journal article·2014-09

Controlled synthesis of porous FeCO3 microspheres and the conversion to α-Fe2O3 with unconventional morphology

Tao Yang, Zhaohui Huang, Yangai Liu, Minghao Fang, Xin Ouyang, Meiling Hu

Ceramics International· Volume 40· Issue 8
Publisher page

Abstract

Abstract Porous FeCO3 microspheres were synthesized via a facile surfactant- and template-free hydrothermal process. The diameters of FeCO3 microspheres are about 20±5 μm. Each FeCO3 microsphere was self-assembled with a number of trilobed wheel-like subunits. The influence of preparation conditions, such as temperature, reaction time and content of urea on the phase composition and morphology were investigated. Based on time-dependent experiments, we proposed the possible formation mechanism for the self-assembled FeCO3 micro-spheres. After calcination at 650 °C, α-Fe2O3 derived from FeCO3 retained the original size and morphology of FeCO3. The prepared α-Fe2O3 with the novel microstructure shows wide potential application as photocatalysts.
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Research context

OpenAlex topics: Iron oxide chemistry and applications · Nanoparticle-Based Drug Delivery · Minerals Flotation and Separation Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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