journal article·2018-10

Site-sensitive energy transfer from Ce3+ to Tb3+/Mn2+ based on an efficient phosphor Li4SrCa(SiO4)2:Ce3+

Shuzhen Liao, Weilu Zhang, Jilin Zhang

Ceramics International· Volume 44· Issue 15
Publisher page

Abstract

Abstract Ce3+,Tb3+/Mn2+ co-doped Li4SrCa(SiO4)2 (LSCSO) phosphors were synthesized by a high-temperature solid-state reaction based on a highly efficient LSCSO:0.03Ce3+ with UV and blue emissions. Energy transfer (ET) in these phosphors was studied. Analyses indicate that ET efficiency from UV Ce3+ to Tb3+ and Mn2+ are larger than that from Ce3+ with blue emission. Different situations in spectral overlap and diverse interactions lead to the different ET efficiency. Emission color of LSCSO:Ce3+,Tb3+,Mn2+ phosphor can be tuned in green-orange-white region by adjusting the concentrations of activators. The present work may provide an example to explore suitable Ce3+ or Eu2+ doped phosphor for single-phase white phosphor on the basis of efficient energy transfer.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Perovskite Materials and Applications · Radiation Detection and Scintillator Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Mn2+ and Mn4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review10.1039/C8TC00251G ↗
2. How to produce white light in a single-phase host?10.1039/C3CS60314H ↗
3. A highly efficient white light (Sr3,Ca,Ba)(PO4)3Cl:Eu2+,Tb3+,Mn2+ phosphor via dual energy transfers for white light-emitting diodes10.1021/ic402870p ↗
4. Tunable color of Ce3+/Tb3+/Mn2+-Coactivated CaScAlSiO6 via energy transfer: a single-component red/white-emitting phosphor10.1021/ic3024666 ↗
5. Color-tunable emission and energy transfer in Ca3Gd7(PO4)(SiO4)5O2:Ce3+/Tb3+/Mn2+ phosphors10.1021/ic3015578 ↗
6. Tunable full-color emitting BaMg2Al6Si9O30:Eu2+,Tb3+,Mn2+ phosphors based on energy transfer10.1021/ic201033e ↗
7. A novel single-composition trichromatic white-light Ca3Y(GaO)3(BO3)4:Ce3+,Mn2+,Tb3+ phosphor for UV-light emitting diodes10.1021/jp107856d ↗
8. Single-phase white-emitting phosphors Ba3Ce(1-x-y)(PO4)3:xTb3+,yMn2+ and Ba3Ce(1-x-z)(PO4)3:xTb3+,zSm3+: structure, luminescence, energy transfer and thermal stability10.1039/C7RA01766A ↗
9. Tunable white light of Ce3+, Tb3+, Mn2+ triply doped Na2Ca3Si2O8 phosphor for high colour-rendering white LED applications: tunable luminescence and energy transfer10.1039/C7DT01086A ↗
10. Tunable luminescence and energy transfer properties in Ca8MgLu(PO4)7:Ce3+,Tb3+,Mn2+ phosphors10.1039/C4TC02433H ↗
11. Generation of orange and green emissions in Ca2GdZr2(AlO4)3:Ce3+,Mn2+,Tb3+ garnets via energy transfer with Mn2+ and Tb3+ as acceptors10.1039/C4TC02652G ↗
12. Single-phased white-light-emitting NaCaBO3:Ce3+,Tb3+,Mn2+ phosphors for LED applications10.1039/C3DT52328D ↗
13. Highly efficient Sr3Y2(Si3O9)2:Ce3+, Tb3+/Mn2+/Eu2+ phosphors for white LEDs: structure refinement, color tuning and energy transfer10.1039/C4RA06538G ↗
14. A novel single-composition trichromatic white-emitting Sr3.5Y6.5O2(PO4)1.5(SiO4)4.5:Ce3+/Tb3+/Mn2+ phosphor: synthesis, luminescent properties and applications for white LEDs10.1039/c3tc32003k ↗
15. Warm white light generation from a single phased phosphor Sr10[(PO4)5.5(BO4)0.5](BO2):Eu2+,Mn2+,Tb3+ for light emitting diodes10.1039/c3ra00040k ↗
16. Single-phased white-light-emitting KCaGd(PO4)2:Eu2+,Tb3+,Mn2+ phosphors for LED applications10.1039/c3ra40471d ↗
17. A full-color emitting phosphor Ca9Ce(PO4)7:Mn2+,Tb3+: efficient energy transfer, stable thermal stability and high quantum efficiency10.1016/j.cej.2017.04.032 ↗
18. Blasse · 1994
19. Site-sensitive energy transfer modes in Ca3Al2O6:Ce3+/Tb3+/Mn2+ Phosphors10.1039/C4DT01587H ↗
20. Color tunable and thermally stable luminescence of Tb3+ doped Li4SrCa(SiO4)2 phosphors10.1016/j.materresbull.2012.04.010 ↗
21. Photoluminescence properties of blue-emitting Li4SrCa(SiO4)2:Eu2+ phosphor for solid-state lighting10.1007/s00340-009-3820-5 ↗
22. Generation of tunable-emission in Li4Ca1-xSr0.96+x(SiO4)2:0.04Eu2+ phosphors for LEDs application10.1364/OME.5.001704 ↗
23. Site-occupancy on the luminescence properties of a single-phase Li4SrCa(SiO4)2:Eu2+ phosphor10.1016/j.ceramint.2014.02.073 ↗
24. Li4SrCa(SiO4)2:Ce3+, a Highly Efficient near-UV and Blue Emitting Orthosilicate Phosphor10.1016/j.jallcom.2015.05.280 ↗
25. Composition Screening in Blue-Emitting Li4Sr1+xCa0.97–x(SiO4)2:Ce3+ Phosphors for High Quantum Efficiency and Thermally Stable Photoluminescence10.1021/acsami.7b08671 ↗
26. The New Orthosilicate Li4SrCa(SiO4)2: structure and Eu2+ Luminescence10.1021/ic00110a005 ↗
27. Ba9Lu2Si6O24:Ce3+: an efficient green phosphor with high thermal and radiation stability for solid-state lighting10.1002/adom.201500078 ↗
28. An excellent cyan-emitting orthosilicate phosphor for NUV-pumped white LED application10.1039/C7TC04168C ↗
29. Photoluminescence properties of efficient blue-emitting phosphor α-Ca1.65Sr0.35SiO4:Ce3+: color tuning via the substitutions of Si by Al/Ga/B10.1021/acs.inorgchem.5b01197 ↗
30. Ab initio structure determination and photoluminescent properties of an efficient, thermally stable blue phosphor, Ba2Y5B5O17:Ce3+10.1021/acs.chemmater.5b04542 ↗
31. Ce-doped La3Si6.5Al1.5N9.5O5.5, a rare highly efficient blue-emitting phosphor at short wavelength toward high color rendering white LED application10.1021/acsami.7b03909 ↗
32. Optical properties of Ce-doped Li4SrCa(SiO4)2: a combined experimental and theoretical study10.1021/acs.inorgchem.7b02561 ↗
33. Energy transfer in oxidic phosphors
34. Theory of concentration quenching in inorganic phosphors10.1063/1.1740265 ↗
35. Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them10.1063/1.1677427 ↗
36. Ronda · 2008 · 18
37. Novel red-emitting phosphor Ca9Y(PO4)7:Ce3+,Mn2+ with energy transfer for fluorescent lamp application10.1021/am100043q ↗
38. Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass10.1016/S0022-3697(02)00416-X ↗