The thermal and microstructural behavior of a R2O–RO–(ZnO)–Al2O3–(TiO2)–SiO2 based macro-crystalline raw glaze system
Source abstract
Abstract
Abstract Macro-crystalline glazes containing significantly large crystals visible to the naked eye are a type of artistic glaze with a decorative and esthetic performance. The use of raw glaze compositions is a cost effective alternative for these types of crystal glazes. In the present study, R2O–RO–(ZnO)–Al2O3–(TiO2)–SiO2-based raw glaze system was studied to produce macro-crystalline glazes for Limoges porcelain bodies. The influence of the addition of TiO2 as a nucleating agent or major phase was evaluated in zinc-based glazes as well as ZnO-free ones. Designed glaze compositions were fired according to a special heat treatment cycle and characterized in terms of thermal and microstructural behavior using a digital microscope, differential thermal analyses, hot stage microscopy, X-ray diffraction, a scanning electron microscope, and energy-dispersive X-ray spectroscopy.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Pigment Synthesis and Properties · Recycling and utilization of industrial and municipal waste in materials production · Building materials and conservation
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (35)
Show source-provided references
1. C.W. Parmelee, Ceramic Glazes: Industrial Publications Inc. Chicago 3: Illinois; 1951
2. Eppler · 2000
3. The control of crystalline glazes10.1111/j.1151-2916.1937.tb19892.x ↗
4. Price · 2003
5. Taylor · 1986
6. The effect of CaCO3 addition on the crystallization behavior of ZnO crystal glaze fired at different gloss firing and crystallization temperatures10.2298/SOS1003345J ↗
7. The development and characterization of zinc crystal glazes used for Amakusa-like soft porcelains10.1016/S0955-2219(00)00075-3 ↗
8. Development of TiO2 white glazes for ceramic tiles10.1016/j.dyepig.2008.07.017 ↗
9. Influence of firing parameters on phase composition of raw glazes10.1016/j.jeurceramsoc.2006.05.012 ↗
10. Decorative zinc-containing crystalline glazes for ornamental ceramics (a review)10.1023/A:1014958309094 ↗
11. Effects of cobalt, copper, manganese and titanium oxide additions on the microstructures of zinc containing soft porcelain glazes10.1016/S0955-2219(01)00456-3 ↗
12. The effect of albite wastes on glaze properties and microstructure of soft porcelain zinc crystal glazes10.1016/S0955-2219(00)00296-X ↗
13. Characterization of Li–Zn–Fe crystalline phases in low temperature ceramic glaze10.1016/j.jeurceramsoc.2012.10.027 ↗
14. Research on the crystallization of willemite in the crystalline glaze kinetics of spherulitic crystallization in the glaze melt
15. Progress in research of willemite crystalline graze in china
16. A study of willemite morphology during the growing period
17. Microscopy and microanalysis of crystalline glazes10.1111/j.0022-2720.2004.01380.x ↗
18. Lewis · 1989
19. A study of nucleation and growth in zinc crystal glaze by firing conditions10.4191/KCERS.2009.46.3.253 ↗
20. The effect of nucleating agent on Zn2SiO4 crystal glaze10.4191/kcers.2013.50.2.116 ↗
21. H. Erkmen, Macro-crystal glaze researches and applications (Master thesis), Mimar Sinan University, Enstitute of Social Sciences, Department of Ceram and Glass Design, Istanbul, 2007 (in Turkish).
22. Kafo E., The Fundamentals of the Glaze Preparation. Japan International Cooperation Agency, 1983.
23. Preda M., Rehner H.H., Crystallized glazes K2O-ZnO-TiO2-SiO2 quaternary system, in: Proceedins of the Conference and Exhibition of the European Ceramic Society, Brighton, 1999.
24. Types and compositions of crystalline glazes10.1007/BF02681330 ↗
25. Thermal decomposition of calcium carbonate polymorphs precipitated in the presence of ammonia and alkylamines10.1016/j.apt.2013.08.003 ↗
26. Kingery · 1976
27. Formation of CaTiO3 by grinding from mixtures of CaO or CaO(OH)2 with anatase or rutile at room temperature10.1016/S0032-5910(98)00012-6 ↗
28. Chemical synthesis of environment-friendly nanosized yellow titanate pigments10.1016/j.materresbull.2007.04.001 ↗
29. Crystallization behavior and microstructure of (CaO·ZrO2·SiO2)–Cr2O3-based glasses10.1016/j.jnoncrysol.2011.07.040 ↗
30. Crystallization kinetics of a soda lime silica glass with TiO2 addition
31. Sintering behaviour of nanostructured glass-ceramic glazes10.1016/j.ceramint.2010.03.029 ↗
32. Characterizing the glaze melting behavior via HSM
33. Crystalline phase characterization of glass-ceramic glazes10.1016/j.ceramint.2005.10.002 ↗
34. Gahnite devitrification in ceramic frits: mechanism and process kinetics10.1111/j.1151-2916.2000.tb01664.x ↗
35. Effects of composition on the phase transformation behavior of anatase TiO2 in photocatalytic ceramics10.1016/j.materresbull.2013.07.033 ↗