016.06.037 ↗
7. Sulfonic groups originated dual-functional interlayer for high performance lithium−sulfur battery10.1021/acsami.7b02142 ↗
8. A hybrid carbon aerogel with both aligned and interconnected pores as interlayer for high-performance lithium-sulfur batteries10.1007/s12274-016-1244-1 ↗
9. A lightweight TiO2/graphene interlayer applied as a highly effective polysulfide absorbent for fast long-life lithium-sulfur batteries10.1002/adma.201405637 ↗
10. Web-structured graphitic carbon fiber felt as an interlayer for rechargeable lithium-sulfur batteries with highly improved cycling performance10.1016/j.jpowsour.2017.06.048 ↗
11. A three-dimensional self-assembled SnS2-nano-dots@graphene hybrid aerogel as an efficient polysulfide reservoir for high-performance lithium-sulfur batteries10.1039/C8TA01089G ↗
12. A freestanding selenium disulfide cathode based on cobalt disulfide-decorated multichannel carbon fibers with enhanced lithium storage performance10.1002/anie.201708105 ↗
13. Pyrite FeS2 as an efficient adsorbent of lithium polysulfide for improved lithium-sulfur batteries10.1039/C6TA01214K ↗
14. A compact nanoconfined sulfur cathode for high-performance lithium-sulfur batteries10.1016/j.joule.2017.06.003 ↗
15. Double-shelled nanocages with cobalt hydroxide inner shell and layered double hydroxides outer shell as high-efficiency polysulfide mediator for lithium-sulfur batteries10.1002/anie.201511632 ↗
16. Vapor growth carbon fiber felt as an efficient interlayer for trapping polysulfide in lithium-sulfur battery10.20964/2018.04.21 ↗
17. A trilayer separator with dual function for high performance lithium–sulfur batteries10.1016/j.jpowsour.2015.10.007 ↗
18. Synthesis of S/CoS2 nanoparticles-embedded N-doped carbon polyhedrons from polyhedrons ZIF-67 and their properties in lithium-sulfur batteries10.1016/j.electacta.2016.09.130 ↗
19. Powering lithium-sulfur battery performance by propelling polysulfide redox at sulfiphilic hosts10.1021/acs.nanolett.5b04166 ↗
20. Facile coating of graphene interlayer onto Li2S as a high electrochemical performance cathode for lithium sulfur battery10.1016/j.electacta.2016.04.171 ↗
21. Ultrafine TiO2 decorated carbon nanofibers as multifunctional interlayer for high performance lithium sulfur battery10.1021/acsami.6b07487 ↗
22. Inhibiting polysulfides diffusion of lithium-sulfur batteries using an acetylene black-CoS2 modified separator: mechanism research and performance improvement10.1016/j.apsusc.2017.08.062 ↗
23. The enhancement of polysulfide absorbsion in Li S batteries by hierarchically porous CoS2/carbon paper interlayer10.1016/j.jpowsour.2016.04.139 ↗
24. Enhanced cycle performance of Li-S battery with a polypyrrole functional interlayer10.1016/j.jpowsour.2014.05.057 ↗
25. Improved lithium–sulfur cells with a treated carbon paper interlayer10.1039/c2cp43394j ↗
26. Nickel foam as interlayer to improve the performance of lithium–sulfur battery10.1007/s10008-013-2351-5 ↗
27. Synergistic ultrathin functional polymer-coated carbon nanotube interlayer for high performance Lithium−SulfurBatteries10.1021/acsami.6b06190 ↗
28. Lightweight reduced graphene Oxide@MoS2 interlayer as polysulfide barrier for high-performance lithium-sulfur batteries10.1021/acsami.7b18645 ↗
29. Facile synthesis of sulfur-polypyrrole as cathode for lithium-sulfur batteries10.1002/celc.201600479 ↗
30. Dense coating of Li4Ti5O12 and graphene mixture on the separator to produce long cycle life of lithium-sulfur battery10.1016/j.nanoen.2016.09.030 ↗