journal article·2010-09

Induced superhydrophobicity in ZnO nanomaterial

Ilya Torchinsky, Michel Molotskii, Gil Rosenman

Journal of Nanoparticle Research· Volume 12· Issue 7
Publisher page

Abstract

Pronounced variation of wettability from high hydrophilic state to superhydrophobic has been observed in ZnO-nanomaterial irradiated by low energy electrons. It has been found that for electron-treated nanomaterial water does not wet the ZnO-nanoparticles and does not penetrate at all inside the micrometer-size pores between individual nanoparticles and their aggregates. The water droplets fix on individual protrusions of strongly inhomogeneous hydrophobic ZnO-nanomaterial surface leading to the superhydrophobic states. The observed effect is consistent with proposed theoretical description. The developed environmentally clean technology of nanomaterial surface modification is the basis for engineering of other related to wettability surface properties such as hygroscopicity and agglomeration and it may be applied in a number of nanotechnology applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Electrohydrodynamics and Fluid Dynamics · Aerogels and thermal insulation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Aronov D, Rosenman G (2007) Surface energy modification by electron beam. Surf Sci 601:5042–504910.1016/j.susc.2007.09.003 ↗
2. Aronov D, Rosen R, Ron EZ, Rosenman G (2006) Tunable hydroxyapatite wettability: effect on adhesion of biological molecules Process. Biochem 41:2367–2372
3. Aronov D, Molotskii M, Rosenman G (2007a) Electron-induced wettability modification. Phys Rev B 76:035437(1-12)10.1103/PhysRevB.76.035437 ↗
4. Aronov D, Molotskii M, Rosenman G (2007b) Charge-induced wettability modification. Appl Phys Lett 90:104104(1-3)10.1063/1.2711656 ↗
5. Aronov D, Rosen R, Ron EZ, Rosenman G (2008) Electron-induced surface modification of hydroxyapatite-coated implant. Surf Coat Tech 202(10):2093–210210.1016/j.surfcoat.2007.08.060 ↗
6. Badre C, Pauport′e T, Turmine M, Lincot D (2007) ZnO nanowire array film with stable highly water-repellent properties. Nanotechnology 18:365705(1-4)10.1088/0957-4484/18/36/365705 ↗
7. Bakaev VA, Steele WA (1999) On the computer simulation of a hydrophobic vitreous silica surface. J Chem Phys 111:9803–981210.1063/1.480317 ↗
8. Barthlott W, Neinhuis C (1997) Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta 202:1–810.1007/s004250050096 ↗
9. Chu PK, Chena JY, Wanga LP, Huang N (2002) Plasma-surface modification of biomaterials. Mater Sci Eng R 36(5):143–206
10. Das SN, Choi JH, Kar JP, Myoung JM (2009) Tunable and reversible surface wettability transition of vertically aligned ZnO nanorod arrays. Appl Surf Sci 255:7319–732210.1016/j.apsusc.2009.03.090 ↗
11. de Gennes PG, Brochrad-Wyart F, Qu′er′e D (2004) Capillarity and wetting phenomena : drops, bubbles, pearls, waves. Springer, New York10.1007/978-0-387-21656-0 ↗
12. Feng X, Jiang L (2006) Design and creation of superwetting/antiwetting surfaces Adv. Mater 18:3063–3078
13. Genzer J, Efimenko K (2006) Recent development in superhydrophobic surfaces and their relevance to marine fouling; a review. Biofouling 22(5):339–36010.1080/08927010600980223 ↗
14. Han J, Gao W (2009) Surface wettability of nanostructured zinc oxide films. J Electron Mater 38(4):601–60810.1007/s11664-008-0615-0 ↗
15. Jeyaprakash JD, Samuela S, Rutherb P, Frerichsc HP, Lehmannc M, Paulb O, Rühe J (2005) A simple route towards the reduction of surface conductivity in gas sensor devices. Sens Actuators B 110(2):218–22410.1016/j.snb.2005.01.032 ↗
16. Kako T, Nakajima A, Irie H, Kato Z, Uematsu ZK, Watanabe T, Hashimoto K (2004) Adhesion and sliding of wet snow on a super-hydrophobic surface with hydrophilic channels. J Mater Sci 39(2):547–55510.1023/B:JMSC.0000011510.92644.3f ↗
17. Li G, Chen T, Yan B, Ma Y, Zhang Z, Yu T, Shen Z, Chen H, Wu T (2008) Tunable wettability in surface-modified ZnO-based hierarchical Nanostructures. Appl Phys Lett 92:173104(1-3)
18. Marmur A (2006) Super-hydrophobicity fundamentals: implications to biofouling prevention. Biofouling 22(2):107–11510.1080/08927010600562328 ↗
19. Molotskii M, Torchinsky I, Rosenman G (2009) Hertz model for contact of water droplet with superhydrophobic surface. Phys Lett A 373:804–80610.1016/j.physleta.2009.01.001 ↗
20. Nakajima A, Abe K, Hashimoto K, Watanabe T (2000) Preparation of hard super-hydrophobic films with visible light transmission. Thin Solid Films 376:140–14310.1016/S0040-6090(00)01417-6 ↗
21. Nakajima A, Hashimoto K, Watanabe T (2001a) Recent studies on super-hydrophobic films. Monatshefte für Chemie 132:31–4110.1007/s007060170142 ↗
22. Nakajima A, Saiki C, Hashimoto K, Watanabe T (2001b) Processing of roughened silica film by coagulated colloidal silica for super-hydrophobic coating. J Mater Sci Lett 20:1975–197710.1023/A:1013199105688 ↗
23. Nohyneka GJ, Dufoura EK, Roberts MS (2008) Nanotechnology, cosmetics and the skin: is there a health risk? Skin Pharmacol Physiol 21:136–14910.1159/000131078 ↗
24. Pukánszky B, Fekete E (1999) Adhesion and surface modification. Adv Polym Sci 139:1436–5030
25. Qu′er′e D (2005) Non-sticking drops. Rep Prog Phys 68:2495–253210.1088/0034-4885/68/11/R01 ↗
26. Rosenman G, Aronov D, Dekhtyar Y (2007) PCT patent, no. WO 2007/049280
27. Sabaev V, Aronov D, Rosenman G (2008) Electron-induced surface reactivity modification in zinc oxide-based thin films. Appl Phys Lett 93:144104(1-3)
28. Stoneham AM, Tasker PW (1986) The wetting of oxide films on silicon and the monitoring of fixed charge. Semicond Sci Technol 1:93–9610.1088/0268-1242/1/1/011 ↗
29. Torchinsky I, Rosenman G (2008) Interface modification and bonding of lithium tantalate crystals. Appl Phys Lett 92: 052903(1–3)10.1063/1.2841706 ↗
30. Torchinsky I, Rosenman G (2008b) Interface engineering and direct bonding of lithium tantalate crystals. J Electron Mater 37(1):1547–155110.1007/s11664-008-0508-2 ↗
31. Zhang J, Huang W, Han Y (2006) Wettability of zinc oxide surfaces with controllable structures. Langmuir 22:2946–295010.1021/la053428q ↗
32. Zhang Z, Chen H, Zhong J, Saraf G, Lu Y (2007) Fast and reversible wettability transitions on ZnO nanostructures. J Electron Mater 36(8):895–89910.1007/s11664-007-0126-4 ↗